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Iodate sulfate

From Wikipedia, the free encyclopedia

Iodate sulfates aremixed anion compounds that contain bothiodate andsulfateanions. Iodate sulfates have been investigated as optical second harmonic generators, and for separation of rare earth elements.[1] Related compounds include theiodate selenates[2] andchromate iodates.[3]


Iodate sulfates can be produced from water solutions of iodic acid and sulfate salts.[4]

List

[edit]
formulanameformula

weight

systemspace groupcell Åvolumedensitycommentsref
Na7(IO3)(SO4)3624.01orthorhombicP212121a=6.839b=10.851c=18.519 Z=41374.23.016at 100K; band gap 4.83; SHQ 0.5×KDP; birefringence 0.075 at 1064 nm[5]
Na9(IO3)(SO4)4HectorfloresitemonoclinicP21/aa = 18.775b = 6.9356c = 14.239 β = 108.91° Z = 4[5][6]
K2SO4·HIO3350.17monoclinicP21/na=7.4215b=7.1578c=13.802β=93.330° Z=4731.93.178colourless; birefingence 0.14 at 589.3 nm; UV edge 275 nm[7]
K3Na5Mg5(IO3)6(SO4)6(H2O)5trigonalP3c1
K7.2Na8.8Mg10(IO3)12(SO4)12(H2O)12FuenzalidaitetrigonalP3c1a = 9.4643 c = 27.3362,120.52colourless; Uniaxial (-)nω = 1.622nε = 1.615; Birefringence = 0.007[5][8][9]
Nb2O3(IO3)2(SO4)679.68monoclinicP21a=5.299 b=20.479 c=5.452β=119.095° Z=2517.04.366band gap 3.25; SHG 6 × KDP; birefringence 0.22 at 1064 nm; stable below 580 °C[5][10]
Ce(IO3)2(SO4)CISO585.98orthorhombicP212121a=7.5366b=8.9787c=11.6121 Z=4785.784.953yellow; SHG 3.5 × KDP; birefringence 0.259 at 546 nm[11]
Sm(IO3)(SO4)monoclinicP21/ca=9.3148b=6.8678c=8.2852β=104.701°[12]
Sm2(IO3)3(SO4)OH·3H2OtriclinicP1a 7.3858b 9.6166c 11.8629α=66.482°β=76.884°γ=69.101°[12]
Eu(IO3)(SO4)monoclinicP21/ca=9.3083b=6.8460c=8.2575β=104.696°[5][1]
Eu2(IO3)3(SO4)OH·3H2OtriclinicP1a=7.3666b=9.5817c=11.8263α=66.5365°β=76.8591°γ=69.1131°[12]
Dy(IO3)(SO4)(H2O)orthorhombicP212121a=7.3088b=9.4824c=11.7302α=66.6573°β=76.8745°γ=69.2970°[5]
Dy(IO3)(SO4)(H2O)3orthorhombicP212121a=6.682b=8.791c=13.632[1]
Dy2(IO3)3(SO4)OH·3H2OtriclinicP1[12]
Hg2(IO3)2(SO4)monoclinicC2/ca=12.040b=4.7133c=15.533β=102.43°[13]
Hg2(IO3)2(SO4)(H2O)monoclinicC2a=11.767b=4.9190c=7.8076β=97.10°band gap 3.98 eV; SHG 6 × KDP; dehydrate 250 °C[13]
Bi(IO3)(SO4)479.94monoclinicP21/ca=9.4355b=6.9168c=8.3374β=105.168° Z=4525.176.070band gap 3.91 eV; birefringence 0.087 at 1064 nm; colourless[14]
Bi2O(SO4)(IO3)2monoclinicP21/na=7.2391b=17.907c=7.7964β = 109.652° Z =4[4]
AgBi(SO4)(IO3)21525.42triclinicP1a=5.5189b=6.9129c=11.8527α=90.598°β=92.151°γ=109.895° Z=1424.785.963colourless; SHG 3.0 × KDP[15]
CdBi(IO3)(SO4)2688.40monoclinicP21/ca=12.777b=6.8491c=9.984β=103.23° Z=4850.55.376band gap 4.03 eV; birefringence 0.100 at 1064 nm[14]

