Nitrate chlorides aremixed anion compounds that contain bothnitrate (NO3−) andchloride (Cl−) ions. Various compounds are known, includingamino acid salts,[1] and also complexes fromiron group,rare-earth, andactinide metals. Complexes are not usually identified as nitrate chlorides, and would be termedchlorido nitrato complexes.
Nitrate chloride compounds may be formed by mixing solutions of chloride and nitrate slats, the addition of nitric acid to a chloride salt solution, or the addition ofhydrochloric acid to a nitrate solution. Most commonly water is used as a solvent, but other solvents such asmethylene dichloride,methanol orethanol can be used.
| name | formula | ratio NO3:Cl | mw | system | space group | unit cell Å | volume | density | optical | references |
|---|---|---|---|---|---|---|---|---|---|---|
| Buttgenbachite | Cu19(NO3)2(OH)32Cl4 · 2H2O | 2:4 | hexagonal | P63/mmc | a = 15.75 Å, c = 9.161 Å Z=1 | 1968 | 4.538 | Blue Uniaxial (+)nω = 1.738nε = 1.752 birefringence: δ = 0.014 | [2][3] | |
| Lislkirchnerite | Pb6Al(OH)8Cl2(NO3)5·2H2O | 5:2 | monoclinic | P21/n | a = 10.7834(6) Å, b = 9.0584(5) Å, c = 13.6178(9) Å β = 102.28(2)° | 1300 | [4] | |||
| Sveite | KAl7(NO3)4(OH)16Cl2 · 8H2O | 4:2 | Monoclinic | a = 10.89 Å, b = 13.04 Å, c = 30.71 Å β = 92.1° | 4,358 | white Biaxial (+)nα = 1.501nβ = 1.503nγ = 1.535 2V: calculated = 30° Max Birefringence = δ = 0.034 | [5] | |||
| Pb8O3(OH)5(NO3)4Cl | 4:1 | Monoclinic | a = 14.831(3) Å, b = 7.659(2) Å, c = 10.186(2) Å β = 108.64(3)° | 1096 | colourless | [6] |
| name | formula | ratio NO3:Cl | mw | system | space group | unit cell Å | volume | density | comment | references |
|---|---|---|---|---|---|---|---|---|---|---|
| Chlorine nitrate | O2NOCl | orthorhombic | P212121 | a = 3.856 b = 6.755 c = 12.07 Z=46 | 314.5 | 2.058 | at −166 °C (related compound) | [7] | ||
| anilinium chloride nitrate | (C6H8N)2ClNO3 | 1:1 | triclinic | P1 | a = 8.418b = 9.648c = 10.036α = 62.993°β = 86.798°γ = 72.999° | [8] | ||||
| o-Phenylenediaminium chloride nitrate | orthorhombic | Pnma | a = 7.3695 b = 8.2367 c = 14.2398 Z=4 | 864.36 | 1.596 | [9] | ||||
| l-lysinium(2+) chloride nitrate | L-Lys2+·Cl−·NO3− | 1:1 | monoclinic | P21 | a 8.8022b 7.0096c 20.2169β 95.226° | [10] | ||||
| L-Lysine L-lysinium dichloride nitrate | 2C6H15N2O2+·H+·NO3−·2Cl− | 1:2 | 428.32 | orthorhombic | P212121 | a 4.9846b 20.604c 20.663 Z=4 | 2122.1 | 1.341 | colourless | [11] |
| L-cysteinium sodium nitrate chloride | 1:1 | monoclinic | P21 | a=18.5, b=5.22, c=7.22 β=103.83° | 678 | transparent from 328 to 1400 nm; SHG 0.51 ×KDP | [12] | |||
