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Reductone

From Wikipedia, the free encyclopedia

Areductone is a special class oforganic compounds. They areenediols with a carbonyl group adjacent to the enediol group, i.e. RC(OH)=C(OH)-C(O)R. The enediol structure is stabilized by theresonance resulting from the tautomerism with the adjacent carbonyl. Therefore, thechemical equilibrium produces mainly the enediol form rather than the keto form.[1]

Reductones arereducing agents, thus efficaciousantioxidants. Some are fairly strong acids.[2]Examples of reductones are tartronaldehyde, reductic acid and ascorbic acid.

Examples of reductones
Tartronaldehyde Reductic acid Ascorbic acid
(Vitamin C)

References

[edit]
  1. ^Schank, Kurt (1972). "Reductones".Synthesis.1972 (4):176–90.doi:10.1055/s-1972-21845.
  2. ^IUPAC,Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "reductones".doi:10.1351/goldbook.R05224
Hydrocarbons
(only C and H)
Onlycarbon,
hydrogen,
andoxygen
(only C, H and O)
R-O-R
carbonyl
carboxy
Only one
element,
not being
carbon,
hydrogen,
or oxygen
(one element,
not C, H or O)
Nitrogen
Silicon
Phosphorus
Sulfur
Boron
Selenium
Tellurium
Polonium
Halo
Other
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