References

[edit]
  1. ^abcLu, Huangjie; Guo, Xiaojing; Wang, Yaxing; Diefenbach, Kariem; Chen, Lanhua; Wang, Jian-Qiang; Lin, Jian; Wang, Shuao (2019)."Size-dependent selective crystallization using an inorganic mixed-oxoanion system for lanthanide separation".Dalton Transactions.48 (34):12808–12811.doi:10.1039/C9DT02387A.ISSN 1477-9226.PMID 31348473.S2CID 198911627.
  2. ^Chen, Qian-Qian; Hu, Chun-Li; Li, Bing-Xuan; Mao, Jiang-Gao (2023)."[M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology".Inorganic Chemistry Frontiers.10 (10):3121–3130.doi:10.1039/D3QI00415E.ISSN 2052-1553.S2CID 258123310.
  3. ^Sullens, Tyler A.; Almond, Philip M.; Byrd, Jessica A.; Beitz, James V.; Bray, Travis H.; Albrecht-Schmitt, Thomas E. (April 2006)."Extended networks, porous sheets, and chiral frameworks. Thorium materials containing mixed geometry anions: Structures and properties of Th(SeO3)(SeO4), Th(IO3)2(SeO4)(H2O)3·H2O, and Th(CrO4)(IO3)2".Journal of Solid State Chemistry.179 (4):1192–1201.Bibcode:2006JSSCh.179.1192S.doi:10.1016/j.jssc.2006.01.017.
  4. ^abShi, Long; Mei, Dajiang; Xu, Jingli; Wu, Yuandong (January 2017)."Bi 2 O(XO 4 )(IO 3 ) 2 (X = S, Se, Cr): Three-dimensional frameworks containing [Bi 4 O 2 ] 8+ clusters".Solid State Sciences.63:54–61.Bibcode:2017SSSci..63...54S.doi:10.1016/j.solidstatesciences.2016.11.010.
  5. ^abcdefDing, Mengmeng; Yu, Hongwei; Hu, Zhanggui; Wang, Jiyang; Wu, Yicheng (2021)."Na 7 (IO 3 )(SO 4 ) 3: the first noncentrosymmetric alkaline-metal iodate-sulfate with isolated [IO 3 ] and [SO 4 ] units".Chemical Communications.57 (75):9598–9601.doi:10.1039/D1CC03483A.ISSN 1359-7345.PMID 34546233.S2CID 237584872.
  6. ^George E. Ericksen; Howard T. Evans; Mary E. Mrose; James J. Mcgee; John W. Marinenko; Judith A. Konnert (1 October 1989)."Mineralogical studies of the nitrate deposits of Chile; VI, Hectorfloresite, Na9(IO3(SO4)4, a new saline mineral".American Mineralogist.74 (9–10):1207–1214. Retrieved2023-09-11.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  7. ^Bai, Zhiyong; Ok, Kang Min (2023)."Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3".Inorganic Chemistry Frontiers.10 (6):1919–1925.doi:10.1039/D3QI00192J.ISSN 2052-1553.S2CID 257071174.
  8. ^"Fuenzalidaite".Mindat.org.
  9. ^Konnert, Judith A.; Evans, Howard T.; McGee, James J.; Ericksen, George E. (October 1994)."Mineralogical studies of the nitrate deposits of Chile: VII. Two new saline minerals with the composition K6(Na,K)4Na6Mg10(XO4)12(IO3)12·12H2O: Fuenzalidaite (X = S) and carlosruizite (X = Se)".American Mineralogist.79 (9–10):1003–1008.Bibcode:1994AmMin..79.1003K. Retrieved2023-09-11.
  10. ^Tang, Hong-Xin; Zhang, Yu-Xiao; Zhuo, Chao; Fu, Rui-Biao; Lin, Hua; Ma, Zu-Ju; Wu, Xin-Tao (2019-03-18)."A Niobium Oxyiodate Sulfate with a Strong Second-Harmonic-Generation Response Built by Rational Multi-Component Design".Angewandte Chemie.131 (12):3864–3868.Bibcode:2019AngCh.131.3864T.doi:10.1002/ange.201813122.ISSN 0044-8249.S2CID 243005250.
