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Gold(III) oxide

From Wikipedia, the free encyclopedia
Gold(III) oxide
Names
IUPAC name
Gold(III) oxide
Other names
Gold trioxide, Gold sesquioxide, Auric oxide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.013.748Edit this at Wikidata
EC Number
  • 215-122-1
UNII
  • InChI=1S/2Au.3O/q2*+3;3*-2
    Key: DDYSHSNGZNCTKB-UHFFFAOYSA-N
  • [O-2].[O-2].[O-2].[Au+3].[Au+3]
Properties
Au2O3
Molar mass441.93
Appearancered-brown solid
Density11.34 g/cm3 at 20 °C[1]
Melting point298 °C (568 °F; 571 K)[2]
insoluble in water, soluble in hydrochloric and nitric acid
Structure
Orthorhombic,oF40
=Fdd2, No. 43[1]
Hazards
GHS labelling:[1]
GHS07: Exclamation mark
Warning
H315,H319
P264,P264+P265,P280,P302+P352,P305+P351+P338,P321,P332+P317,P337+P317,P362+P364
NFPA 704 (fire diamond)
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound

Gold(III) oxide (Au2O3) is aninorganic compound ofgold andoxygen with the formula Au2O3. It is a red-brown solid that decomposes at 298 °C.[3]

According toX-ray crystallography, Au2O3 features square planar gold centers with both 2- and 3-coordinated oxides. The four Au-O bond distances range from 193 to 207picometers.[1] The crystals can be prepared by heating amorphous hydrated gold(III) oxide withperchloric acid and analkali metalperchlorate in a sealedquartz tube at a temperature of around 250 °C and a pressure of around 30 MPa.[4]

References

[edit]
  1. ^abcJones, P. G.; Rumpel, H.; Schwarzmann, E.; Sheldrick, G. M.; Paulus, H. (1979)."Gold(III) oxide".Acta Crystallographica Section B.35 (6): 1435.doi:10.1107/S0567740879006622.
  2. ^Kawamoto, Daisuke; Ando, Hiroaki; Ohashi, Hironori; Kobayashi, Yasuhiro; Honma, Tetsuo; Ishida, Tamao; Tokunaga, Makoto; Okaue, Yoshihiro; Utsunomiya, Satoshi; Yokoyama, Takushi (2016-11-15)."Structure of a Gold(III) Hydroxide and Determination of Its Solubility".Bulletin of the Chemical Society of Japan.89 (11). The Chemical Society of Japan:1385–1390.doi:10.1246/bcsj.20160228.ISSN 0009-2673.
  3. ^Greenwood, Norman N.; Earnshaw, Alan (1997).Chemistry of the Elements (2nd ed.).Butterworth-Heinemann.doi:10.1016/C2009-0-30414-6.ISBN 978-0-08-037941-8.
  4. ^Jones, Peter G.; Rumpel, Horst; Sheldrick, George M.; Schwarzmann, Einhard (1980)."Gold(III) oxide and oxychloride"(open access).Gold Bulletin.13 (2): 56.doi:10.1007/BF03215453.

External links

[edit]
Gold(-I)
Gold(I)
Organogold(I) compounds
Gold(II)
Gold(I,III)
Gold(III)
Aurates(III)
Gold(V)
Gold(VI)


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