| Bis(L-ornithinium) chloride nitrate sulfate | 2C5H14N2O22+·Cl−·NO3−·SO42- | 461.88 | monoclinic | C2 | a 13.872b 9.578c 9.178β 125.35° Z=2 | 994.6 | 1.542 | [13] | ||
| (μ4-octahydroxycucurbit(5)uril)-(μ2-nitrato)-aqua-di-potassium chloride nonahydrate | {[K(H2O)](NO3⊂C30H28N20O20)[K(η2-NO3)]}Cl(H3O)22+·7H2O | monoclinic | P21/c | a 13.8265b 14.2642c 25.143β 92.711° Z=4 | 4953.2 | 1.806 | colourless | [14] | ||
| Thecotrichite | Ca3(CH3COO)3Cl(NO3)2 • 6H2O | 2:1 | monoclinic | P21/c | a 23.5933b 13.8459c 6.8010β 95.195° Z=4 | 2212.57 | anthropogenic, formed on ceramics in damp wooden cupboards; refractive index: nx = 1.491 nz = 1.494stable to 110 °C | [15] | ||
| di-μ-hydroxido-bis[triaqua(nitrato-κ2O,O′)scandium(III)] dichloride | [Sc2(NO3)2(OH)2(H2O)6]Cl2 | 1:1 | 426.95 | triclinic | P1 | a=6.7221 b=7.6279 c=8.5181 α=100.904° β=110.125° γ=102.329° Z=1 | 383.87 | 1.847 | colourless @100K | [16] |
| [Fe(Cl)4](Fe(NO3)2(OPPh2py)2 | [17] | |||||||||
| [Fe(NO3)2(Cl)(OPPh2py)]· CH2Cl2 | monoclinic | P21/n | a 9.138b 15.69c 16.68β 94.50° | [17] | ||||||
| hexamethylphosphoric triamide | Fe(NO3)2(Cl)(HMPA)1.5 | [18] | ||||||||
| hexamethylphosphoric triamide | Fe(NO3)2(Cl)(HMPA)2 | [18] | ||||||||
| hexamethylphosphoric triamide | Fe(NO3)(Cl)2(HMPA)2 | monoclinic | P21/c | a 15.994b 10.172c 16.571β 104.7° | [18] | |||||
| pypn=N,N′-bis(2-pyridylmethyl)-1,3-propanediamine (N,N'-bis((pyridin-2-yl)methyl)propane-1,3-diamine)-dichloro-iron(iii) nitrate | [Fe(pypn)Cl2](NO3) | monoclinic | P21/c | a 11.848b 12.474c 12.301β 94.56° | Cl incis position | [19] | ||||
| pentaamminenitrocobalt(III) chloride nitrate | [Co(NH3)5NO2](NO3)Cl | orthorhombic | Pnam | a 14.814b 9.623c 7.309 | @290K; photosalient (jumps under UV) | [20][21][22] | ||||
| trans-Dichloro-bis(ethylenediamine)-cobalt(III) nitrate | [Co en2Cl2]NO3 | monoclinic | P21/n | a = 6.348b = 9.304c = 9.853β = 101.79° | 569.6 | 1.82 | green | [23][24] | ||
| cis-Chloro(ammine)bis(ethylenediamine)cobalt dinitrate | [Co(en)2(NH3)Cl](NO3)2 | [25] | ||||||||
| trans-Chloro(ammine)bis(ethylenediamine)cobalt dinitrate | [Co(en)2(NH3)Cl](NO3)2 | [25] | ||||||||
| 5-nitrosalicyliddineaminato tetraamino cobalt dichloride nitrate | orange | [26] | ||||||||
| cis-Chlorobis(ethylenediamine)dodecylaminecobalt(III) nitrate | cis-[Co(en)2(C12H25NH2)Cl](NO3)2 | [27] | ||||||||
| bis(1,4,7-triazacyclononane) nickel(ii) nitrate chloride monohydrate | [Ni([9]aneN3)2](NO3)Cl·H2O | orthorhombic | Pna21 | a 17.584b 8.860c 12.141 | [28] | |||||
