
Electron optics is a mathematical framework for the calculation of electron trajectories in the presence ofelectromagnetic fields. The termoptics is used becausemagnetic andelectrostatic lenses act upon acharged particle beam similarly tooptical lenses upon alight beam.
Electron optics calculations are crucial for the design ofelectron microscopes andparticle accelerators. In theparaxial approximation, trajectory calculations can be carried out usingray transfer matrix analysis.

Electrons are charged particles (point charges withrest mass) withspin 1/2 (hence they arefermions). Electrons can beaccelerated by suitableelectric fields, thereby acquiringkinetic energy. Given sufficient voltage, the electron can be accelerated sufficiently fast to exhibit measurablerelativistic effects. According towave particle duality, electrons can also be considered asmatter waves with properties such aswavelength,phase andamplitude.
TheHamilton's optico-mechanical analogy shows that electron beams can be modeled using concepts and mathematical formula of light beams. The electron particle trajectory formula matches the formula forgeometrical optics with a suitable electron-optical index of refraction.[1]: 745 Thisindex of refraction functions like the material properties of glass in altering the direction ray propagation. In light optics, the refractive index changes abruptly at a surface between regions of constant index: the rays are controlled with the shape of the interface. In the electron-optics, the index varies throughout space and is controlled by electromagnetic fields created outside the electron trajectories.[2]
Electrons interact with magnetic fields according to the second term of the Lorentz force: across product between the magnetic field and the electron velocity. In an infinite uniform field this results in acircular motion of the electron around the field direction with a radius given by:
wherer is the orbit radius,m is themass of an electron, is the component of the electron velocity perpendicular to the field,e is the electron charge andB is the magnitude of the applied magnetic field. Electrons that have a velocity component parallel to the magnetic field will proceed alonghelical trajectories.
In the case of an applied electrostatic field, an electron will deflect towards the positive gradient of the field. Notably, this crossing of electrostatic field lines means that electrons, as they move through electrostatic fields change the magnitude of their velocity, whereas in magnetic fields, only the velocity direction is modified.
At relativistic electron velocity the geometrical electron optical equations rely on an index of refraction that includes both the ratio of electron velocity to light and, the component of themagnetic vector potential along the electron direction:[1]: 754 where,, and are the electron mass, electron charge, and the speed of light. The first term is controlled by electrostatic lens while the second one by magnetic lens.
Although not very common, it is also possible to derive effects of magnetic structures to charged particles starting from theDirac equation.[3]
As electrons can exhibit non-particle (wave-like) effects such asinterference anddiffraction, a full analysis of electron paths must go beyond geometrical optics. Free electron propagation (invacuum) can be accurately described as ade Brogliematter wave with a wavelength inversely proportional to its longitudinal (possibly relativistic) momentum. Fortunately as long as the electromagnetic field traversed by the electron changes only slowly compared with this wavelength (see typical values inmatter wave#Applications of matter waves),Kirchhoff's diffraction formula applies.[1] The essential character of this approach is to use geometrical ray tracing but to keep track of the wave phase along each path to compute the intensity in the diffraction pattern.
As a result of the charge carried by the electron, electric fields, magnetic fields, or the electrostatic mean inner potential of thin, weakly interacting materials can impart a phase shift to the wavefront of an electron.[4] Thickness-modulatedsilicon nitride membranes and programmable phase shift devices have exploited these properties to apply spatially varying phase shifts to control the far-field spatial intensity and phase of the electron wave. Devices like these have been applied to arbitrarily shape the electron wavefront, correct theaberrations inherent toelectron microscopes, resolve theorbital angular momentum of a free electron, and to measuredichroism in the interaction between free electrons and magnetic materials or plasmonic nanostructures.[5]
Electrons interact strongly with matter as they are sensitive to not only the nucleus, but also the matter's electron charge cloud. Therefore, electrons requirevacuum to propagate any reasonable distance, such as would be desirable in electron optic system.
Penetration in vacuum is dictated bymean free path, a measure of the probability of collision between electrons and matter, approximate values for which can be derived fromPoisson statistics.
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