Movatterモバイル変換


[0]ホーム

URL:


Jump to content
WikipediaThe Free Encyclopedia
Search

Iridium(III) sulfide

From Wikipedia, the free encyclopedia
Iridium(III) sulfide
Identifiers
3D model (JSmol)
  • Key: UVJVOJHPJVDQLS-UHFFFAOYSA-N
  • InChI=1S/2Ir.3S
  • S=[Ir]S[Ir]=S
Properties
Ir2S3
Molar mass480.61 g·mol−1
Appearanceblack solid
insoluble
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
very flammable
Flash pointnone
Related compounds
Othercations
Rhodium(III) sulfide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Iridium(III) sulfide is theinorganic compound with the formula Ir2S3. It is an insoluble black solid, prepared by heating a mixture of elemental iridium and sulfur[citation needed]. Crystals can be grown bychemical vapor transport usingbromine as the transporting agent. The structure consists ofoctahedral and tetrahedral Ir and S centers, respectively. No close Ir-Ir contacts are observed.[1]Rh2S3 and Rh2Se3 adopt the same structure.

References

[edit]
  1. ^Parthée, Erwin; Hohnke, Dieter K.; Hulliger, Fritz (1967). "New structure type with octahedron pairs for rhodium(III) sulfide, rhodium(III) selenide, and iridium(III) sulfide".Acta Crystallographica.23:832–840.doi:10.1107/S0365110X67003767.
Iridium(0)
Iridium(I)
Organoiridium(I)
Iridium(II)
Iridium(III)
Organoiridium(III)
Iridium(IV)
Iridium(V)
Iridium(VI)
Iridium(VII)
Iridium(VIII/IX)
Sulfides(S2−)
Retrieved from "https://en.wikipedia.org/w/index.php?title=Iridium(III)_sulfide&oldid=1270187619"
Categories:
Hidden categories:

[8]ページ先頭

©2009-2025 Movatter.jp