| Year elected | Image | Name of president[4] (Birth–Death) | UN member state | Region | Sessions |
|---|
| 1946 |  | Paul-Henri Spaak (1889–1972) | Belgium | WES | First |
| 1947 |  | Oswaldo Aranha (1894–1960) | Brazil | LAS | First special Second |
| 1948 |  | José Arce (1881–1968) | Argentina | LAS | Second special |
| 1948 |  | Herbert Vere Evatt (1894–1965) | Australia | COS | Third |
| 1949 |  | Carlos P. Romulo (1898–1985) | Philippines | EAS | Fourth, First Asian president |
| 1950 |  | Nasrollah Entezam (1900–1980) | Iran | EAS | Fifth |
| 1951 |  | Luis Padilla Nervo (1894–1985) | Mexico | LAS | Sixth |
| 1952 |  | Lester B. Pearson (1897–1972) | Canada | COS | Seventh |
| 1953 |  | Vijaya Lakshmi Pandit (1900–1990) | India | COS | Eighth, First woman president |
| 1954 |  | Eelco van Kleffens (1894–1983) | Netherlands | WES | Ninth |
| 1955 |  | José Maza Fernández (1889–1964) | Chile | LAS | Tenth |
| 1956 |  | Rudecindo Ortega Mason (1896–1962) | Chile | LAS | First emergency special Second emergency special |
| 1956 |  | Wan Waithayakon (1891–1976) | Thailand | EAS | Eleventh |
| 1957 |  | Leslie Munro (1901–1974) | New Zealand | COS | Twelfth Third emergency special |
| 1958 |  | Charles Malik (1906–1987) | Lebanon | MES | Thirteenth |
| 1959 |  | Víctor Andrés Belaúnde (1893–1966) | Peru | LAS | Fourteenth Fourth emergency special |
| 1960 |  | Frederick Boland (1904–1985) | Ireland | WES | Fifteenth Third special |
| 1961 |  | Mongi Slim (1908–1969) | Tunisia | MES | Sixteenth, First African president |
| 1962 |  | Muhammad Zafarullah Khan (1893–1985) | Pakistan | COS | Seventeenth Fourth special |
| 1963 |  | Carlos Sosa Rodríguez (1912–1997) | Venezuela | LAS | Eighteenth |
| 1964 |  | Alex Quaison-Sackey (1924–1992) | Ghana | COS | Nineteenth |
| 1965 |  | Amintore Fanfani (1908–1999) | Italy | WES | Twentieth |
| 1966 | | Abdul Rahman Pazhwak (1919–1995) | Afghanistan | Asia | Twenty-first Fifth special Fifth emergency special |
| 1967 |  | Corneliu Mănescu (1916–2000) | Romania | EEG | Twenty-second |
| 1968 |  | Emilio Arenales Catalán (1922–1969) | Guatemala | GRULAC | Twenty-third |
| 1969 |  | Angie Brooks (1928–2007) | Liberia | Africa | Twenty-fourth |
| 1970 |  | Edvard Hambro (1911–1977) | Norway | WEOG | Twenty-fifth |
| 1971 |  | Adam Malik (1917–1984) | Indonesia | Asia | Twenty-sixth |
| 1972 |  | Stanisław Trepczyński (1924–2002) | Poland | EEG | Twenty-seventh |
| 1973 |  | Leopoldo Benites (1905–1996) | Ecuador | GRULAC | Twenty-eighth Sixth special |
| 1974 |  | Abdelaziz Bouteflika (1937–2021) | Algeria | Africa | Twenty-ninth Seventh special |
| 1975 |  | Gaston Thorn (1928–2007) | Luxembourg | WEOG | Thirtieth |
| 1976 |  | Hamilton Shirley Amerasinghe (1913–1980) | Sri Lanka | Asia | Thirty-first |
| 1977 |  | Lazar Mojsov (1920–2011) | Yugoslavia | EEG | Thirty-second Eighth special Ninth special Tenth special |
| 1978 |  | Indalecio Liévano (1917–1982) | Colombia | GRULAC | Thirty-third |
| 1979 |  | Salim Ahmed Salim (born 1942) | United Republic of Tanzania | Africa | Thirty-fourth Sixth emergency special Seventh emergency special Eleventh special |
| 1980 |  | Rüdiger von Wechmar (1923–2007) | Federal Republic of Germany | WEOG | Thirty-fifth Eighth emergency special |
| 1981 |  | Ismat T. Kittani (1929–2001) | Iraq | Asia | Thirty-sixth Seventh emergency special—Continuation Ninth emergency special Twelfth special |
| 1982 |  | Imre Hollai (1925–2017) | Hungary | EEG | Thirty-seventh |
| 1983 |  | Jorge Illueca (1918–2012) | Panama | GRULAC | Thirty-eighth |
| 1984 | | Paul J. F. Lusaka (1935–1996) | Zambia | Africa | Thirty-ninth |
| 1985 |  | Jaime de Piniés (1917–2003) | Spain | WEOG | Fortieth Thirteenth special |
