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Lithium chlorate

From Wikipedia, the free encyclopedia
Lithium chlorate
Lithium ion   Chlorate
Names
Other names
Chloric acid, lithium salt
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.033.288Edit this at Wikidata
  • InChI=1S/ClHO3.Li/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1
  • [Li+].[O-]Cl(=O)=O
Properties
LiClO3
Molar mass90.39 g/mol
Melting point127.6 to 129 °C (261.7 to 264.2 °F; 400.8 to 402.1 K)[2][3][4]
241 g/100 mL (0 °C)
459 g/100 mL (25 °C)
777 g/100 mL (60 °C)
2226 g/100 mL (100 °C)[1]
−28.8·10−6 cm3/mol
Related compounds
Otheranions
Lithium chloride
Lithium hypochlorite
Lithium perchlorate
Othercations
Sodium chlorate
Potassium chlorate
Caesium chlorate
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Lithium chlorate is the inorganicchemical compound with the formula LiClO3.Like allchlorates, it is an oxidizer and may become unstable and possibly explosive if mixed with organic materials, reactive metal powders, or sulfur.

It can be manufactured by the reaction of hot, concentratedlithium hydroxide with chlorine:

3 Cl2 + 6 LiOH → 5 LiCl + LiClO3 + 3 H2O

Lithium chlorate has one of the highest solubilities in water for a chemical compound. It is also a six-electron oxidant. Its electrochemical reduction is facilitated by acid, electrocatalysts and redox mediators. These properties make lithium chlorate a useful oxidant for highenergy densityflow batteries.[5] Lithium chlorate has a very low melting point for an inorganic ionic salt.

References

[edit]
  1. ^John Rumble (June 18, 2018).CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 4–47.ISBN 978-1138561632.
  2. ^Wang, Su-Chee Simon (1983). "The Electrochemistry of Molten Lithium Chlorate and its Possible Use with Lithium in a Battery".Journal of the Electrochemical Society.130 (4):741–747.Bibcode:1983JElS..130..741W.doi:10.1149/1.2119796.
  3. ^A. N. Campbell, E. M. Kartzmark, W. B. Maryk (1966). "The Systems Sodium Chlorate - Water - Dioxane and Lithium Chlorate - Water - Dioxane, at 25°".Can. J. Chem.44 (8):935–937.doi:10.1139/v66-136.S2CID 97413079.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  4. ^http://scitation.aip.org/getabs/servlet/GetabsServlet?prog=normal&id=JESOAN000130000004000741000001&idtype=cvips&gifs=yes&ref=no[dead link]
  5. ^US 20140170511 
Inorganic (list)
Organic (soaps)
Minerals
Hypothetical
Other Li-related
Salts and covalent derivatives of thechlorate ion
HClO3He
LiClO3BeBCNH4ClO3OFNe
NaClO3Mg(ClO3)2Al(ClO3)3SiPSClAr
KClO3Ca(ClO3)2ScTiVCrMn(ClO3)2Fe(ClO3)3Co(ClO3)2Ni(ClO3)2Cu(ClO3)2Zn(ClO3)2Ga(ClO3)3GeAsSeBrKr
RbClO3Sr(ClO3)2Y(ClO3)3ZrNbMoTcRuRhPdAgClO3Cd(ClO3)2InSnSbTeIXe
CsClO3Ba(ClO3)2*LuHfTaWReOsIrPtAuClO3Hg(ClO3)2TlPb(ClO3)2BiPoAtRn
FrRa(ClO3)2**LrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
 
*La(ClO3)2CePr(ClO3)2NdPmSmEuGdTbDyHoEr(ClO3)2TmYb
**AcThPaUNpPuAmCmBkCfEsFmMdNo
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