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Solubility chart

From Wikipedia, the free encyclopedia
Chart describing whether ionic compounds dissolve or precipitate
For detailed information on exact solubility of compounds, seesolubility table.

Asolubility chart is a chart describing whether theionic compounds formed from different combinations ofcations and anions dissolve in orprecipitate from solution.

Chart

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The following chart shows thesolubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds likecalcium sulfate may require heat to precipitate. For compounds with multiple hydrates, the solubility of the most soluble hydrate is shown.

Some compounds, such asnickel oxalate, will not precipitate immediately even though they are insoluble, requiring a few minutes to precipitate out.[1]

Key
Shighly soluble or miscible≥20 g/L
sSslightly soluble0.1~20 g/L
Irelatively insoluble<0.1 g/L
Rreacts with or in waterN/a
?unavailableN/a
Ions names and symbolsHalogensChalcogensPnictogensCrystallogens
Fluoride
F
Chloride
Cl
Bromide
Br
Iodide
I
Perchlorate
ClO
4
Oxide
O2−
Hydroxide
OH
Sulfide
S2−
Sulfate
SO2−
4
Nitrate
NO
3
[a]
Phosphate
PO3−
4
Carbonate
CO2−
3
[a]
Cyanide
CN
Thiocyanate
SCN
Acetate
C
2
H
3
O
2
Oxalate
C
2
O2−
4
Hydrogen H+SSSSSN/AN/AsSSSSSSSSS
AmmoniumNH+
4
[a]
SSSSSS[b]SRSSSSSSSS
Lithium Li+sSSSSSRSRSSsSsSSSSS
Sodium Na+SSSSSRSRSSSSSSSS
Potassium K+SSSSsSRSRSSSSSSSS
Rubidium Rb+SSSSsSRSRSSSSSS[3]SS
Caesium Cs+SSSSsSRSRSSSSSSSS
Beryllium Be2+SSSRS[4]IIRSSIsSRS[5]SS
Magnesium Mg2+sSSSSSRIRSSIsSRS[6]SsS
Calcium Ca2+ISSSSRsSRsSSIIRS[7]SsS
Strontium Sr2+sSSSSSRsSRsSSIISS[8]SI
Barium Ba2+sSSSSSRSRISI[9]ISSSI
Aluminium Al3+sSSSS[c]S[10]IIRSSIRRS[11]SI
Gallium Ga3+ISSRS[10]IIRsSSIRRS[12]S?
Manganese(II) Mn2+sSSSSS[13]IIISSIISS[14]SI
Iron(II) Fe2+sSSSSSIIISSII?SSsS
Cobalt(II) Co2+sSSSSS[15]IIISSIIISSI
Nickel(II) Ni2+SSSSSIIISSIIISSI[1]
Copper(II) Cu2+sSSS?SIIISSII[d]IISI
Zinc Zn2+sSSSSS[16]IIISSIIIS[17]SI
Cadmium Cd2+SSSSS[18]IIISSIIsSsS[17]SI
Mercury(II) Hg2+RSsSIS[19]IIIRSIISsSSsS[20]
Vanadium(III) V3+ISSSS[21]IIIsSSI??S??
Chromium(III) Cr3+sSSSSSIIISSIISSS?
Iron(III) Fe3+S[e]SSRS[22]IIISSsSR[23]SS[24]S[25][f]sS
Gold(III) Au3+RSsS??III??IIS?sS?
Tin(II) Sn2+SSSSS[26]IIIS?II?I[27]RsS
Lead(II) Pb2+sSsSsSsSSIsSIISII?[28]sSSI
Silver Ag+SIIISIIIsSSIIIIsSI
Mercury(I)Hg2+
2
RIIIS[29]I??sSS[g]?II?S[30][g]?
 Fluoride
F
Chloride
Cl
Bromide
Br
Iodide
I
Perchlorate
ClO
4
Oxide
O2−
Hydroxide
OH
Sulfide
S2−
Sulfate
SO2−
4
Nitrate
NO
3
[a]
Phosphate
PO3−
4
Carbonate
CO2−
3
[a]
Cyanide
CN
Thiocyanate
SCN
Acetate
C
2
H
3
O
2
Oxalate
C
2
O2−
4

