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Laponite

From Wikipedia, the free encyclopedia
Synchetic chemical compound

Laponite is a syntheticsmectite clay invented in 1962 by clay scientistBarbara Neumann. Usually produced as powder, laponite is ananomaterial made up of very small disk-shaped crystals used in multiple industrial applications. Laponite was first marketed by the companyLaporte plc and is currently produced byBYK Additives & Instruments.[1][2][3][4][5] Laponite is not an approvedmineral species, since it is not naturally occurring and it is not produced by geological processes.[6]

In the first formulation of laponite created by Neumann in 1962, the synthetic clay was determined to be afluorohectorite and was produced in the form of discs 1 nanometer thick and with a diameter of 60 to 80 nanometers. This went into mass production in 1964.[7] The mineral structure of the clay gives laponite its particular physical characteristics and is similar to thesmectite group of clay minerals, with a 2:1 layered crystal structure in which two tetrahedral silica sheets lie either side of an octahedral sheet containing magnesium ions.[5] In 1966, Neumann patented a second formulation of laponite, called 'Laponite RD'. This form was free from fluorine, and has subsequently become the most widely used form of laponite.[8] This form of laponite has an empirical formula ofNa0.7[(Si8Mg5.5Li0.3)O20(OH)4].[5] In later years, Neumann also created other variants of laponite including a lithium-free magnesium silicate clay, a form of syntheticstevensite, and an iron silicate clay, which was a synthetic form ofnontronite.[7]

References

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  1. ^GB 1054111, Neumann, B.S., "Improvements in or Relating to Synthetic Clay-Like Minerals" 
  2. ^Neumann, B.S. (1965)."Behaviour of a synthetic clay in pigment dispersions".Rheologica Acta.4 (4):250–255.Bibcode:1965AcRhe...4..250N.doi:10.1007/BF01973660.
  3. ^Brunchi, C.-E.; Morariu, S. (2024)."Laponite—From Dispersion to Gel—Structure, Properties, and Applications".Molecules.29 (2823): 2823.doi:10.3390/molecules29122823.PMC 11206873.PMID 38930887.
  4. ^Shafran, Kirill; Jeans, Christopher V; Kemp, Simon J; Murphy, Kevin (2021)."Dr Barbara S. Neumann: Clay Scientist, Industrial Pioneer, Creator of Laponite".Elements.17 (1):69–70.Bibcode:2021Eleme..17...69S.doi:10.2138/gselements.17.1.69.
  5. ^abcTomás, Helena; Alves, Carla S.; Rodrigues, João (2018)."Laponite®: A key nanoplatform for biomedical applications?".Nanomedicine: Nanotechnology, Biology and Medicine.14 (7):2407–2420.doi:10.1016/j.nano.2017.04.016.PMID 28552649.
  6. ^"Laponite".mindat.org.
  7. ^abShafran, Kirill; Jeans, Christopher V; Kemp, Simon J; Murphy, Kevin (2020)."Dr Barbara S. Neumann: Clay Scientist and Industrial Pioneer".Clay Minerals.55:256–260.doi:10.1180/clm.2020.35.
  8. ^GB 1213122, Neumann, B.S., "Clays" 
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