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Erbium(III) selenide

From Wikipedia, the free encyclopedia
Erbium(III) selenide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.031.494Edit this at Wikidata
EC Number
  • 234-657-1
  • InChI=1S/2Er.3Se
    Key: SAJINCSOEUABRO-UHFFFAOYSA-N
  • [Se].[Se].[Se].[Er].[Er]
Properties
Er2Se3
Molar mass571.431 g·mol−1
Appearancegreen-brown[1] or yellow crystals[2]
Density6.83 g·cm−3[1]
6.855 g·cm−3[2]
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Erbium(III) selenide is an inorganic compound with a chemical formula of Er2Se3.

Preparation

[edit]

Erbium(III) selenide can be obtained by the reaction oferbium andselenium:

2 Er + 3 Se → Er2Se3

It can also be prepared by reactingerbium oxide andhydrogen selenide at high temperature.[3]

Er2O3 + 3 H2Se → Er2Se3 + 3 H2O

Properties

[edit]

Erbium(III) selenide is anorthorhombic crystal with a Sc2S3 structure and a space group ofFddd.[2] It reacts withmagnesium selenide at 1000 °C to obtain MgEr2Se4.[4]

References

[edit]
  1. ^abK.-J. Range, Ch. Eglmeier (August 1991)."Crystal data for rare earth sesquiselenides Ln2Se3 (Ln ≡ Ho, Er, Tm, Yb, Lu) and structure refinement of Er2Se3".Journal of the Less Common Metals.171 (1):L27–L30.doi:10.1016/0022-5088(91)90254-2. Retrieved2023-06-13.
  2. ^abcC.M. Fang, A. Meetsma, G.A. Wiegers (March 1995)."Crystal structure of erbium sesquiselenide, Er2Se3".Journal of Alloys and Compounds.218 (2):224–227.doi:10.1016/0925-8388(94)01394-2. Retrieved2023-06-13.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  3. ^Guittard, Micheline; Benacerraf, A.; Flahaut, J. Selenides L2Se3 and L2Se4 of rare earth elements.Ann. Chim. (Paris), 1964. 9 (1-2): 25-34. CAN61: 38017.
  4. ^D. Reig-i-Plessis, S. V. Geldern, A. A. Aczel, D. Kochkov, B. K. Clark, G. J. MacDougall (2019-04-26)."Deviation from the dipole-ice model in the spinel spin-ice candidate MgEr 2 Se 4".Physical Review B.99 (13) 134438.arXiv:1703.04267.Bibcode:2019PhRvB..99m4438R.doi:10.1103/PhysRevB.99.134438.ISSN 2469-9950.S2CID 119502480. Retrieved2023-06-13.{{cite journal}}: CS1 maint: multiple names: authors list (link)

External reading

[edit]
Salts and covalent derivatives of theselenide ion
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