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Lithium hexafluoroantimonate

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Lithium hexafluoroantimonate
Names

IUPAC name lithium;hexafluoroantimony(1-)
Other names Lithium hexafluoroantimonate(V)
Identifiers
CAS Number	18424-17-4
3D model (JSmol)	Interactive image
ChemSpider	16700586
ECHA InfoCard	100.196.093
EC Number	670-363-3
PubChem CID	16700586
CompTox Dashboard(EPA)	DTXSID00587189
InChI InChI=1S/6FH.Li.Sb/h6*1H;;/q;;;;;;+1;+5/p-6 Key: YVBBFYDVCPCHHG-UHFFFAOYSA-H
SMILES [Li+].F[Sb-](F)(F)(F)(F)F
Properties
Chemical formula	NaSbF₆
Appearance	White to off-white powder
Solubility in water	soluble
Hazards
GHS labelling:
Pictograms
Signal word	Warning
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa). Infobox references

Chemical compound

Lithium hexafluoroantimonate is an inorganicchemical compound with the chemical formulaLiSbF₆.^[1]^[2]^[3]

Physical properties

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The compound crystallizes in the rhombohedral space groupR3 with the lattice constants a = 5.43 Å, α = 56° 58', Z = 1. The structure corresponds to that of rhombohedral distortedNaSbF₆ type.^[4]^[5]

References

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^"Lithium hexafluoroantimonate(V)".Sigma Aldrich. Retrieved1 July 2024.
^Haynes, William M. (9 June 2015).CRC Handbook of Chemistry and Physics, 96th Edition.CRC Press. p. 4-72.ISBN 978-1-4822-6097-7. Retrieved1 July 2024.
^Manthiram, Arumugam (March 2009).Rechargeable Lithium and Lithium Ion Batteries. The Electrochemical Society. p. 157.ISBN 978-1-56677-704-9. Retrieved1 July 2024.
^Burns, J. H. (10 November 1962)."The crystal structure of lithium fluoroantimonate(V)".Acta Crystallographica.15 (11):1098–1101.doi:10.1107/S0365110X62002935.ISSN 0365-110X. Retrieved1 July 2024.
^Donnay, Joseph Désiré Hubert (1978).Crystal Data: Inorganic compounds 1967-1969. National Bureau of Standards. p. H/R-188. Retrieved1 July 2024.