See also

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Notes

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  1. ^abcdeCompounds that include ammonium (NH+
    4
    ), chlorate (ClO
    3
    ), or nitrate (NO
    3
    ) are soluble without exceptions. Compounds that include carbonate (CO2−
    3
    ) are insoluble, unless the compound includesgroup 1 elements or ammonium.[2]
  2. ^"Ammonium oxide" does not exist. However, its theoretical molecular formula (NH+
    4
    )2O2− represents that ofaqueous ammonia.
  3. ^Partial electrolysis.
  4. ^The commonly encounteredbasic copper carbonate (Cu2CO3(OH)2) is insoluble in water. Truecopper(II) carbonate (CuCO3) is rare and reacts with water to form basic copper carbonate.
  5. ^Anhydrous FeF3 is slightly soluble in water; FeF3·3H2O is much more soluble in water.
  6. ^The commonly encounteredbasic iron(III) acetate ([Fe3O(OAc)6(H2O)3]OAc) is insoluble in water. True iron(III) acetate (Fe(OAc)3) is rare and is soluble in water.
  7. ^abSlowly decomposes in water.

References

[edit]
  1. ^abJ. A. Allen (1953). "The Precipitation of Nickel Oxalate".J. Phys. Chem.57 (7):715–716.doi:10.1021/j150508a027.
  2. ^"Solubility Table".intro.chem.okstate.edu.
  3. ^M. J. Joyce; F. Ninio (1989)."Raman Spectrum of Rubidium Thiocyanate at 37 K and Room Temperature".Australian Journal of Physics.42 (4):389–400.doi:10.1071/PH890389.
  4. ^Birgitta Carell; Åke Olin (1961)."Studies on the Hydrolysis of Metal Ions. 37. Application of the Self-Medium Method to the Hydrolysis of Beryllium Perchlorate".Acta Chemica Scandinavica.15:1875–1884.doi:10.3891/acta.chem.scand.15-1875.
  5. ^W. J. Biermann; R. H. McCorkell (1967)."Liquid–liquid extraction of beryllium thiocyanate".Canadian Journal of Chemistry.45 (22):2846–2849.doi:10.1139/v67-459.
  6. ^K. Mereiter; A. Preisinger (1982). "Structure of magnesium isothiocyanate tetrahydrate".Acta Crystallographica B.38 (4):1263–1265.doi:10.1107/S0567740882005433.
  7. ^Claudia Wickleder; Patrick Larsen (2002). "Ca(SCN)2 and Ca(SCN)2 · 2 H2O: Crystal Structure, Thermal Behavior and Vibrational Spectroscopy".Zeitschrift für Naturforschung B.57 (12):1419–1426.doi:10.1515/znb-2002-1213.
  8. ^Claudia Wickleder (2001). "M(SCN)2 (M = Eu, Sr, Ba): Kristallstruktur, thermisches Verhalten, Schwingungsspektroskopie".Zeitschrift für anorganische und allgemeine Chemie (in German).627 (7):1693–1698.doi:10.1002/1521-3749(200107)627:7<1693::AID-ZAAC1693>3.0.CO;2-U.
  9. ^Hazen, Jeffery L.; Cleary, David A. (July 2, 2014). "Yielding Unexpected Results: Precipitation of Ba3(PO4)2 and Implications for Teaching Solubility Principles in the General Chemistry Curriculum".Journal of Chemical Education.91 (8):1261–1263.Bibcode:2014JChEd..91.1261H.doi:10.1021/ed400741k.
  10. ^abLaurence S. Foster (1939). "(I) The Reaction of Gallium with Perchloric Acid and (II) the Preparation and Properties of Gallium Perchlorate Hydrates".Journal of the American Chemical Society.61 (11):3122–3124.doi:10.1021/ja01266a041.
  11. ^S.J. Patel (1971). "Aluminium(III) isothiocyanate and its addition compounds".Journal of Inorganic and Nuclear Chemistry.33 (1):17–22.doi:10.1016/0022-1902(71)80004-0.
  12. ^S. J. Patel; D. G. Tuck (1969). "Gallium(III) isothiocyanate and its addition compounds".Canadian Journal of Chemistry.47 (2):229–233.doi:10.1139/v69-032.
