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Iron pentahydride

From Wikipedia, the free encyclopedia
Iron pentahydride
Identifiers
3D model (JSmol)
  • InChI=1S/Fe.5H
    Key: HAXLEIPZVOGIBZ-UHFFFAOYSA-N
  • [Fe].[H].[H].[H].[H].[H]
Properties
FeH5
Molar mass60.885 g·mol−1
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Iron pentahydrideFeH5 is asuperhydride compound ofiron andhydrogen, stable under high pressures. It is important because it contains atomic hydrogen atoms that are not bonded into smaller molecular clusters, and may be asuperconductor. Pairs of hydrogen atoms are not bonded together into molecules.FeH5 has been made by compressing a flake of iron with hydrogen in adiamond anvil cell to a pressure of 130 GPa and heating to below 1500K.[1] When decompressed to 66 GPa it decomposes to solidFeH3.

The unit cell istetragonal withspace groupI4/mmm.[2]

See also

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References

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  1. ^Pépin, C. M.; Geneste, G.; Dewaele, A.; Mezouar, M.; Loubeyre, P. (28 July 2017)."Synthesis of FeH5: A layered structure with atomic hydrogen slabs".Science.357 (6349):382–385.Bibcode:2017Sci...357..382P.doi:10.1126/science.aan0961.ISSN 0036-8075.PMID 28751605.
  2. ^"Synthesis of FeH5 under pressure: Dense atomic metal hydrogen stabilised with Fe".Spotlight on Science. European Synchrotron Radiation Facility. 27 July 2017.


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