Arce played at theright defender position, competing a total of 61 times for the Paraguay national team between 1995 and 2004.[1] He has the distinction of being chosen seven times as the "Ideal Team of America", thus having been nominated the most times in history. He also holds the distinction of having been selected in history as the coach on two occasions of theParaguay national team.
Arce started his career in Paraguay playing for his natal city club, 15 de Mayo, where he made his professional debut at the age of fifteen. The same year he was recruited by theCerro Porteño club in the Paraguayan capital (Asuncion), where he won three national championships. Arce then played for Brazilian clubsGrêmio andPalmeiras and won international tournaments including theCopa Libertadores. Arce played forParaguay in the1998 and2002 FIFA World Cups and has appeared 61 times for his country. He was famous for hisfree kick shot technique, where he scored goals during the2002 FIFA World Cup including afree kick againstSouth Africa.
After retiring as a player, Arce became a coach and managed the Paraguayan second division teamClub Rubio Ñú, leading the squad to the2nd division championship in 2008.[2]
In March 2013, Arce was appointed coach of the ParaguayanCerro Porteño.[5] He won theTorneo Clausura in 2013 with Cerro Porteño in highly impressive form, as the club went the entire Clausura undefeated. After a 4–1 defeat toClub Guaraní on 24 August 2014 Arce left Cerro Porteño.
On 15 March 2015, Arce was appointed manager ofOlimpia, the arch-rivals of his old club Cerro Porteño.
A year later he coached the Guarani club with good results, leading to his position at the Paraguay national team.[6] In 2018, he was appointed as manager of General Díaz.