Movatterモバイル変換


[0]ホーム

URL:


Jump to content
WikipediaThe Free Encyclopedia
Search

Hexaborane(12)

From Wikipedia, the free encyclopedia
Hexaborane(12)
Identifiers
3D model (JSmol)
  • InChI=1S/B6H12/c7-1-3-4(5(1,3,7)10-4)2-6(3,4,8-2)9-3/h3-6H,1-2H2
    Key: ZMLJCODVOXNMHE-UHFFFAOYSA-N
  • [BH2]12[BH]34([H]1)[BH]256[BH]38([H]4)[BH]75([H]6)[BH2]8[H]7
Properties
B6H12
Molar mass76.96 g·mol−1
Appearancecolorless liquid
Melting point−82.3 °C (−116.1 °F; 190.8 K)
Boiling point85 °C (185 °F; 358 K) (approx)
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Hexaborane(12) is aninorganic compound with the formula B6H12. It is an obscure member of theboranes. It is a colorless liquid that, like some otherboron hydride clusters, is readily hydrolyzed and flammable.

The molecular structure conforms to C2symmetry group. With the formula BnHn+6, it is classified as anarachno-cluster. As such the boron positions match six of the boron positions in the closo-B8H2−
8
.

Preparation

[edit]

It is typically prepared by the cluster expansion method from B5H
8
, the conjugate base ofpentaborane(9):[2]

LiB5H8 + 1/2 B2H6 → LiB6H11
LiB6H11 + HCl → B6H12 + LiCl

References

[edit]
  1. ^"Hexaborane(12)".webbook.nist.gov. National Institute of Standards and Technology.
  2. ^Greenwood, Norman N.; Earnshaw, Alan (1997).Chemistry of the Elements (2nd ed.).Butterworth-Heinemann.doi:10.1016/C2009-0-30414-6.ISBN 978-0-08-037941-8. p.172.
Boron pnictogenides
Boron halides
Acids
Boranes
Boron oxides and sulfides
Carbides
Organoboron compounds
Alkali metal
(Group 1) hydrides
Alkaline (Group 2)
earth hydrides
Monohydrides
Dihydrides
Group 13
hydrides
Boranes
Alanes
Gallanes
Indiganes
Thallanes
Nihonanes(predicted)
  • NhH
  • NhH3
  • Nh2H6
  • NhH5
Group 14 hydrides
Hydrocarbons
Silanes
Silenes
Silynes
Germanes
Stannanes
Plumbanes
Flerovanes(predicted)
  • FlH
  • FlH2
  • FlH4
Pnictogen
(Group 15) hydrides
Azanes
Azenes
Phosphanes
Phosphenes
Arsanes
Stibanes
Bismuthanes
Moscovanes
Hydrogen
chalcogenides
(Group 16 hydrides)
Polyoxidanes
Polysulfanes
Selanes
Tellanes
Polanes
Livermoranes
Hydrogen halides
(Group 17 hydrides)
  • HF
  • HCl
  • HBr
  • HI
  • HAt
  • HTs(predicted)
  • Transition
    metal hydrides
    Lanthanide
    hydrides
    Actinide
    hydrides
    Exotic matter hydrides
    Stub icon

    Thisinorganiccompound–related article is astub. You can help Wikipedia byexpanding it.

    Retrieved from "https://en.wikipedia.org/w/index.php?title=Hexaborane(12)&oldid=1269345564"
    Categories:
    Hidden categories:

    [8]ページ先頭

    ©2009-2025 Movatter.jp