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Masakatsu Shibasaki

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Japanese chemist
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Masakatsu Shibasaki
Born(1947-01-25)25 January 1947
Saitama, Japan
Alma materUniversity of Tokyo
Known forShibasaki catalysts,Binol, enantioselectiveheterobimetallic catalysis
AwardsAmerican Chemical Society Award for Creative Work in Synthetic Organic Chemistry (2008)
Scientific career
FieldsChemistry
InstitutionsMicrobial Chemistry Research Center
Doctoral advisorShun’ichi Yamada

Masakatsu Shibasaki (柴崎 正勝,Shibasaki Masakatsu; born 25 January 1947) is aJapanesechemist. In 1974 he earned hisdoctorate inchemistry, in the group of Shun’ichi Yamada. He did a post doc withElias J. Corey atHarvard. He returned to Japan and became a professor in 1977 atTeikyō University and moved toHokkaidō University in 1986. 1983–1986 Shibasaki was a research group leader at theSagami chemical research center. From 1991 until 2010 he served as professor atTokyo University. Since 2010 he is representative director of Microbial Chemistry Research Foundation (Chemistry), Tokyo. He is perhaps best known for developing a range ofbinol based heterobimetallic catalysts, which nowbear his name.

Selected publications

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  • Organic Synthesis Directed Toward Life Science, (Japanese), Kodansha, 1985.
  • Organic Chemistry for Graduate Students, (Japanese), Tokyo Kagaku Dojin, 1998.
  • Asymmetric Reaction for the Basis of Medicinal Chemistry, (Japanese, Hirokawa Shoten
  • Stimulating Concepts in Chemistry, (English), VCH Verlagsgesellschaft mbH, 2000.
  • Multimetallic Catalysts In Organic Synthesis, (English), John Wiley & Sons Inc., 2004.
  • New Development of Organocatalyst, (Japanese), CMC publishing Co., Ltd., 2006.
  • Shibasaki M, Yoshikawa N:Lanthanide complexes in multifunctional asymmetric catalysis,Chemical Reviews102 (2002) 2187–2209.
  • Sasai H, Suzuki T, Arai S, Arai T, Shibasaki M:Basic Character of Rare-Earth-Metal Alkoxides – Utilization in Catalytic C-C Bond-Forming Reactions and Catalytic Asymmetric Nitroaldol Reactions,Journal of the American Chemical Society114 (1992) 4418–4420.
  • Yoshikawa N, Yamada YMA, Das J, Sasai H, Shibasaki M:Direct catalytic asymmetric aldol reaction, Journal of the American Chemical Society121 (1999) 4168–4178.
  • Yamada YMA, Yoshikawa N, Sasai H, Shibasaki M:Direct catalytic asymmetric aldol reactions of aldehydes with unmodified ketones,Angewandte Chemie International Edition in English36 (1997) 1871–1873.
  • Sasai H, Arai T, Satow Y, Houk KN, Shibasaki M:The first Heterobimetallic Multifunctional Asymmetric Catalyst, Journal of the American Chemical Society117 (1995) 6194–6198.
  • Shibasaki M, Boden CDJ, Kojima A:The asymmetric Heck reaction,Tetrahedron53 (1997) 7371–7395.
  • Gröger H, Vogl EM, Shibasaki M:New catalytic concepts for the asymmetric aldol reaction,Chemistry – a European Journal4 (1998) 1137–1141.
  • Hamashima Y, Sawada D, Kanai M, Shibasaki M:A new bifunctional asymmetric catalysis: An efficient catalytic asymmetric cyanosilylation of aldehydes, Journal of the American Chemical Society121 (1999) 2641–2642.
  • Bougauchi M, Watanabe S, Arai T, Sasai H, Shibasaki M:Catalytic asymmetric epoxidation of alpha,beta-unsaturated ketones promoted by lanthanoid complexes, Journal of the American Chemical Society119 (1997) 2329–2330.
  • Arai T, Sasai H, Aoe K, Okamura K, Date T, Shibasaki M:A new multifunctional heterobimetallic asymmetric catalyst for Michael additions and tandem Michael-Aldol reactions, Angewandte Chemie-International Edition in English35 (1996) 104–106.

His research interests are focussed on the development of new synthetic methods, the design of biologically significant compounds and synthetic studies of such compounds.

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