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Fenoprop

From Wikipedia, the free encyclopedia
Fenoprop
Names
Preferred IUPAC name
rac-(2R)-2-(2,4,5-trichlorophenoxy)propanoic acid
Other names
2-(2,4,5-Trichlorophenoxy)propionic acid
Silvex
Identifiers
3D model (JSmol)
Abbreviations2,4,5-TP
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard100.002.066Edit this at Wikidata
KEGG
UNII
  • InChI=1S/C9H7Cl3O3/c1-4(9(13)14)15-8-3-6(11)5(10)2-7(8)12/h2-4H,1H3,(H,13,14) checkY
    Key: ZLSWBLPERHFHIS-UHFFFAOYSA-N checkY
  • InChI=1/C9H7Cl3O3/c1-4(9(13)14)15-8-3-6(11)5(10)2-7(8)12/h2-4H,1H3,(H,13,14)
    Key: ZLSWBLPERHFHIS-UHFFFAOYAC
  • Clc1cc(OC(C(=O)O)C)c(Cl)cc1Cl
Properties[1]
C9H7Cl3O3
Molar mass269.51
AppearanceWhite powder
Density1.21 g/cm3 at 20 °C
Melting point180 °C (356 °F; 453 K)
logP3.8 (20 °C)
Acidity (pKa)2.84
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Fenoprop, also called2,4,5-TP, is theorganic compound 2-(2,4,5-trichlorophenoxy)propionic acid.[2] It is aphenoxy herbicide and aplant growth regulator, ananalog of2,4,5-T in which the latter'sacetic acid sidechain is replaced with apropionate group (with an extra CH3). The addition of this extramethyl group creates achiral centre in the molecule and usefulbiological activity is found only in the (2R)-isomer.[3] The compound's mechanism of action is to mimic the auxin growth hormoneindoleacetic acid (IAA).[4] When sprayed on plants it induces rapid, uncontrolled growth. As with 2,4,5-T, fenoprop is toxic to shrubs and trees.

The name Silvex was used in the USA but it has been banned from use there since 1985. According to theEnvironmental Protection Agency its greatest use was as a postemergence herbicide for control of woody plants, and broadleaf herbaceous weeds in rice and bluegrass turf, in sugarcane, in rangeland improvement programs and on lawns.[5]Fenoprop and some of itsesters were in use from 1945 but are now obsolete.[1]

See also

[edit]

References

[edit]
  1. ^abPesticide Properties Database."Fenoprop". University of Hertfordshire. Retrieved2021-03-11.
  2. ^"Compendium of Pesticide Common Names".alanwood.net.
  3. ^Wendeborn, S.; Smits, H. (31 December 2012). "Synthetic Auxins". In Erick M. Carreira; Hisashi Yamamoto (eds.).Comprehensive Chirality.ISBN 9780080951683.
  4. ^Grossmann, K. (2010). "Auxin herbicides: current status of mechanism and mode of action".Pest Management Science.66 (2):2033–2043.doi:10.1002/ps.1860.PMID 19823992.
  5. ^US Environmental Protection Agency."Consumer Factsheet on: 2,4,5-TP (SILVEX)"(PDF). Retrieved2021-03-11.
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