| Bis[chlorobis(1,10-phenanthroline-N,N')(thiourea-S)nickel(II)] chloride nitrate diethanol solvate | [NiCl(C12H8N2)2(CH4N2S)]2(NO3)Cl·2C2H6O | orthorhombic | Fdd2 | a 22.813b 29.024c 17.113 Z=8 | 11331 | 1.467 | blue | [29] | ||
| Cucurbit[8]uril (1-n-butyl-4,4'-bipyridin-1-ium 1-n-butyl-4,4'-bipyridin-1-ium-penta-aqua-nickel(ii)) clathrate chloride trinitrate undecahydrate | {[C14H17N2Ni(H2O)5]2⊂C48H48N32O16}[(C14H17N2)2⊂C48H48N32O16]Cl2(NO3)6·22H2O | triclinic | P1 | a 16.671b 16.678c 20.442α 112.772°β 101.844°γ 90.102° | [30] | |||||
| bis(bis(1,4,7-triazacyclonon-1-yl)pentane)-di-nickel(ii) trichloride nitrate pentadecahydrate | [Ni2(EM5)2]Cl3NO3·15H2O | orthorhombic | Pbcn | a 28.030b 17.469c 12.289 | [31] | |||||
| bis(bis(1,4,7-triazacyclonon-1-yl)hexane)-di-nickel(ii) dichloride dinitrate hexahydrate | [Ni2(EM6)2]Cl3(NO3)2·6H2O | triclinic | P1 | a 9.529b 9.566c 14.684α 81.08°β 78.84°γ 88.82° | [31] | |||||
| dapsc = 2,6-diacetylpyridine-bis(semicarbazone)) | [Ni(dapsc)(H2O)2]Cl(NO3)·H2O | triclinic | P1 | a=6.9130 b=12.3410α=114.8010β=93.946γ=103.7760 Z=2 | 933.10 | 1.735 | green | [32] | ||
| hexakis(1H-imidazole)-nickel(ii) chloride nitrate tetrahydrate | [Ni(Im)6][(NO3)Cl(H2O)4] | hexagonal | P63m | a 9.003c 21.034 | [33] | |||||
| bis(M-2-chloro)-(nitrato-o)-(2,2 '-bipyridine-N.N ')-copper(II) | Cu(2,2'-BP)Cl NO3 | triclinic | P1 | a = 7.515 b = 9.253 c = 10.283α=112.181°β= 102.155°γ= 105.617° Z=2 | 597.4 | 1.769 | green; dimer | [34] | ||
| bis(M-2-chloro)-(nitrato-o)-(2,2 '-4,4'-dimethylbipyridine-N.N ')-copper(II) | Cu(2,2'-dmBP)ClNO3 | dimer | [34] | |||||||
| Chloro(1,10-phenanthroline-2-carboxamide oxime)copper(II) Nitrate | [35] | |||||||||
| bis(μ2-2,4,4,6,6-pentakis(2-pyridyloxy)cyclo-2,4,6-triphosphazene 2-oxide)-dichloro-nitrato-cobalt(ii)-di-copper chloride | [{(N3P3(OC5H4N)5(O)CuCl)2Co(NO3)}Cl] | orthorhombic | Fddd | a =22.639b =28.202c =45.260 | [36] | |||||
| Copper(II)–sparteine nitrate chloride | CuII{(−)Sp}(NO3)Cl | orthorhombic | P212121 | a 16.370b 13.334c 7.6803 | [37] | |||||
| Cucurbit[8]uril (1-n-butyl-4,4'-bipyridin-1-ium 1-n-butyl-4,4'-bipyridin-1-ium-penta-aqua-copper(ii)) clathrate dichloride dinitrate hexadecahydrate | {[C14H17N2Cu(H2O)5]2⊂C48H48N32O16}[(C14H17N2)2⊂C48H48N32O16]Cl4(NO3)4·32H2O | triclinic | P1 | a 16.607b 17.093c 20.509α 66.003°β 77.568°γ 89.155° | [30] | |||||
| copper(II)-di-2-pyridylamine complex chloride nitrate (μ2-Chloro)-(nitrato-O)-(bis(2-pyridyl)amine-N,N')-copper(ii) hemihydrate | [Cu(dipyam)Cl(NO3)].0.5H2O | monoclinic | P21/a | a 7.382b 21.494c 8.032β 94.26 | [38] | |||||
