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Sodium dichloroisocyanurate

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(Redirected fromSodium dichloro-s-triazinetrione)
Sodium dichloroisocyanurate
Names
IUPAC name
Sodium 3,5-dichloro-2,4,6-trioxo-1,3,5-triazinan-1-ide
Other names
  • Sodium dichloroisocyanurate
  • Sodium troclosene
  • Sodic troclosene
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.018.880Edit this at Wikidata
RTECS number
  • XZ1900000
UNII
UN number2465 or 3077
  • InChI=1S/C3HCl2N3O3.Na/c4-7-1(9)6-2(10)8(5)3(7)11;/h(H,6,9,10);/q;+1/p-1 checkY
    Key: MSFGZHUJTJBYFA-UHFFFAOYSA-M checkY
  • InChI=1S/C3HCl2N3O3.Na/c4-7-1(9)6-2(10)8(5)3(7)11;/h(H,6,9,10);/q;+1/p-1
    Key: MSFGZHUJTJBYFA-REWHXWOFAV
  • Key: MSFGZHUJTJBYFA-UHFFFAOYSA-M
  • [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O
Properties
C3Cl2N3NaO3
Molar mass219.95 g/mol (anhydrous)

255.98 g/mol (dihydrate)

Appearancewhite, crystalline powder
Odorchlorine-like
Density0.7 g/cm3 (as granules)
Melting point225 °C (437 °F; 498 K)
22.7 g/100 mL (25 °C)
Solubility inacetone0.5 g/100 mL (30 °C)
Acidity (pKa)6.2-6.8
Hazards
GHS labelling:
GHS03: OxidizingGHS05: CorrosiveGHS07: Exclamation markGHS09: Environmental hazard
Danger
H272,H302,H314,H319,H335,H410
P210,P220,P260,P261,P264,P264+P265,P270,P271,P273,P280,P301+P317,P301+P330+P331,P302+P361+P354,P304+P340,P305+P351+P338,P305+P354+P338,P316,P317,P319,P321,P330,P337+P317,P363,P370+P378,P391,P403+P233,P405,P501
NFPA 704 (fire diamond)
Lethal dose or concentration (LD, LC):
(Rat oral) 1670 mg/kg
Related compounds
Othercations
Potassium dichloroisocyanurate
Calcium dichloroisocyanurate
Lithium dichloroisocyanurate
Barium dichloroisocyanurate
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Chemical compound

Sodium dichloroisocyanurate (INN: sodium troclosene,troclosenum natricum or NaDCC or SDIC) is a chemical compound widely used as a cleansing agent and disinfectant.[1] It is a colorless, water-soluble solid, produced as a result of reaction ofcyanuric acid withchlorine. The dihydrate is also known (51580-86-0 ) as is the potassium salt (2244-21-5 ).

Uses

[edit]

It is mainly used as adisinfectant,biocide and industrialdeodorant. It is found in some modernwater purification tablets/filters. It is more efficient than the formerly usedhalazone water disinfectant. In these applications, it is a slow-release source of chlorine in low concentrations at a relatively constant rate. As a disinfectant, it is used to sterilize drinking water, swimming pools, tableware and air, and to fight against infectious diseases as a routine disinfection agent.

It can be used for disinfection and environmentalsterilization, for example in livestock, poultry, fish andsilkworm raising, forbleaching textiles, for cleaning industrial circulating water, and to prevent wool from shrinking.

The reaction between NaDCC and a dilute solution ofcopper (II) sulfate produces an intenselilac precipitate of the complex saltsodium copper dichloroisocyanurate. The reactions between dichloroisocyanurate salts (Na,K,Li,Ba,Ca) and transition metal salts (Ni,Cu,Cd) are described in patentUS 3,055,889. The overall reaction is:

CuSO4 + 4 Na(C3N3O3Cl2) → Na2[Cu(C3N3O3Cl2)4] + Na2SO4

Sodium dichloroisocyanurate reacts with concentrated (130 vol, 35%)hydrogen peroxide to createsinglet oxygen which emits red light upon decomposition .[2]

It is considered hazardous according to OSHA 29 CFR 1910.1200. High-level exposure can causereactive airways dysfunction syndrome (R.A.D.S.)[3]

See also

[edit]

References

[edit]
  1. ^Huthmacher, Klaus; Most, Dieter (2000). "Cyanuric Acid and Cyanuric Chloride".Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH.doi:10.1002/14356007.a08_191.ISBN 3-527-30673-0..
  2. ^[Acc. Chem. Res. 2006, 39, 11, 797–804]
  3. ^"Sodium dichloroisocyanurate - Material Safety Data Sheet"(PDF). September 30, 2009.
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