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Octatetraynyl radical

From Wikipedia, the free encyclopedia
Organic radical molecule
Octatetraynyl radical
Skeletal formula of the octatetraynyl radical with the explicit hydrogen added
Skeletal formula of the octatetraynyl radical with the explicit hydrogen added
Names
Preferred IUPAC name
Octa-1,3,5,7-tetrayn-1-yl
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C8H/c1-3-5-7-8-6-4-2/h1H checkY
    Key: GTEOCQSGHJLKQX-UHFFFAOYSA-N checkY
  • anion: InChI=1S/C8H/c1-3-5-7-8-6-4-2/h1H/q-1
    Key: JPYHXIJMECKQLV-UHFFFAOYSA-N
  • [C]#CC#CC#CC#C
  • anion: [C-]#CC#CC#CC#C
Properties
C8H
Molar mass97.096 g·mol−1
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Chemical compound

Octatetraynyl radical (C8H) is anorganicfree radical with eightcarbon atoms linked in alinear chain with alternatingsingle bonds andtriple bonds (H−C≡C−C≡C−C≡C−C≡C•).

In 2007 negatively charged octatetraynyl was detected in Galactic molecular sourceTMC-1, making it the second type ofanion to be found in theinterstellar medium (afterhexatriynyl radical) and the largest such molecule detected to date.[1][2]

References

[edit]
  1. ^Remijan, Anthony J.; J. M. Hollis; F. J. Lovas; M. A. Cordiner; T. J. Millar; A. J. Markwick-Kemper; P. R. Jewell (July 20, 2007)."Detection of C8H and Comparison with C8H toward IRC +10 216".The Astrophysical Journal.664 (1):L47 –L50.Bibcode:2007ApJ...664L..47R.doi:10.1086/520704.
  2. ^Brünken, S.; H. Gupta; C. A. Gottlieb; M. C. McCarthy; P. Thaddeus (July 20, 2007). "Detection of the Carbon Chain Negative Ion C8H in TMC-1".The Astrophysical Journal.664 (1):L43 –L46.Bibcode:2007ApJ...664L..43B.doi:10.1086/520703.S2CID 120912943.
Molecules
Diatomic








Triatomic
Four
atoms
Five
atoms
Six
atoms
Seven
atoms
Eight
atoms
Nine
atoms
Ten
atoms
or more
Deuterated
molecules
Unconfirmed
Related
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