v t e Lithium compounds (list)
Compounds withnoble gases	LiHe HLiHe⁺ (hypothetical) LiFHeO(hypothetical) LiHe₂ (hypothetical) (HeO)(LiF)₂ (hypothetical) La_2/3−xLi_3xTiO₃He (hypothetical)
Compounds withhalogens	FLiBe FLiNaK LiAt (hypothetical) LiBr LiBrO LiBrO₂ LiBrO₃ LiBrO₄ LiCl LiClO LiClO₂ LiClO₃ LiClO₄ LiF Li₂F LiFO LiI LiIO LiIO₂ LiIO₃ LiIO₄
Oxides andhydroxides	LiO⁻ LiO₂ LiO₃ Li₂O Li₂O₂ LiOH
Compounds withchalcogens	LiCF₃SO₃ LiHSO₃ LiHSO₄ Li₂Po Li₂S Li₂Se Li₂SeO₃ Li₂SeO₄ Li₂Te LiTe₃ Li₂TeO₃ Li₂TeO₄
Compounds withpnictogens	Li_1+xAl_xGe_2−x(PO₄)₃ LiAl_1+xTi_2−x(PO₄)₃ LiAs LiAsF₆ Li₃AsO₄ LiFePO₄ LiGe₂(PO₄)₃ LiH₂AsO₄ Li₂HAsO₄ Li₂HPO₃ Li₂HPO₄ Li₃PO₃ Li₃PO₄ LiH₂PO₃ LiH₂PO₄ LiN₃ Li₃N LiNH₂ Li₂NH LiNO₂ LiNO₃ Li₂N₂O₂ Li₂NaPO₃ LiNaNO₂ Li₃P LiPF₆ Li₃PO₄ Li[SbF₆] LiTi₂(PO₄)₃ LiZr₂(PO₄)₃
Compounds withgroup 14 elements	Li₂C₂ Li₂CO₃ Li₂GeF₆ Li₂GeO₃ LiHCO₃ Li₃H(CO₃)₂ LiSi Li₂SiF₆ Li₂SiO₃ Li₂Si₂O₅ Li₄SiO₄ Li₂SnF₆
Compounds withgroup 13 elements	CsLiB₆O₁₀ LiAlCl₄ LiAlF₄ Li₃AlF₆ LiAlH₄ LiAlO₂ LiB(C₂O₄)₂ LiB(C₆F₅)₄ LiBF₄ LiBH₄ LiBO₂ LiB₃O₅ Li₂B₄O₇ LiBSi₂ LiGaH₄
Compounds withtransition metals	Li[AuCl₄] LiCoO₂ Li₂CrO₄ Li₂Cr₂O₇ Li₂IrO₃ Li₇La₃Zr₂O₁₂ LiMn₂O₄ Li₂MoO₄ Li_0.9Mo₆O₁₇ LiNbO₃ Li₂NbO₃ Li₂PtO₃ Li₂RuO₃ LiTaO₃ Li₂TiF₆ Li₂TiO₃ Li₄Ti₅O₁₂ LiVO₃ Li₃V₂(PO₄)₃ LiWF₆ Li₂WO₄ Li₂ZrF₆ Li₂ZrO₃
Organic (soaps)	Hemolithin (extraterrestrial protein) Organolithium reagents Gilman reagent CH₃COOLi C₄H₆LiNO₄ LiC₂F₆NO₄S₂ LiN(SiMe₃)₂ Li₃C₆H₅O₇ C₅H₅Li LiN(C₃H₇)₂ (C₆H₅)₂PLi C₁₈H₃₅LiO₃ C₆H₁₃Li C₄H₉Li CH₃CHLiCH₂CH₃ (CH₃)₃CLi C₁₂H₂₈BLi CH₃Li Li⁺C₁₀H−8 C₅H₁₁Li C₅H₃LiN₂O₄ C₆H₅Li LiC₂CH₃ LiO₂C(CH₂)₁₆CH₃ C₄H₅LiO₄ LiEt₃BH LiOC(CH₃)₃ C₉H₁₈LiN LiC₂H₃ Vinyllithium LiC ₁₁H ₂₃COO CH₃CH(OH)COOLi LiC₂H₂ClO₂ LiC₂H₃IO₂ Li(CH₃)₂N LiCHO₂ LiCH₃O LiC₂H₅O Li₂C₂O₄
Other compounds	Li₂ Li_xBe_y (hypothetical) LiCN Li₂CN₂ LiCNO LiH LiNa LiSCN LiYF₄ Neodymium-doped
Minerals	Amblygonite Berezanskite Brannockite Cryolithionite Darapiosite Darrellhenryite Elbaite Fluorine Elbaite Fluor-liddicoatite Emeleusite Eucryptite Faizievite Hectorite Hsianghualite Jadarite Kunzite Lavinskyite Lepidolite Lithiophilite Lithiophosphate Manandonite Manganoneptunite Nambulite Neptunite Olympite Petalite Pezzottaite Rossmanite Saliotite Sogdianite Spodumene Sugilite Tiptopite Tourmaline Triphylite Zabuyelite Zektzerite Zinnwaldite
Other Li-related	Aluminium–lithium alloys Heteroatom-promoted lateral lithiation LB buffer Lithium atom Lithium medication LiNi_xCo_yAl_zO₂ LiNi_xMn_yCo_zO₂ Lithium soap Lithium Triangle Lucifer yellow Magnesium–lithium alloys NASICON Environmentally friendly red light flare

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