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Lazurite

From Wikipedia, the free encyclopedia
Alumino-silicate mineral whose blue colour is due to a sulfide species and not copper
Not to be confused withAzurite orLazulite.
For other uses, seeAzure spar.
Lazurite
Lazurite, Ladjuar Medam (Lajur Madan; Lapis-lazuli Mine), Sar-e-Sang District, Koksha Valley (Kokscha; Kokcha), Badakhshan (Badakshan; Badahsan) Province, Afghanistan
General
CategoryTectosilicateminerals,feldspathoidgroup,sodalite group
Formula(Na,Ca)8[(S,Cl,SO4,OH)2|(Al6Si6O24)]
IMA symbolLzr[1]
Strunz classification9.FB.10
Crystal systemIsometric
Crystal classHextetrahedral (43m)
H-M symbol: (4 3m)
Space groupP43n
Unit cella = 9.09 Å; Z = 2
Identification
ColorDeep blue, azure, violet-blue, greenish blue
Crystal habitCrystals occur as dodecahedra, or rarely cubes; granular, disseminated, or massive
CleavageImperfect on {110}
FractureUneven
TenacityBrittle
Mohs scale hardness5–5.5
LusterVitreous
DiaphaneityTranslucent to opaque
Specific gravity2.38–2.45
Optical propertiesIsotropic; anomalously anisotropic
Refractive index1.502–1.522
Fusibility3.5
SolubilitySoluble inHCl
References[2][3][4][5][6]

Lazurite, old nameAzure spar[7]: 14  is atectosilicate mineral withsulfate,sulfur andchloride with formula(Na,Ca)8[(S,Cl,SO4,OH)2|(Al6Si6O24)]. It is afeldspathoid and a member of thesodalite group. Lazurite crystallizes in theisometric system although well‐formed crystals are rare. It is usually massive and forms the bulk of the gemstonelapis lazuli.

Mineral

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Lazurite is a deep‐blue to greenish‐blue. The colour is due to the presence ofS
3
anions.[8] It has aMohs hardness of 5.0 to 5.5 and aspecific gravity of 2.4. It is translucent with arefractive index of 1.50. It is fusible at 3.5 onWolfgang Franz von Kobell'sfusibility scale, and soluble inHCl. It commonly contains or is associated with grains ofpyrite.

Lazurite is a product ofcontact metamorphism oflimestone and is typically associated withcalcite, pyrite,diopside,humite,forsterite,hauyne andmuscovite.[2]

Other blue minerals, such as thecarbonate mineral,azurite, and thephosphate mineral,lazulite, may be confused with lazurite, but are easily distinguished with careful examination. At one time, lazurite was a synonym forazurite.[5]

Lazurite was first described in 1890 for an occurrence in theSar-e-Sang District,Koksha Valley,Badakhshan Province,Afghanistan.[3] It has been mined for more than 6,000 years in thelapis lazuli district of Badakhshan. It has been used as a pigment in painting and clothdyeing since at least the 6th or 7th century.[9] It is also mined atLake Baikal in Siberia;Mount Vesuvius;Burma;Canada; and theUnited States.[9] The name is from thePersianlajvard for blue.[10]

The most important mineral component of lapis lazuli islazurite[11] (25% to 40%)[citation needed]

Redefinition

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Most lapis lazuli gets its blue color from Hauyne and almost none contain "true lazurite".[11] This was changed in 2021, as lazurite was redefined so that it is enough for a quarter (instead of half) of the cages to contain sulfide.[12]

Structure

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Lazurite andhauyne seem to have the same structure and both are sulfate-dominant minerals.[13] Lazurite is apigment (opalescent) and has a bright blue streak (especially as a component of the semiprecious stonelapis lazuli). Many hauynes have a white or pale blue streak and are translucent. The difference might be a consequence of theredox state (sulfate to sulfide ratio).[8][14]

See also

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  • Hauyne – Rare feldspathoid mineral in the sodalite group
  • Ultramarine – Deep blue purple color pigment which was originally made with ground lapis lazuli

References

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  1. ^Warr, L.N. (2021)."IMA–CNMNC approved mineral symbols".Mineralogical Magazine.85 (3):291–320.Bibcode:2021MinM...85..291W.doi:10.1180/mgm.2021.43.S2CID 235729616.
  2. ^abHandbook of Mineralogy
  3. ^abMindat with location data
  4. ^Webmineral data
  5. ^abHurlbut, Cornelius S. and Klein, Cornelis, 1985,Manual of Mineralogy, 20th ed., Wiley, p. 459ISBN 0-471-80580-7
  6. ^"Mineralogical Society of America"(PDF). Archived fromthe original(PDF) on 2016-03-03. Retrieved2011-03-08.
  7. ^Krivovichev V. G. Mineralogical glossary. Scientific editorA. G. Bulakh. — St.Petersburg: St.Petersburg Univ. Publ. House. 2009. — 556 p. — ISBN 978-5-288-04863-0.(in Russian)
  8. ^abTauson VL, Sapozhnikov AN (2003)."On the nature of lazurite coloring"(PDF).Zapiski Vserossijskogo Mineralogicheskogo Obshchestva (in Russian).132 (5):102–107.
  9. ^abEastaugh, Nicholas; et al. (2004).The Pigment Compendium: Optical Microscopy of Historical Pigments. Oxford: Elsevier Butterworth-Heinemann. p. 219.ISBN 0-7506-4553-9.
  10. ^"Tile fragment". Victoria and Albert Museum. Retrieved11 January 2020.
  11. ^ab"Lapis lazuli: Mineral information, data and localities".www.mindat.org.Archived from the original on 2020-01-29. Retrieved2024-08-30.
  12. ^"Lazurite".mindat.org. Retrieved2024-08-30.
  13. ^Moore, T.P.; Woodside, R. W. M. (2014). "The Sar-e-Sang Lapis Mines".Mineralogical Record.45 (3):281–336.
  14. ^Hettmann K, Wenzel T, Marks M, Markl G (2012). "The sulfur speciation in S-bearing minerals: New constraints by a combination of electron microprobe analysis and DFT calculations with special reference to sodalite-group minerals".American Mineralogist.97 (10):1653–1661.Bibcode:2012AmMin..97.1653H.doi:10.2138/am.2012.4031.S2CID 54921328.

External links

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  • Media related toLazurite at Wikimedia Commons
Gemmological classifications by E. Ya. Kievlenko (1980), updated
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