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Microcosmic salt

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Chemical compound found in urine
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Microcosmic salt[1]
Names
IUPAC name
Ammonium sodium phosphate
Other names
Microcosmic salt, ammonium sodium hydrogen phosphate or phosphorsalz
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.128.899Edit this at Wikidata
EC Number
  • 250-787-1
UNII
  • InChI=1S/H3N.Na.H3O4P/c;;1-5(2,3)4/h1H3;;(H3,1,2,3,4)/q;+1;/p-1 ☒N
    Key: CUXQLKLUPGTTKL-UHFFFAOYSA-M ☒N
  • InChI=1/H3N.Na.H3O4P/c;;1-5(2,3)4/h1H3;;(H3,1,2,3,4)/q;+1;/p-1
    Key: CUXQLKLUPGTTKL-REWHXWOFAM
  • [NH4+].OP(=O)([O-])[O-].[Na+]
Properties
Na(NH4)HPO4
Molar mass137.0077 g/mol
Appearanceodorless crystals
Density1.544 g/cm3
Melting point80 °C (176 °F; 353 K)
5 parts cold, 1 part boiling water. Practically insoluble inethanol
Structure
Monoclinic
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound

Microcosmic salt (see infobox for systematic names) is a salt found inurine with the formula Na(NH4)HPO4. It is left behind in the residues after extracting theurea from driedurine crystals with alcohol. In the mineral form, microcosmic salt is calledstercorite.

Its name was coined in Latin (sal microcosmicum) byParacelsus in the 16th century, but it was also referenced byPseudo-Geber in the late Middle Ages; another alchemical name for it wassal urinae fixum (as opposed tosal urinae volatile).[2] The first extraction of purephosphorus came from this salt in the 17th century, whenHennig Brandt attempted to extractgold from urine.

Microcosmic salt is used in the laboratory as an essential ingredient of themicrocosmic salt bead test for identification of metallic radicals on the basis of the color they produce inoxidizing or reducing flame, in hot or cold conditions.

Microcosmic salts form atetrahydrate.

References

[edit]
  1. ^"572. Ammonium Sodium Phosphate".The Merck Index (10th ed.). Merck and Co. Inc. 1983. pp. 80.ISBN 0-911910-27-1.
  2. ^Mellor, Joseph William (1922).Supplement to Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry: suppl. 3. K, Rb, Cs, Fr. Longmans, Green and Company.
Ammonium salts
Inorganic salts
monatomic anions
oxyanions
other anions
Organic salts
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