  11. ^Wu, Tianhui; Jiang, Xingxing; Zhang, Yiran; Wang, Zujian; Sha, Hongyuan; Wu, Chao; Lin, Zheshuai; Huang, Zhipeng; Long, Xifa; Humphrey, Mark G.; Zhang, Chi (2021-12-14)."From CeF 2 (SO 4 )·H 2 O to Ce(IO 3 ) 2 (SO 4 ): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence".Chemistry of Materials.33 (23):9317–9325.doi:10.1021/acs.chemmater.1c03053.ISSN 0897-4756.S2CID 244494818.
  12. ^abcdAslani, Ceren Kutahyali; Klepov, Vladislav V.; zur Loye, Hans-Conrad (July 2022)."Hydrothermal synthesis of new mixed-oxoanion materials: Rare earth iodate sulfates Sm(IO3)(SO4) and Ln2(IO3)3(SO4)OH·3H2O (Ln = Sm, Eu, Dy)".Solid State Sciences.129 106918.Bibcode:2022SSSci.12906918A.doi:10.1016/j.solidstatesciences.2022.106918.
  13. ^abLi, Yi-Lin; Ji, Meng-Ya; Hu, Chun-Li; Chen, Jin; Li, Bing-Xuan; Lin, Yuan; Mao, Jiang-Gao (April 2022)."Explorations of New SHG Materials in Mercury Iodate Sulfate System**".Chemistry – A European Journal.28 (19) e202200001.doi:10.1002/chem.202200001.ISSN 0947-6539.PMID 35156759.S2CID 246813632.
  14. ^abLi, Yilin; Hu, Chunli; Chen, Jin; Mao, Jianggao (2021)."Two bismuth iodate sulfates with enhanced optical anisotropy".Dalton Transactions.50 (44):16139–16146.doi:10.1039/D1DT02514G.ISSN 1477-9226.PMID 34677566.S2CID 239456548.
  15. ^Liu, Hongming; Wu, Qingchen; Liu, Lili; Lin, Zheshuai; Halasyamani, P. Shiv; Chen, Xingguo; Qin, Jingui (2021)."AgBi(SO 4 )(IO 3 ) 2: aliovalent substitution induces structure dimensional upgrade and second harmonic generation enhancement".Chemical Communications.57 (30):3712–3715.doi:10.1039/D0CC07862J.ISSN 1359-7345.PMID 33729224.S2CID 232262974.
Compounds containing thesulfate group (SO2−4)
H2SO4He
Li2SO4BeSO4B2S2O9
-BO3
+BO3		esters
ROSO−3
(RO)2SO2
+CO3
+C2O4		(NH4)2SO4
[N2H5]HSO4
(NH3OH)2SO4
NOHSO4
+NO3		H2OSO4+FNe
Na2SO4
NaHSO4		MgSO4Al2(SO4)3
Al2SO4(OAc)4		Si+PO4SO2−4
HSO3HSO4
(HSO4)2
+SO3		+ClAr
K2SO4
KHSO4		CaSO4Sc2(SO4)3TiOSO4VSO4
V2(SO4)3
VOSO4		CrSO4
Cr2(SO4)3		MnSO4FeSO4
Fe2(SO4)3		CoSO4
Co2(SO4)3		NiSO4
Ni2(SO4)3		CuSO4
Cu2SO4
[Cu(NH3)4(H2O)]SO4		ZnSO4Ga2(SO4)3Ge(SO4)2+AsO4+SeO3+BrKr
RbHSO4
Rb2SO4		SrSO4Y2(SO4)3Zr(SO4)2Nb2O2(SO4)3MoO(SO4)2
MoO2(SO4)		TcRu(SO4)2Rh2(SO4)3PdSO4Ag2SO4
AgSO4		CdSO4In2(SO4)3SnSO4
Sn(SO4)2		Sb2(SO4)3TeOSO4I2(SO4)3
(IO)2SO4
+IO3		Xe
Cs2SO4
CsHSO4		BaSO4*Lu2(SO4)3Hf(SO4)2Ta(SO4)67–WO(SO4)2Re2O5(SO4)2OsSO4
Os2(SO4)3
Os(SO4)2		IrSO4
Ir2(SO4)3		Pt2(SO4)54–AuSO4
Au2(SO4)3		Hg2SO4
HgSO4		Tl2SO4
Tl2(SO4)3		PbSO4
Pb(SO4)2		Bi2(SO4)3PoSO4
Po(SO4)2		AtRn
FrRaSO4**LrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
 
*La2(SO4)3Ce2(SO4)3
Ce(SO4)2		Pr2(SO4)3Nd2(SO4)3Pm2(SO4)3Sm2(SO4)3EuSO4
Eu2(SO4)3		Gd2(SO4)3Tb2(SO4)3Dy2(SO4)3Ho2(SO4)3Er2(SO4)3Tm2(SO4)3Yb2(SO4)3
**Ac2(SO4)3Th(SO4)2(PaO)2(SO4)3
H3PaO(SO4)3		U2(SO4)3
U(SO4)2
UO2SO4		Np(SO4)2
(NpO2)2SO4
NpO2SO4		Pu(SO4)2
PuO2SO4		Am2(SO4)3
Am2O2SO4		Cm2(SO4)3
Cm2O2SO4		Bk2O2SO4Cf2(SO4)3
Cf2O2SO4		EsFmMdNo
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