| Names | |
|---|---|
| Other names pentachloroosmium, osmium pentachloride | |
| Identifiers | |
3D model (JSmol) | |
| ChemSpider | |
| |
| |
| Properties | |
| Cl5Os | |
| Molar mass | 367.48 g·mol−1 |
| Appearance | black solid |
| Density | 4.09 |
| Melting point | 160 °C (320 °F; 433 K) |
| soluble | |
| Structure | |
| P21/c[1] | |
a = 9.17 Å,b = 11.5 Å,c = 11.97 Å α = 90°, β = 109°°, γ = 90°.[2] | |
Lattice volume (V) | 1194 Å3 |
Formula units (Z) | 8 |
| Related compounds | |
Related compounds | Osmium pentafluoride;Rhenium pentachloride |
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa). | |
Osmium(V) chloride is aninorganic chemical compound ofosmium metal andchlorine with the chemical formulaOsCl5.[3][4]
Osmium(V) chloride can be obtained in small amounts by reactingosmium hexafluoride with excessboron trichloride:[5]
It can also be obtained by the action ofsulfur dichloride onosmium tetroxide:[2]
Osmium(V) chloride forms a black dimeric solid, isomorphic withrhenium(V) chloride.OsCl5 is sparingly soluble in non-polar solvents.[2] It is soluble inPOCl3 to form a red-brown solution, which can crystallize OsCl5·POCl3.[6]
Thismetal halide related article is astub. You can help Wikipedia byadding missing information. |