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Fluomine

From Wikipedia, the free encyclopedia
Fluomine
Names
Other names
  • Fluomine dust
  • Cobalt(II),N,N'-ethylenebis-(3-fluorosalicyclideneiminato)-
  • Cobalt, bis(3-fluorosalicylaldehyde)ethylenediimine-
Identifiers
3D model (JSmol)
ECHA InfoCard100.057.672Edit this at Wikidata
EC Number
  • 263-458-2
  • InChI=1S/C16H14F2N2O2.Co/c17-13-3-1-5-15(21)11(13)9-19-7-8-20-10-12-14(18)4-2-6-16(12)22;/h1-6,9-10,21-22H,7-8H2;/q;+2/p-2/b19-9+,20-10+;
    Key: VUNNDCACJFYYFK-HCURTGQUSA-L
  • c12c(cccc1[O-][Co+2]13[N](=C2)CC[N]1=Cc1c(cccc1[O-]3)F)F
Properties
C16H12CoF2N2O2
Molar mass361.214 g·mol−1
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Fluomine is achemical compound containing acobaltchelate. It has the ability to form a complex withmolecular oxygen (O2) and then release it upon heating.[1] Because of this ability to reversiblysorb and desorb oxygen, it has been used in high-altitude aircraft oxygen-generating systems.[2][3]

The toxicity of fluomine has been studied[1][4] and it is classified by theEmergency Planning and Community Right-to-Know Act as anextremely hazardous substance.[5]

References

[edit]
  1. ^abKinkead, E.R.; Haun, C.C.; Bowers, R.S.; Vernot, E.H.; Mac Ewen, J.D.; Amster, R.L. (1981). "The mammalian toxicity of fluomine dust".American Industrial Hygiene Association Journal.42 (9):675–680.doi:10.1080/15298668191420503.PMID 7293930.
  2. ^Manatt, S. A. (1981). "Onboard oxygen generation systems".Aviation, Space, and Environmental Medicine.52 (11 Pt 1):645–53.PMID 7305791.
  3. ^"Breathing Oxygen: Purity of Oxygen Generated By a Fulomine-Based System"(PDF). USAF School of Aerospace Medicine, Aerospace Medical Division (AFSC). September 1976.Archived(PDF) from the original on June 1, 2022. RetrievedMarch 10, 2019.
  4. ^Kinkead, E.R.; Haun, C.C.; Bowers, R.S.; Vernot, E.H.; MacEwen, J.D.; Amster, R.L. (1982). "Six month inhalation toxicity of fluomine dust".American Industrial Hygiene Association Journal.43 (1):66–71.doi:10.1080/15298668291409361.PMID 7055087.
  5. ^40 C.F.R.: Appendix A to Part 355—The List of Extremely Hazardous Substances and Their Threshold Planning Quantities(PDF) (July 1, 2008 ed.),Government Printing Office, archived fromthe original(PDF) on 2012-02-25, retrievedMarch 8, 2009
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