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Roscoelite

From Wikipedia, the free encyclopedia
True mica, phyllosilicate mineral
Roscoelite
Roscoelite and gold
General
CategoryPhyllosilicateminerals,micagroup
FormulaK(V3+,Al,Mg)2AlSi3O10(OH)2
IMA symbolRcl[1]
Strunz classification9.EC.15
Crystal systemMonoclinic
Crystal classPrismatic (2/m)
(sameH-M symbol)
Space groupC2/m
Identification
Formula mass426.53 g/mol
Colourolive-green to green-brown
Crystal habitscales, fans,druses,rosettes, fibrous orfelted aggregate.
CleavagePerfect plane {0,0,1}
Fractureplaty
Mohs scale hardness1
Lustrepearly
Diaphaneitysemi-transparent totranslucent
Specific gravity2.92 - 2.96
Optical propertiesBiaxial (-)
Refractive indexnα=1.60 nβ=1.66 nγ=1.67
Birefringenceδ =
Pleochroismolive green to green-brown
Fusibilityloses water

Roscoelite is a green mineral from themica group that containsvanadium.The chemical formula isK(V3+,Al,Mg)2AlSi3O10(OH)2.[2]Crystals of roscoelite take on themonoclinic form, and are from the 2/mpoint group.The appearance is semi transparent to translucent coloured olive brown to green brown. Thelustre is pearly. The mineral showspleochroism with X showing green-brown, and Y and Z axes showing olive-green colour. The mineral was named afterHenry Enfield Roscoe who first produced vanadium metal.

Chemical properties

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Roscoelite is amuscovite withaluminium substituted with vanadium. Vanadium can also be substituted bymagnesium,iron, ormanganese.

Physical properties

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It is soft and the density is 2.93±0.01. Theunit cell has dimensions

a = 526 pm
b = 909 pm
c = 1025 pm,

with an angle between axes of β=101.0°. The tetrahedral cation-oxygen atom distance is 164.1 pm, The distance from the cation to the oxygen in the octahedral plan is 202 pm.[3]

Formation

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Two kinds of mineral deposits contain roscoelite, eithergold-silver-tellurium low temperature epithermal deposits where it occurs along withquartz,fluorite,pyrite andcarbonates, or oxidized low temperatureuranium-vanadiumores insedimentary rocks, where it occurs withcorvusite,hewettite,carnotite andtyuyamunite. Roecoelite is considered agangue mineral of no value when found with gold.[4] However it has also been used as a vanadium ore.

In the Mt. Kare mine in New Guinea the mineral occurs with gold and is an important maker of gold deposits. The temperature of the geothermal fluid that deposited the roscoelite was from 127 to 167 °C (261 to 333 °F). The fluid contained a high level ofsalt and also containedcarbon dioxide,methane,carbonyl sulfide and other minor amounts of rock forming elements.[5]

Occurrence

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The mineral has been found in numerous places in US, Australia, Japan, Gabon, Fiji, New Guinea[6] and Czech Republic. In theUnited States, it was the principalvanadium ore mineral at the mines atPlacerville, Colorado. In Australia roscoelite has been found atKalgoorlie,Radium Hill and the Kintore Open Cut atBroken Hill.[citation needed]

References

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  1. ^Warr, L.N. (2021)."IMA–CNMNC approved mineral symbols".Mineralogical Magazine.85 (3):291–320.Bibcode:2021MinM...85..291W.doi:10.1180/mgm.2021.43.S2CID 235729616.
  2. ^Roscoelite information[full citation needed]
  3. ^Brigatti, Maria Franca; Caprilli, Enrico; Marchesini, Marco; Poppi, Luciano (2003). "The crystal structure of Roscoelite-1M".Clays and Clay Minerals.51 (3):301–8.Bibcode:2003CCM....51..301B.doi:10.1346/CCMN.2003.0510306.S2CID 94934052.INIST 14848261.
  4. ^Kelley, Karen; Armbrustmacher, Theodore; Klein, Douglas (2004) [1996]."Au-Ag-Te Vein Deposits"(PDF). In du Bray, Edward A. (ed.).Preliminary Compilation of Descriptive Geoenvironmental Mineral Deposit Models.United States Geological Survey.
  5. ^Ronacher, E.; Richards, J. P.; Reed, M. H.; Bray, C. J.; Spooner, E. T. C.; Adams, P. D. (2004). "Characteristics and Evolution of the Hydrothermal Fluid in the North Zone High-Grade Area, Porgera Gold Deposit, Papua New Guinea".Economic Geology.99 (5):843–67.Bibcode:2004EcGeo..99..843R.doi:10.2113/gsecongeo.99.5.843.
  6. ^Buffalo Gold at Mt Kare
Micas
Talcs
Pyrophyllite series
Kaolinites
Serpentines
Corrensites
Smectites andvermiculite family
Chlorites
Allophanes
Sepiolites
Pyrosmalites
Stilpnomelanes
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