| tipa=tri(4-imidazolylphenyl)amine (μ3-tris(4-(Imidazol-1-yl)phenyl)amine)-chloro-zinc nitrate dimethylformamide solvate | [Zn(tipa)Cl]•NO3•2 DMF | orthorhombic | Pnna | a=28.470b=27.784c=9.255 | 7321 | 1.044 | [39] | |||
| Na3Rb6(CO3)3(NO3)2Cl·(H2O)6 | 2:1 | 1029.39 | hexagonal | P63/mcm | a = 9.5732c = 15.820 Z=2 | 1255.6 | 2.723 | UV cut off 231 nm; uniaxial; birefringence 0.14 @ 546 nm | [40] | |
| KRb2(NO3)2Cl | 2:1 | 369.51 | orthorhombic | pbam | a=12.1863 b=12.4072 c=5.8203 Z=4 | 880.02 | 2.789 | transparent; birefringence = 0.084 at 1064 nm | [41] | |
| [Ru(NH3)5Cl](NO3)2 | tetragonal | I4 | a = 7.5811b = 7.5811c = 10.535 | 605.5 | 1.896 | yellow | [42] | |||
| [RuNO(NH3)3(H2O)Cl](NO3)2 | monoclinic | Cc | a = 13.7924b = 6.9114c = 12.3577 β = 111.863°Z = 4 | 1093.27 | 2.185 | [43] | ||||
| bis((μ2-chloro)-(nitrato)-(η5-pentamethylcyclopentadienyl)-rhodium(iii)) | [Cp*Rh(η1-NO3)(μ-Cl)]2 | monoclinic | P21/n | a 8.3874b 10.4549c 14.8585β 104.385° | [44] | |||||
| chloro-(cyclohexylisocyano)-(η5-pentamethylcyclopentadienyl)-(triphenylphosphine)-rhodium nitrite nitrate dihydrate | {[Cp*RhCl(PPh3)(CNC6H11)]2(NO2)(NO3)}·2H2O | triclinic | P1 | a 10.319b 10.5582c 17.371α 97.011°β 94.35°γ 112.154° | [44] | |||||
| [Rh(NH3)5Cl](NO3)2 | tetragonal | I4 | a = 7.5858b = 7.5858c = 10.41357 Z=2 | 599.24 | 1.926 | yellow | [42] | |||
| bis(μ2-4'-(4-pyridyl)-2,2':6',2''-terpyridine)-bis(η5-pentamethylcyclopentadienyl)-tetra-chloro-di-rhodium-nickel dinitrate methanol solvate dihydrate | {Cp*2Rh2[Ni(pyterpy)2]Cl4}(NO3)2 | monoclinic | C2/c | a 53.4454b 8.8419c 33.7700β 112.029° | [45] | |||||
| cis-dichlorobis(ethylenediamine)rhodium(III) nitrate | [Rh(en)2Cl2]NO3 | triclinic | P1 | a=8.619 b=6.528 c=11.687α=I02.18β=90.98γ=112.46 Z=2 | 590.5 | 2.00 | yellow | [46] | ||
| trans-dichlorobis(ethylenediamine)rhodium(III) nitrate | [Rh(en)2Cl2]NO3 | monoclinic | P21/n | a = 6.441 b=9.281 c=10.010β=102.42 Z=2 | 584.4 | 2.02 | orange | [46] | ||
| L=3,6,9,16,19,22-hexaazatricyclo[22.2.2.211,14]triacon-11,13,24,26(1),2 7,29-hexaene (μ2-3,6,9,16,19,22-Hexa-azatricyclo(22.2.2.211,14)triaconta-1(26),11,13,24,27,29-hexaene)-dichloro-di-palladium(ii) dinitrate monohydrate | [Pd2LCl2](NO3)2·H2O | monoclinic | P2/c | a 21.744b 9.243c 16.259β 93.580° | [47] | |||||
| en=Ethylenediamine py=pyridine | [Pd(en)(py)Cl]NO3 | monoclinic | P21/c | a = 7.990,b = 16.058,c = 9.846β = 103.81°Z = 4 | [48] | |||||
| 4-Methylpyridine, | [Pd(en)(4-Me-py)Cl]NO3 | [48] | ||||||||
| 4-hydroxy-pyridine | [Pd(en)(4-OH-py)Cl]NO3 | [48] | ||||||||
| 4-NH2-py=4-aminopyridine | [Pd(en)(4-NH2-py)Cl]NO3 | [48] | ||||||||
