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Sodium deuteroxide

From Wikipedia, the free encyclopedia
Sodium deuteroxide[1]
Names
IUPAC name
Sodium deuteroxide
Other names
  • Deuterated sodium hydroxide
  • Sodium hydroxide-d
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.034.373Edit this at Wikidata
EC Number
  • 237-825-2
  • InChI=1S/Na.H2O/h;1H2/q+1;/p-1/i/hD
    Key: HEMHJVSKTPXQMS-DYCDLGHISA-M
  • [Na+].[O-][2H]
Properties
NaOD or NaO2H
Molar mass41.003 g/mol
AppearanceWhite solid
Soluble
Hazards
GHS labelling:
GHS05: Corrosive
Danger
H290,H314
P260,P264,P280,P301+P330+P331,P303+P361+P353,P304+P340,P305+P351+P338,P310,P321,P363,P405,P501
NFPA 704 (fire diamond)
Related compounds
Related compounds
Sodium hydroxide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Sodium deuteroxide ordeuterated sodium hydroxide is a chemical compound with the formulaNaOD or NaO2H.IUPAC recommends that the symbol for deuterium should be2H,[2] although most chemists use the term NaOD. It is a white solid very similar tosodium hydroxide, of which it is anisotopologue. It is used as astrong base anddeuterium source in the production of other deuterated compounds. For example, reaction withchloral hydrate givesdeuterated chloroform,[3] and reaction withN-nitrosodimethylamine gives the deuterated analog of that compound.[4][full citation needed] Sodium deuteroxide is anionic compound, consisting ofsodiumcationsNa+ and deuteroxideanionsOD (orO2H).

Notes

[edit]

References

[edit]
  1. ^"Sodium deuteroxide".Sigma aldrich. Retrieved30 April 2021.
  2. ^"Provisional Recommendations".Nomenclature of Inorganic Chemistry. Chemical Nomenclature and Structure Representation Division.IUPAC. § IR-3.3.2. Archived fromthe original on 27 October 2006. Retrieved2024-08-01.
  3. ^Breuer, F. W. (1935). "Chloroform-d (Deuteriochloroform)".Journal of the American Chemical Society.57 (11):2236–2237.Bibcode:1935JAChS..57.2236B.doi:10.1021/ja01314a058.
  4. ^National Cancer Institute (U.S.) (1973).Journal (51 ed.). the University of Michigan.
Inorganic
Halides
Chalcogenides
Pnictogenides
Oxyhalides
Oxychalcogenides
Oxypnictogenides
Metalates
Others
Organic
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