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Hassium tetroxide

From Wikipedia, the free encyclopedia
Hassium tetroxide
Stick model hassium tetroxide
Stick model hassium tetroxide
Names
Preferred IUPAC name
Hassium tetraoxide
Systematic IUPAC name
Tetraoxohassium
Other names
Hassium(VIII) oxide
Identifiers
3D model (JSmol)
  • InChI=1S/4O.Hs
    Key: ZEDIDOIMNXPGSR-UHFFFAOYSA-N
  • O=[Hs](=O)(=O)=O
Properties
HsO4
Molar mass334 g·mol−1
Structure[1]
tetrahedral (predicted)
Related compounds
Othercations
Osmium(VIII) oxide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Hassium tetroxide (alsohassium(VIII) oxide) is theinorganic compound with theformula HsO4. It is the highestoxide ofhassium, atransactinidetransition metal. It has little use outside of scientific interest, where it is often studied in comparison toosmium tetroxide andruthenium tetroxide, its lighter octavalentgroup 8 element analogs.

Physical properties

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Because of the extreme cost and difficulty of producing hassium, hassium tetroxide has never been obtained in macroscopic amounts, as only a few molecules have ever been synthesized. As a result, many of its physical properties are experimentally uncharacterized and unknown. However, most research available generally shows hassium tetroxide to behave like a typicalcongener to osmium tetroxide. Hassium tetroxide is less volatile than osmium tetroxide.[2][3][4]

Synthesis

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Hassium tetroxide can be obtained by reacting atomic hassium with oxygen at 600 °C.[3][2]

Hs + 2 O2 → HsO4

Reactions

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Hassium tetroxide can be combined withsodium hydroxide in an acid-base reaction, in which case it acts like the acid, to formsodium hassate(VIII):[5]

HsO4 + 2 NaOH → Na2[HsO4(OH)2]

References

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  1. ^Gulzari, Malli L. (2002). "Dramatic relativistic effects in atomization energy and volatility of the superheavy Hassium tetroxide and OsO4".Journal of Chemical Physics.117 (23):10441–10443.Bibcode:2002JChPh.11710441M.doi:10.1063/1.1527057.
  2. ^ab"Chemistry of Hassium"(PDF). Gesellschaft für Schwerionenforschung. 2002. Archived fromthe original(PDF) on 2012-03-11. Retrieved2019-06-30.
  3. ^abDüllmann, Ch. E.; Brüchle, W.; Dressler, R.; et al. (August 2002). "Chemical investigation of hassium (element 108)".Nature.418 (6900):859–862.Bibcode:2002Natur.418..859D.doi:10.1038/nature00980.PMID 12192405.S2CID 4412944.
  4. ^Hoffman, Lee & Pershina 2006, pp. 1714–1715.
  5. ^von Zweidorf, A.; Angert, R.; Brüchle, W.; et al. (2003)."Final result of the CALLISTO-experiment: Formation of sodium hassate(VIII)"(PDF).Advances in Nuclear and Radiochemistry. Vol. 3. Forschungszentrum Jülich. pp. 141–143.ISBN 978-3-89336-362-9. Retrieved2023-07-11.

Sources

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Mixed oxidation states
+1 oxidation state
+2 oxidation state
+3 oxidation state
+4 oxidation state
+5 oxidation state
+6 oxidation state
+7 oxidation state
+8 oxidation state
Related
Oxides are sorted byoxidation state.Category:Oxides
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