| tetrakis(μ-tris((diphenylphosphino)methyl)amine)-tetrachloro-pentadeca-silver tris(nitrate) octahydrate | [Ag15(N-triphos)4(Cl4)](NO3)3 | 3649.32 | orthorhombic | C2221 | a 18.702b 36.975c 28.652 Z=6 | 19813 | 1.835 | [49] | ||
| bis(tetrakis(Triphenylphosphine)-silver) chloro-diphenyl-bis(nitrato-O,O')-tin diphenyl-tris(nitrato-O,O')-tin | [Ag(PPh3)4][SnPh2(NO3)2(Cl,NO3)] | triclinic | P1 | a 22.43b 14.13c 13.96α 90.59°β 69.82°γ 64.58° | [50] | |||||
| barium chloride nitrate | Ba(NO3)Cl | orthorhombic | Pnma | a 8.9108b 5.2991c 8.3414 | UV cutoff 213 nm; birefringence 0.009 @ 1064 nm | [51] | ||||
| LSS=trans-N,N′-bis(salicylidene)-(1S,2S)-cyclohexanediamine | [La(H2LSS)(NO3)2Cl]·2CH2Cl2 | tetragonal | P43212 | a = 18.1798c = 16.4174 Z=4 | 5426.0 | 1.150 | [52] | |||
| tris(μ2-N',N''-((5-Chloro-2-oxy-1,3-phenylene)dimethylylidene)bis(benzohydrazide))-bis(ethanol)-di-lanthanum dinitrate chloride acetone solvate dihydrate | [La2(H2L1)3(C2H5OH)2]·(Cl)·(NO3)2·((CH3)2CO)2·(H2O)2 | monoclinic | C2/c | a 21.1020b 18.5070c 23.1880β 114.452° | [53] | |||||
| LSS=trans-N,N′-bis(salicylidene)-(1S,2S)-cyclohexanediamine | [Ce(H2LSS)(NO3)2Cl]·2CH2Cl2 | tetragonal | P43212 | a = 18.216c = 16.483 Z=4 | 5469.6 | 1.147 | [52] | |||
| Chloro-nitrato-pentakis(tetrahydrofuran)-cerium(iii) pentachloro-(tetrahydrofuran)-cerium(iv) | [CeCl(NO3)(THF)5]+[CeCl5(THF)]− | monoclinic | P2/c | a 12.138b 11.299c 14.066β 104.31° | [54] | |||||
| Praseodymium dichloride nitrate pentahydrate | [PrCl2(H2O)6][PrCl2(NO3)2(H2O)4] | monoclinic | P2/c | a = 12.288 b = 6.484 c = 12.660 β = 91.91° Z = 4 | green | [55] | ||||
| L=N,N′‐bis (salicylidene)‐1,2‐cyclohexanediamine | [Pr(H2L)2(NO3)2Cl]·2CH2Cl2 | 941.14 | tetragonal | P43212 | a=18.0936 c=16.3490 Z=4 | 5352.3 | 1.168 | [56] | ||
| LSS=trans-N,N′-bis(salicylidene)-(1S,2S)-cyclohexanediamine | [Nd(H2LSS)(NO3)2Cl]·2CH2Cl2 | tetragonal | P43212 | a = 18.1041c = 16.4374 Z=4 | 5387.5 | 1.164 | [52] | |||
| Chloro-bis(nitrato-O,O')-bis(tetramethyl (t-butyl(hydroxy)methylene)-bis(phosphonate)-O,O')-neodymium(iii) | NdCl(NO3)2{[(MeO)2PO]2C(OH)tBu}2 | monoclinic | P21/a | a 17.0961b 9.3040c 24.4989β 110.244° | [57] | |||||
| tri-sodium hexakis(μ-oxo)-tetraoctacontakis(μ-hydroxo)-triacontakis(μ-2-thiophenecarboxylato)-tetrakis(2-thiophenecarboxylato)-decakis(μ-glycinato)-diglycine-docosa-aqua-octatetraconta-europium(iii) nitrate hexachloride 2-thiophenecarboxylic acid pentahydrate | Na3[Eu48O6(OH)84(tca)34(gly)12(H2O)22]·2Htca·6Cl·6H2O·NO3 | 15118.80 | triclinic | P1 | a 20.720b 23.227c 24.562α 88.66°β 71.76°γ 63.57° Z=1 | 9960 | 2.500 | [58] | ||
