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Hexaoxotricyclobutabenzene

From Wikipedia, the free encyclopedia
Hexaoxotricyclobutabenzene
Structural formula of hexaoxotricyclobutabenzene
Structural formula of hexaoxotricyclobutabenzene
Ball and stick model of hexaoxotricyclobutabenzene
Ball and stick model of hexaoxotricyclobutabenzene
Names
Preferred IUPAC name
Tetracyclo[8.2.0.02,5.06,9]dodeca-1,5,9-triene-3,4,7,8,11,12-hexone
Other names
Hexaoxotricyclobutabenzene
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/C12O6/c13-7-1-2(8(7)14)4-6(12(18)11(4)17)5-3(1)9(15)10(5)16
    Key: QRXXJVVGRWBSJV-UHFFFAOYSA-N
  • O=C1C(=O)C2=C3C(=O)C(=O)C3=C3C(=O)C(=O)C3=C12
Properties
C12O6
Molar mass240.12 g mol−1
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound

Hexaoxotricyclobutabenzene is an organic compound with formula C12O6. It can be viewed as the sixfold ketone oftricyclobutabenzene.

It is anoxide of carbon, detected by13C NMR in 2006.[1][2]

References

[edit]
  1. ^Hamura, T.; Ibusuki, Y.; Uekusa, H.; Matsumoto, T.; Siegel, J. S.; Baldridge, K. K.; Suzuki, K. (2006). "Dodecamethoxy- and Hexaoxotricyclobutabenzene: Synthesis and Characterization".Journal of the American Chemical Society.128 (31):10032–10033.doi:10.1021/ja064063e.PMID 16881630.
  2. ^Butenschön, H. (2007). "A new oxocarbon C12O6 via highly strained benzyne intermediates".Angewandte Chemie.46 (22):4012–4014.doi:10.1002/anie.200700926.PMID 17508349.
Common oxides
Exotic oxides
Polymers
Compounds derived from oxides
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