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Lithium hypofluorite

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Lithium hypofluorite
Names
Preferred IUPAC name
Lithium hypofluorite
Other names
Lithium fluoride oxide, lithium oxyfluoride
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/FO.Li/c1-2;/q-1;+1
    Key: WYWLSUBVZXKJGO-UHFFFAOYSA-N
  • [Li+].[O-]F
Properties
LiOF
Molar mass41.94 g·mol−1
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Lithium hypofluorite is aninorganic compound with thechemical formula ofLiOF. It is a compound oflithium,fluorine, andoxygen.[1][2][3] This is a lithiumsalt ofhypofluorous acid,[4] and contains lithiumcationsLi+ and hypofluoriteanionsOF.[dubiousdiscuss]

Synthesis

[edit]

The salt theoretically results from theneutralization ofhypofluorous acid (HOF) andlithium hydroxide (LiOH). It can be formed by the action of fluorine on lithium hydroxide:

HOF + LiOH → LiOF + H2O

Chemical properties

[edit]

The compound is quite unstable, since it contains oxygen in the oxidation state of 0. It, therefore, tends to decompose tolithium fluoride and oxygen gas:

2 LiOF → 2 LiF + O2

References

[edit]
  1. ^Science Data Booklet. Manjunath.R. 11 July 2020. p. 146. Retrieved12 May 2023.
  2. ^Barin, Ihsan (1995).Thermochemical Data of Pure Substances: La-Zr. VCH. p. 965.ISBN 978-3-527-28745-1. Retrieved12 May 2023.
  3. ^Binnewies, M.; Milke, E. (3 December 2002).Thermochemical Data of Elements and Compounds. Wiley. p. 466.ISBN 978-3-527-30524-7. Retrieved12 May 2023.
  4. ^"NIST-JANAF Themochemical Tables, Fourth Edition".NIST. 1998. pp. 1–1951. Retrieved12 May 2023.
Inorganic (list)
Organic (soaps)
Minerals
Hypothetical
Other Li-related
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