| sodium tetradecakis(μ-3-hydroxy-2-(hydroxymethyl)-2-methylpropanoato)-hexakis(μ-oxo)-tetraoctacontakis(μ-hydroxo)-octadecakis(μ-2-thiophenecarboxylato)-octakis(2-thiophenecarboxylato)-tetracosa-aqua-octatetraconta-terbium(iii) nitrate octakis(chloride) | Na[Tb48O6(OH)84(fca)26(dmp)14(H2O)24]·4Hfca·NO3·8Cl | 15154.02 | monoclinic | P21/n | a 24.0145b 32.9221c 25.6605β 97.521° Z=2 | 20112.9 | 2.490 | [58] | ||
| L=2-methyl-8-hydroxyquinoline tetrakis(μ-2-methylquinolin-8-olato)-(μ-chloro)-ethanol-dinitrato-di-nickel(ii)-dysprosium(iii) acetonitrile solvate | [Ni2IIDyIII(EtOH)(L2)4(NO3)2Cl] ⋅ CH3CN | triclinic | P1 | a 11.1201b 14.1566c 15.448α 78.625°β 73.918°γ 81.055° | [59] | |||||
| (tetrakis(μ-(1-phenylethyl)ammoniomethylphosphonato)-chloro-nitrato-di-erbium | R- orS-[Er2(pempH)4(NO3)Cl] | orthorhombic | P21212 | a 15.986b 32.069c 9.1593 | quadruple stranded helix | [60] | ||||
| [{trans-PtCl(NH3)2}{μ-(H2N(CH2)6NH2)}{trans-PdCl(NH3)2](NO3)Cl | yellow | [61] | ||||||||
| [{trans-PtCl(NH3)2}2{trans-Pt(thiazole)2}{H2N(CH2)6NH2}2]Cl3(NO3) | [62] | |||||||||
| [PtPy2(NH=CH-OH)Cl3]NO3 | orthorhombic | P212121 | a = 10.381b = 11.776c = 13.848Z = 4 | 1692.9 | [63] | |||||
| alpha pyridone | cis-[Pt(NH3)2(C5H4NOH)Cl](NO3) | triclinic | P1 | a=10.706 b=12.552 c=4.151α =95.57°β=92.32°γ=99.05° Z=2 | 547.4 | 2.558 | white needles | [64] | ||
| [PtIV(trans-1R,2R-diaminocyclohexane)trans-(acetate)2(9-ethylguanine)Cl]NO3 · H2O | P21 | a = 10.446b = 22.906c = 10.978Z = 4 | [65] | |||||||
| Chloro-(homopiperazine)-(diphenylsulfido)-platinum(ii) nitrate | [PtII(homopiperazine)(diphenylsulfide)Cl]NO3 | monoclinic | P21/c | a 17.666b 8.812c 12.619β 101.02° | [66] | |||||
| mmap=1-methyl-4-(methylamino)piperidine | [Pt(mmap)(CH3)2S)Cl](NO3) | white | [67] | |||||||
| dhq=decahydroquinoline | [Pt(dhq)(CH3)2S)Cl](NO3) | [67] | ||||||||
| [La(NO3)2(H2O)6]2[PtCl6]·2H2O | monoclinic | P21/c | a = 6.974b = 16.545c = 13.177β = 93.97° Z=2 | yellow | [68] | |||||
| [Pr(NO3)2(H2O)6]2[PtCl6]·2H2O | monoclinic | P21/c | a = 6.955b = 16.525,c = 13.18.5β = 93.93° Z=2 | yellow | [68] | |||||
| [Gd(NO3)(H2O)7][PtCl6]·4H2O | monoclinic | P21/n | a = 8.3872b = 21.3198c = 11.4263β = 95.670° Z=4 | yellow | [68] | |||||
| [Dy(NO3)(H2O)7][PtCl6]·4H2O | monoclinic | P21/n | a = 8.3840b = 21.3950c = 11.4310β = 95.698° Z=4 | yellow | [68] | |||||
| Ir[NO3]2Cl[NH3]5 | tetragonal | I4 | a = 7.6061c = 10.4039 | 601.89 | 2.410 | yellow | [42] | |||
| {Cp*2Ir2[Ni(pyterpy)2]Cl4}(NO3)2 | [45] | |||||||||
| Dichloro(ethylenediamine)gold(III) nitrate | [Au(NH2CH2CH2NH2)Cl2]NO3 | orthorhombic | Pbca | a = 10.338b = 8.2105c = 19.625 Z=8 | [69] | |||||
