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Scandium phosphide

From Wikipedia, the free encyclopedia
Scandium phosphide
Names
Other names
Scandium monophosphide,[1] phosphanylidynescandium
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.032.153Edit this at Wikidata
EC Number
  • 235-381-4
  • InChI=1S/P.Sc
    Key: QWQKEJRTWGEIBF-UHFFFAOYSA-N
  • [Sc+3].[P-3]
Properties
ScP
Molar mass75.929670 g·mol−1
Structure[2]
Rock salt structure
Fm3m
a = 0.5312 nm
4
Octahedral at Sc3+,Octahedral at P3-
Related compounds
Otheranions
Othercations
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Scandium phosphide is aninorganic compound ofscandium andphosphorus with thechemical formulaScP.[3][4][5]

Synthesis

[edit]

ScP can be obtained by the reaction of scandium andphosphorus at 1000 °C.[2]

4 Sc + P4 → 4 ScP

Physical properties

[edit]

This compound is calculated to be asemiconductor used in high power,high frequency applications and inlaser diodes.[6][7]

Chemical properties

[edit]

ScP can besmelted withcobalt ornickel throughelectric arc to obtain ScCoP and ScNiP.[8]

References

[edit]
  1. ^Gschneidner (Jr.), Karl A.; Eyring, LeRoy (1978).Handbook on the Physics and Chemistry of Rare Earths: without special title. North-Holland Publishing Company. p. 287.ISBN 978-0-444-82507-0. Retrieved10 December 2021.
  2. ^abParthé, E. (10 January 1963)."Note on the structure of ScP and YP".Acta Crystallographica.16 (1): 71.Bibcode:1963AcCry..16...71P.doi:10.1107/S0365110X63000141. Retrieved12 December 2021.
  3. ^"Scandium Phosphide".American Elements. Retrieved10 December 2021.
  4. ^"scandium phosphide".National Institute of Standards and Technology. Retrieved10 December 2021.
  5. ^Toxic Substances Control Act (TSCA) Chemical Substance Inventory.U.S. Government Printing Office. 1979. p. 79. Retrieved10 December 2021.
  6. ^Karil, Poornima; Karma, Nikita; Choudhary, K. K.; Kaurav, Netram (29 May 2020)."Effect of pressure on structural and elastic properties of Scandium phosphide".AIP Conference Proceedings. Emerging Interfaces of Physical Sciences and Technology 2019: Eipt2019.2224 (1): 030001.Bibcode:2020AIPC.2224c0001K.doi:10.1063/5.0000475.S2CID 219883570. Retrieved10 December 2021.
  7. ^Perkins, Peter G.; Marwaha, Ashok K.; Stewart, James J. P. (1 November 1981)."The band structures and magnetic properties of some transition-metal monophosphides I. Scandium phosphide".Theoretica Chimica Acta.59 (6):555–568.doi:10.1007/BF00552849.S2CID 94901262. Retrieved10 December 2021.
  8. ^Kleinke, Holger; Franzen, Hugo F. (1 May 1998)."Sc–Sc Bonding in the New Ternary Phosphide ScNiP".Journal of Solid State Chemistry.137 (2):218–222.Bibcode:1998JSSCh.137..218K.doi:10.1006/jssc.1997.7704. Retrieved12 December 2021.
Phosphides
Other compounds
Binary phosphides
Ternary phosphides
Quaternary phosphides
Quinary phosphides
See also
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