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Lactonitrile

From Wikipedia, the free encyclopedia
Lactonitrile
Names
IUPAC name
2-Hydroxypropanenitrile
Other names
Acetaldehyde cyanohydrin
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.001.058Edit this at Wikidata
UNII
  • InChI=1S/C3H5NO/c1-3(5)2-4/h3,5H,1H3
    Key: WOFDVDFSGLBFAC-UHFFFAOYSA-N
  • InChI=1/C3H5NO/c1-3(5)2-4/h3,5H,1H3
    Key: WOFDVDFSGLBFAC-UHFFFAOYAF
  • N#CC(C)O
Properties
C3H5NO
Molar mass71.079 g·mol−1
AppearanceYellow
Melting point−40 °C (−40 °F; 233 K)
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Lactonitrile is theorganic compound with the formula CH3CH(OH)CN. It is an intermediate in the industrial production ofethyl lactate andlactic acid.[1][2][3] It is thecyanohydrin ofacetaldehyde. It is a colorless liquid, although degraded samples can appear yellow.

Synthesis and use

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Lactonitrile is obtained by the addition ofhydrogen cyanide toacetaldehyde.[1]

Lactonitrile is used in making esters of lactic acid.[1]

Regulations

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Cyanohydrins are sources of highly toxichydrogen cyanide.The substance is classified as anextremely hazardous substance in the United States as defined in Section 302 of the U.S.Emergency Planning and Community Right-to-Know Act (42 U.S.C. 11002), and is subject to strict reporting requirements by facilities which produce, store, or use it in significant quantities.[4]

References

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  1. ^abcWesthoff, Gerrit; Starr, John N. (2012). "Lactic Acids".Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH.doi:10.1002/14356007.a15_097.pub3.ISBN 9783527306732.
  2. ^"Lactonitrile".EChA. echa.europa.eu. Retrieved13 June 2017.
  3. ^Lactonitrile at www.chemicalbook.com.
  4. ^"40 C.F.R.: Appendix A to Part 355—The List of Extremely Hazardous Substances and Their Threshold Planning Quantities"(PDF) (July 1, 2008 ed.).Government Printing Office. Archived fromthe original(PDF) on February 25, 2012. RetrievedOctober 29, 2011.{{cite journal}}:Cite journal requires|journal= (help)
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