  13. ^"44318 Manganese(II) perchlorate hexahydrate, 99.995% (metals basis)".Alfa Aesar. Retrieved16 September 2022.
  14. ^B. Beagley; C.A. McAuliffe; A.G. Mackie; R.G. Pritchard (1984). "Preparation and crystal structure of manganese(II) isothiocyanate tetrahydrate".Inorganica Chimica Acta.89 (3):163–166.doi:10.1016/S0020-1693(00)82345-2.
  15. ^E. Kamieńska-Piotrowicz (1999). "Conductometric Studies of Cobalt(II) Perchlorate in Acetonitrile-Water Solutions".Zeitschrift für Physikalische Chemie.210 (1):1–13.doi:10.1524/zpch.1999.210.Part_1.001.S2CID 102316324.
  16. ^Lili Lin; Xiaohua Liu; Xiaoming Feng (2014). "Zinc(II) Perchlorate Hexahydrate".Encyclopedia of Reagents for Organic Synthesis. John Wiley & Sons, Ltd. pp. 1–5.doi:10.1002/047084289X.rn01657.ISBN 9780470842898.
  17. ^abMasaki Kosaku (1931)."The Solubilities of Thiocyanate of Metals".Bulletin of the Chemical Society of Japan.6 (7):163–165.doi:10.1246/bcsj.6.163.
  18. ^P. J. Reilly; R. H. Strokes (1971). "The diffusion coefficients of cadmium chloride and cadmium perchlorate in water at 25°".Australian Journal of Chemistry.24 (7):1361–1367.doi:10.1071/CH9711361.
  19. ^Franco Cristiani; Francesco Demartin; Francesco A. Devillanova; Angelo Diaz; Francesco Isaia; Gaetano Verani (1990). "Reactivity of Mercury(II) Perchlorate Towards 5,5 -Dimethylimidazolidine-2- Thione-4-One. Structure of Bis(5,5-Dimethylimidazolidine-2-Thione-4-One)Mercury(II) Perchlorate Triaquo".Journal of Coordination Chemistry.21 (2):137–146.doi:10.1080/00958979009409182.
  20. ^"Properties of substance: mercury(II) oxalate Group of substances".Chemister. Retrieved13 September 2022.
  21. ^Burkhart, M J; Newton, T W (1969). "Kinetics of the reaction between vanadium(II) and neptunium(IV) in aqueous perchlorate solutions".J. Phys. Chem.73 (6):1741–1746.doi:10.1021/j100726a018.
  22. ^M. Magini (1978). "An X-ray investigation on the structure of iron(III) perchlorate solutions".Journal of Inorganic and Nuclear Chemistry.40 (1):43–48.doi:10.1016/0022-1902(78)80304-2.
  23. ^"Iron (III) Carbonate Formula".softschools.com. p. 1. Retrieved19 August 2022.
  24. ^Sano Hirotoshi; Akane Michiko (1973). "MÖSSBAUER SPECTROSCOPIC STUDIES ON IRON THIOCYANATE".Chemistry Letters.2 (1):43–46.doi:10.1246/cl.1973.43.
  25. ^Ram C. Paul; Ramesh C. Narula; Sham K. Vasisht (1978). "Iron(III) acetates".Transition Metal Chemistry.3:35–38.doi:10.1007/BF01393501.S2CID 94447648.
  26. ^C.G.Davies; J.D.Donaldson (1968). "Tin(II) perchlorate trihydrate".Journal of Inorganic and Nuclear Chemistry.30 (10). Chelsea College of Science and Technology:2635–2639.doi:10.1016/0022-1902(68)80389-6.
  27. ^Tewfik B. Absi; Ramesh C. Makhija; Mario Onyszchuk (1978). "Synthesis and vibrational spectra of tin(II) isothiocyanate adducts with some O- and N-donor ligands".Canadian Journal of Chemistry.56 (15):2039–2041.doi:10.1139/v78-333.
  28. ^Schulz, Axel; Surkau, Jonas (2023)."Main group cyanides: from hydrogen cyanide to cyanido-complexes".Reviews in Inorganic Chemistry.43 (1):49–188.doi:10.1515/revic-2021-0044.ISSN 0193-4929.
  29. ^D. R. Rossėinsky (1963). "The reaction between mercury(I) and manganese(III) in aqueous perchlorate solution".Journal of the Chemical Society (Resumed):1181–1186.doi:10.1039/JR9630001181.
  30. ^National Center for Biotechnology Information."PubChem Compound Summary for CID 61181, Mercurous acetate".PubChem.
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