| (2,2'-Bipyridine)dichlorogold(III) nitrate | [AuCl2(C10H8N2)]NO3 | 486.06 | monoclinic | C2/c | a 6.9240b 14.0460c 13.0560β 96.562° Z=4 | 1261.44 | 2.559 | pale yellow | [70] | |
| Bis(methy1 L-cysteineato)mercury(II) hydrochloride hydronitrate monohydrate | (C4H9NO2S)2ClHgNO3•H2O | [71] | ||||||||
| chloronitrato-2-{2′-[(1′-methyl)benzimidazolyl]}- 4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxidemercury(II) – mercury(II)chloride | HgCl(NO3)(C15H19N4O2) · HgCl2 | triclinic | P1 | a=9.922 b=10.822 c=11.460α=107.518°β=102.046°γ=96.639° Z=2 | 1126.5 | black | [72] | |||
| caesium mercuric nitrate chloride | CsHgNO3Cl2 | 1:2 | 466.41 | hexagonal | P63/mmc | a=5.8817 c=11.3920 Z=2 | 341.30 | 4.538 | birefringent Δn = 0.145@546 nm | [73] |
| 4-chloropyridinium | (C5H5NCl)2[UO2Cl3(NO3)] | 1:3 | triclinic | P1 | a=6.819b=10.781c=14.252α=72.890°β=80.394°γ=74.456° Z=2 | 960.3 | 2.308 | [74] | ||
| 4-bromopyridinium | (C5H5NBr)2[UO2Cl3(NO3)] | 1:3 | 756.41 | monoclinic | P21/m | a =9.739b =16.484c =12.950β =102.360° Z=4 | 2030.8 | 2.474 | [74] | |
| 4-iodopyridinium | (C5H5NI)3[UO2Cl3(NO3)](NO3) | 2:3 | 559.20*2 | monoclinic | P21/c | a =7.9797b =25.043c =14.730β =103.019° Z=4 | 2868.0 | 2.590 | [74] | |
| pyr2phen =N,N′-bis-(pyridoxylideneiminato)2−phenylene (N-(3-Hydroxy-5-(hydroxymethyl)-2-methylpyridin-4-ylmethylidene)-N'-(5-(hydroxymethyl)-2-methyl-3-oxypyridin-4-ylmethylidene)-o-phenylenediamine-N,N',O,O')-chloro-dioxo-uranium nitrate dihydrate | [UO2(H2pyr2phen)Cl]NO3 | triclinic | P1 | a 9.231b 11.855c 14.026α 114.8°β 94.012°γ 97.95° | [75] | |||||
| K3[(UO2)(NO3)Cl3](NO3) | monoclinic | P21 | a 7.8596b 15.8675c 10.6823β 90.141° Z=4 | 1332.21 | 3.08 | [76] | ||||
| Cs2(UO2)(NO3)Cl3 | 1:3 | 704.21 | monoclinic | P21/n | a=10.375 b=9.468 c=12.553 β= 110.280 Z=4 | 1156.7 | 4.04 | lemon yellow | [77] | |
| bis(4-iodo-pyridinium) dinitrato-tetrachloro-plutonium(iv) | (C5H5NI)2[Pu(IV)Cl4(NO3)2] | triclinic | P1 | a =9.8096 b=10.1402 c=11.5033 73.416 82.364 87.100 Z=2 | 1086.8 | 2.811 | orange | [78] | ||
| bis(pyridinium) trinitrato-trichloro-plutonium(iv) | (C5H6N)2[Pu(IV)Cl3(NO3)3] | 694.60 | monoclinic | P21/c | a 17.268b 7.7622c 15.112β 97.598° Z=4 | 2007.8 | 2.298 | dark red | [78] | |
| bis(4-chloro-pyridinium) dioxo-trichloro-nitrato-plutonium(vi) | (C5H5NCl)2[Pu(VI)O2Cl3(NO3)] | 671.46 | triclinic | P1 | a 6.7493b 10.8107c 14.171α 73.657°β 81.412°γ 75.206° Z=2 | 956.0 | 2.333 | yellow | [78] |
{{cite journal}}: CS1 maint: DOI inactive as of July 2025 (link)