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Plutonium(III) bromide

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(Redirected fromPlutonium tribromide)
Plutonium(III) bromide
Names
IUPAC name
Plutonium tribromide
Other names
Plutonium(III) bromide
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/3BrH.Pu/h3*1H;/q;;;+3/p-3
    Key: ZOUHELNKIRPXTH-UHFFFAOYSA-K
  • [Br-].[Br-].[Br-].[Pu+3]
Properties
Br3Pu
Molar mass484 g·mol−1
AppearanceGreen[1]
Melting point767 °C (1,413 °F; 1,040 K)[1]
Boiling point1,463 °C (2,665 °F; 1,736 K)
Water soluble
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Plutonium(III) bromide is aninorganic salt ofbromine andplutonium with the formula PuBr3. This radioactive green solid has few uses, however itscrystal structure is often used as a structural archetype incrystallography.

Crystal structure

[edit]
Crystal structure of PuBr3
Crystal structure
unit cell of PuBr3
Unit cell
PuBr3:  Pu3+  Br

The PuBr3 crystal structure was first published in 1948 byWilliam Houlder Zachariasen.[2] The compound forms orthorhombic crystals, a type of square antiprism, within which the Pu atoms adopt an 8-coordinatebicapped trigonal prismatic arrangement. ItsPearson symbol is oS16 with the corresponding space group No. 63 (in International Union of Crystallography classification) or Cmcm (inHermann–Mauguin notation).

References

[edit]
  1. ^abGreenwood, N. N. (2001).Chemistry of the elements (2nd ed.). Boston, Mass. p. 1270.ISBN 0750633654.{{cite book}}: CS1 maint: location missing publisher (link)
  2. ^Zachariasen, W. H. (2 November 1948)."Crystal chemical studies of the 5f-series of elements. I. New structure types".Acta Crystallographica.1 (5):265–268.Bibcode:1948AcCry...1..265Z.doi:10.1107/S0365110X48000703.
Plutonium(II)
  • PuH2
  • [K(2.2.2-crypt)][PuCp'3]
Plutonium(III)
Organoplutonium(III) componunds
Plutonium(III,IV)
Plutonium(IV)
Organoplutonium(IV) compounds
Hexachloroplutonates(IV)
Plutonium(V)
Plutonium(VI)
Plutonyl compounds
Plutonium(VIII)
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