Movatterモバイル変換


[0]ホーム

URL:


Jump to content
WikipediaThe Free Encyclopedia
Search

Magnesium chromate

From Wikipedia, the free encyclopedia
Magnesium chromate
Names
Other names
Magnesium chromate(VI)
Magnesium monochromate
Magnesium monochromate(VI)
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.033.204Edit this at Wikidata
  • InChI=1S/Cr.Mg.4O/q;+2;;;2*-1
    Key: CRGGPIWCSGOBDN-UHFFFAOYSA-N
  • InChI=1/Cr.Mg.4O/q;+2;;;2*-1/rCrO4.Mg/c2-1(3,4)5;/q-2;+2
    Key: CRGGPIWCSGOBDN-OVNOGNLDAB
  • [O-][Cr](=O)(=O)[O-].[Mg+2]
Properties
MgCrO4
Molar mass140.297 g·mol−1
AppearanceYellow solid
soluble
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Magnesium chromate is a chemical compound, with the formulaMgCrO4. It is a yellow, odorless, water-soluble salt with several important industrial uses. This chromate can be manufactured as a powder.

History

[edit]

Before 1940, the literature about magnesium chromate and its hydrates was sparse, but studies starting in that year looked at its properties and solubility.[1]

Uses

[edit]

It is available commercially in a variety of powders, fromnanoscale tomicron-sized, either as ananhydrous orhydrated form.[2][3]

As a hydrate, it is useful as a corrosion inhibitor and pigment,[4] or as an ingredient incosmetics.[5][dubiousdiscuss]In 2011, an undecahydrate (containing 11 molecules of water) of this compound was discovered by scientists at theUniversity College London.[6]

Hazards

[edit]

Magnesium chromate hydrate should be stored atroom temperature, and there is no current therapeutic use.[7] It is a confirmedcarcinogen, and can cause acutedermatitis, and possibly kidney and liver damage if inhaled, so it should be treated as ahazardous waste.[8]

References

[edit]
  1. ^Hill, Arthur E.; Soth, Glenn C.; Ricci, John E. (1940). "The Systems Magnesium Chromate—Water and Ammonium Chromate—Water from 0 to 75 °C".Journal of the American Chemical Society.62 (8): 2131.Bibcode:1940JAChS..62.2131H.doi:10.1021/ja01865a059.
  2. ^"Magnesium Chromate".American Elements. Archived fromthe original on 2013-07-22. Retrieved2013-07-16.
  3. ^Li, Su Ping; Jia, Xiao Lin; Qi, Ya Fang (2011). "Synthesis of Nano-Crystalline Magnesium Chromate Spinel by Citrate Sol-Gel Method".Advanced Materials Research.284–286: 730.doi:10.4028/www.scientific.net/AMR.284-286.730.S2CID 137408833.
  4. ^"Magnesium chromate hydrate, 99.8% (metals basis)". Us.vwr.com. Retrieved2013-07-16.
  5. ^"Item # MG-401, Heavy Magnesium Chromate Powder On Atlantic Equipment Engineers, A Division Of Micron Metals, Inc". Metal-powders-compounds.micronmetals.com. Retrieved2013-07-16.
  6. ^Fortes, A. Dominic; Wood, Ian G. (March 2012). "X-ray powder diffraction analysis of a new magnesium chromate hydrate, MgCrO4·11H2O".Powder Diffraction.27 (1):8–11.Bibcode:2012PDiff..27....8F.doi:10.1017/S088571561200005X.S2CID 101802113.
  7. ^"Magnesium chromate hydrate | CAS 23371-94-0 | Santa Cruz Biotech". Santa Cruz Biotechnology, Inc. Retrieved2013-07-16.
  8. ^"Material Data Sheet"(PDF).McGean-Rohco, Inc. Archived fromthe original(PDF) on 2013-07-09. Retrieved2013-07-16.
Chromates
Chlorochromates
Chromate esters
Dichromates
Other chromates
Related
Retrieved from "https://en.wikipedia.org/w/index.php?title=Magnesium_chromate&oldid=1315558324"
Categories:
Hidden categories:

[8]ページ先頭

©2009-2025 Movatter.jp