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Dysprosium(III) fluoride

From Wikipedia, the free encyclopedia
Dysprosium(III) fluoride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.033.615Edit this at Wikidata
EC Number
  • 236-992-9
  • InChI=1S/Dy.3FH/h;3*1H/q+3;;;/p-3
    Key: FWQVINSGEXZQHB-UHFFFAOYSA-K
  • F[Dy](F)F
Properties
DyF3
Molar mass219.50
AppearanceWhite crystalline powder
Density6.9 g/cm3
Melting point1,740 °C
Hazards
GHS labelling:
GHS07: Exclamation mark
Warning
H315,H319,H335
Related compounds
Otheranions
Dysprosium(III) chloride,Dysprosium(III) bromide,Dysprosium(III) iodide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Dysprosium(III) fluoride is aninorganic compound ofdysprosium with achemical formula DyF3.

Production

[edit]

Dysprosium(III) fluoride can be produced by mixingdysprosium(III) chloride ordysprosium(III) carbonate into 40%hydrofluoric acid.[1]

DyCl3 + 3 HF → DyF3 + 3 HCl
Dy2(CO3)3 + 6 HF → 2 DyF3 + 3 H2O + 3 CO2

DyF3 can also be produced by hydrothermal reaction ofdysprosium nitrate andsodium tetrafluoroborate at 200 °C.[2]

DyF3 can also be produced whendysprosium oxide andammonium bifluoride are mixed and heated to 300 °C until the oxide is porous, and continued to heat to 700 °C. Whenhydrogen fluoride is introduced, a reaction occurs:[3]

Dy2O3 + 6 HF → 2 DyF3 + 3 H2O

Properties

[edit]

Dysprosium(III) fluoride is a white, odorless solid that is insoluble in water.[4] It has anorthorhombic crystal structure with the space group Pnma (space group no. 62).[5]

References

[edit]
  1. ^Wang Ya-jun, Suo Quan-ling, Hao Dong-sheng, Liu Qian, Guo Feng. 稀土氟化物的沉淀方法及组成研究 (in Chinese) (lit. Precipitation and composition of rare earth fluorides). Chinese Rare Earths, 2000, 21 (1): 14-18.
  2. ^孙元平, 贾佩云, 王芳, 等. 水热条件下稀土氟化物形貌的规律性生长[J]. 中国陶瓷, 2013(6).
  3. ^刘文生, 云月厚, 李国栋. 干法氟化制备高纯金属镝的工艺研究[J]. 稀有金属, 2003, 27(1):154-156.
  4. ^Dysprosium(III) fluoride at AlfaAesar, accessed on 2023-12-22 (PDF) (JavaScript required).[dead link]
  5. ^Ans, Jean d'; Lax, Ellen (1998).Taschenbuch für Chemiker und Physiker (in German). Springer.ISBN 978-3-540-60035-0.
Dy(II)
Dy(III)
Salts and covalent derivatives of thefluoride ion
HF?HeF2
LiFBeF2BF
BF3
B2F4
+BO3
CF4
CxFy
+CO3
NF3
FN3
N2F2
NF
N2F4
NF2
?NF5
+N
+NO3
OF2
O2F2
OF
O3F2
O4F2
?OF4
F2Ne
NaFMgF2AlF
AlF3
SiF4P2F4
PF3
PF5
+PO4
S2F2
SF2
S2F4
SF3
SF4
S2F10
SF6
+SO4
ClF
ClF3
ClF5
?ArF2
?ArF4
KFCaF
CaF2
ScF3TiF2
TiF3
TiF4
VF2
VF3
VF4
VF5
CrF2
CrF3
CrF4
CrF5
?CrF6
MnF2
MnF3
MnF4
?MnF5
FeF2
FeF3
FeF4
CoF2
CoF3
CoF4
NiF2
NiF3
NiF4
CuF
CuF2
?CuF3
ZnF2GaF2
GaF3
GeF2
GeF4
AsF3
AsF5
Se2F2
SeF4
SeF6
+SeO3
BrF
BrF3
BrF5
KrF2
?KrF4
?KrF6
RbFSrF
SrF2
YF3ZrF2
ZrF3
ZrF4
NbF4
NbF5
MoF4
MoF5
MoF6
TcF4
TcF
5

TcF6
RuF3
RuF
4

RuF5
RuF6
RhF3
RhF4
RhF5
RhF6
PdF2
Pd[PdF6]
PdF4
?PdF6
Ag2F
AgF
AgF2
AgF3
CdF2InF
InF3
SnF2
SnF4
SbF3
SbF5
TeF4
?Te2F10
TeF6
+TeO3
IF
IF3
IF5
IF7
+IO3
XeF2
XeF4
XeF6
?XeF8
CsFBaF2 LuF3HfF4TaF5WF4
WF5
WF6
ReF4
ReF5
ReF6
ReF7
OsF4
OsF5
OsF6
?OsF
7

?OsF
8
IrF2
IrF3
IrF4
IrF5
IrF6
PtF2
Pt[PtF6]
PtF4
PtF5
PtF6
AuF
AuF3
Au2F10
?AuF6
AuF5•F2
Hg2F2
HgF2
?HgF4
TlF
TlF3
PbF2
PbF4
BiF3
BiF5
PoF2
PoF4
PoF6
AtF
?AtF3
?AtF5
RnF2
?RnF
4

?RnF
6
FrFRaF2 LrF3RfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
LaF3CeF3
CeF4
PrF3
PrF4
NdF2
NdF3
NdF4
PmF3SmF
SmF2
SmF3
EuF2
EuF3
GdF3TbF3
TbF4
DyF2
DyF3
DyF4
HoF3ErF3TmF2
TmF3
YbF2
YbF3
AcF3ThF2
ThF3
ThF4
PaF4
PaF5
UF3
UF4
UF5
UF6
NpF3
NpF4
NpF5
NpF6
PuF3
PuF4
PuF5
PuF6
AmF2
AmF3
AmF4
?AmF6
CmF3
CmF4
 ?CmF6
BkF3
BkF
4
CfF3
CfF4
EsF3
EsF4
?EsF6
FmMdF3No
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