| 1986 | | Humayun Rashid Choudhury (1928–2001) | Bangladesh | Asia | Forty-first Fourteenth special |
| 1987 |  | Peter Florin (1921–2014) | German Democratic Republic | EEG | Forty-second Fifteenth special |
| 1988 |  | Dante Caputo (1943–2018) | Argentina | GRULAC | Forty-third |
| 1989 |  | Joseph Nanven Garba (1943–2002) | Nigeria | Africa | Forty-fourth Sixteenth special Seventeenth special Eighteenth special |
| 1990 |  | Guido de Marco (1931–2010) | Malta | WEOG | Forty-fifth |
| 1991 |  | Samir Shihabi (1925–2010) | Saudi Arabia | Asia | Forty-sixth |
| 1992 |  | Stoyan Ganev (1955–2013) | Bulgaria | EEG | Forty-seventh |
| 1993 |  | Rudy Insanally (1936–2023) | Guyana | GRULAC | Forty-eighth |
| 1994 |  | Amara Essy (1944–2025) | Ivory Coast | Africa | Forty-ninth |
| 1995 |  | Diogo de Freitas do Amaral (1941–2019) | Portugal | WEOG | Fiftieth |
| 1996 |  | Razali Ismail (born 1939) | Malaysia | Asia | Fifty-first Tenth emergency special Nineteenth special |
| 1997 |  | Hennadiy Udovenko (1931–2013) | Ukraine | EEG | Fifty-second Tenth emergency special—Continuation Twentieth special |
| 1998 |  | Didier Opertti (born 1937) | Uruguay | GRULAC | Fifty-third Tenth emergency special—Continuation Twenty-first special |
| 1999 |  | Theo-Ben Gurirab (1938–2018) | Namibia | Africa | Fifty-fourth Twenty-second special Twenty-third special Twenty-fourth special |
| 2000 |  | Harri Holkeri (1937–2011) | Finland | WEOG | Fifty-fifth Tenth emergency special—Continuation Twenty-fifth special Twenty-sixth special |
| 2001 |  | Han Seung-soo (born 1936) | South Korea | Asia | Fifty-sixth Tenth emergency special—Continuation Twenty-seventh special |
| 2002 |  | Jan Kavan (born 1946) | Czech Republic | EEG | Fifty-seventh Tenth emergency special—Continuation |
| 2003 |  | Julian Hunte (born 1940) | Saint Lucia | GRULAC | Fifty-eighth Tenth emergency special—Continuation |
| 2004 |  | Jean Ping (born 1942) | Gabon | Africa | Fifty-ninth Twenty-eighth special |
| 2005 |  | Jan Eliasson (born 1940) | Sweden | WEOG | Sixtieth |
| 2006 |  | Haya Rashed Al-Khalifa (born 1952) | Bahrain | Asia | Sixty-first Tenth emergency special—Continuation |
| 2007 |  | Srgjan Kerim (born 1948) | FYR Macedonia | EEG | Sixty-second |
| 2008 |  | Miguel d'Escoto Brockmann (1933–2017) | Nicaragua | GRULAC | Sixty-third |
| 2009 |  | Ali Treki (1937–2015) | Libya | Africa | Sixty-fourth |
| 2010 |  | Joseph Deiss (born 1946) | Switzerland | WEOG | Sixty-fifth |
| 2011 |  | Nassir Al-Nasser[5] (born 1952) | Qatar | Asia-Pacific | Sixty-sixth |
| 2012 |  | Vuk Jeremić (born 1975) | Serbia | EEG | Sixty-seventh (election) |
| 2013 |  | John William Ashe (1954–2016) | Antigua and Barbuda | GRULAC | Sixty-eighth |
| 2014 |  | Sam Kutesa (born 1949) | Uganda | Africa | Sixty-ninth Twenty-ninth special |
| 2015 |  | Mogens Lykketoft (born 1946) | Denmark | WEOG | Seventieth Thirtieth special |
| 2016 |  | Peter Thomson (born 1948) | Fiji | Asia-Pacific | Seventy-first (election) |
| 2017 |  | Miroslav Lajčák (born 1963) | Slovakia | EEG | Seventy-second Tenth emergency special—Continuation |
| 2018 |  | María Fernanda Espinosa (born 1964) | Ecuador | GRULAC | Seventy-third |
| 2019 |  | Tijjani Muhammad-Bande (born 1957) | Nigeria | Africa | Seventy-fourth |
| 2020 |  | Volkan Bozkır (born 1950) | Turkey | WEOG | Seventy-fifth |
| 2021 |  | Abdulla Shahid (born 1962) | Maldives | Asia-Pacific | Seventy-sixth Eleventh emergency special |
| 2022 |  | Csaba Kőrösi (born 1958) | Hungary | EEG | Seventy-seventh |
| 2023 |  | Dennis Francis (born 1956) | Trinidad and Tobago | GRULAC | Seventy-eighth |
| 2024 |  | Philémon Yang (born 1947) | Cameroon | Africa | Seventy-ninth |
| 2025 |  | Annalena Baerbock (born 1980) | Germany | WEOG | Eightieth |