Electropolishing, also known aselectrochemical polishing,anodic polishing, orelectrolytic polishing (especially in themetallography field), is anelectrochemical process that removes material from a metallic workpiece, reducing thesurface roughness by levelling micro-peaks and valleys, improving thesurface finish.[1] Electropolishing is often compared to, but distinctly different from,electrochemical machining. It is used topolish,passivate, anddeburr metal parts. It is often described as the reverse ofelectroplating.[citation needed]
It may be used in lieu ofabrasive fine polishing inmicrostructural preparation.[2]
Typically, the workpiece is immersed in a temperature-controlled bath ofelectrolyte and serves as theanode. At the cathode, areduction reaction occurs, which normally produces hydrogen. The tiny hydrogen bubbles forming on the surface of the workpiece exert a scrubbing action which can be used to clean and polish the part. Electrolytes used for electropolishing are most often concentrated acid solutions such as mixtures ofsulfuric acid andphosphoric acid. Other electropolishing electrolytes reported in the literature include mixtures ofperchloric acid withacetic anhydride (which has caused fatal explosions), andmethanolic solutions of sulfuric acid.[3]
To electropolish a rough surface, the protruding parts of a surface profile must dissolve faster than the recesses. This process, referred to asanodic leveling, can be subject to incorrect analysis when measuring the surface topography.[4] Anodic dissolution under electropolishing conditions deburrs metal objects due to increased current density on corners and burrs.Most importantly, successful electropolishing should operate under diffusion limited constant current plateau, achieved by following current dependence on voltage (polarisation curve), under constant temperature and stirring conditions.
Due to its ease of operation and its usefulness in polishing irregularly-shaped objects, electropolishing has become a common process in the production of semiconductors.
As electropolishing can also be used to sterilize workpieces, the process plays an essential role in the food, medical, and pharmaceutical industries.[5]
It is commonly used in the post-production of large metal pieces such as those used in drums of washing machines, bodies of ocean vessels and aircraft, and automobiles.
While nearly any metal may be electropolished, the most-commonly polished metals are 300- and 400-seriesstainless steel, aluminum, copper, titanium, and nickel- and copper-alloys.
Ultra-high vacuum (UHV) components are typically electropolished in order to have a smoother surface for improved vacuum pressures, out-gassing rates, and pumping speed.
Electropolishing is commonly used to prepare thin metal samples fortransmission electron microscopy andatom probe tomography[6] because the process does not mechanically deform surface layers like mechanical polishing does.