Movatterモバイル変換


[0]ホーム

URL:


Jump to content
WikipediaThe Free Encyclopedia
Search

Dysprosium(II) iodide

From Wikipedia, the free encyclopedia
Dysprosium(II) iodide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.151.507Edit this at Wikidata
EC Number
  • 622-765-5
  • InChI=1S/Dy.2HI/h;2*1H/p-2
    Key: SSDFPWIJYIKUFK-UHFFFAOYSA-L
  • [I-].[I-].[Dy+2]
Properties
DyI2
Molar mass416.309 g·mol−1
Appearancedark purple-black solid[1]
Melting point659 °C[1]
Hazards
GHS labelling:[2]
GHS07: Exclamation mark
Warning
H315,H319,H335
P261,P264,P264+P265,P271,P280,P302+P352,P304+P340,P305+P351+P338,P319,P321,P332+P317,P337+P317,P362+P364,P403+P233,P405,P501
Related compounds
Otheranions
dysprosium(II) chloride
dysprosium(II) bromide
Related compounds
dysprosium(III) iodide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Dysprosium(II) iodide is aniodide ofdysprosium with thechemical formula DyI2.

Preparation

[edit]

Dysprosium(II) iodide can be produced by reducingdysprosium(III) iodide with metallicdysprosium under a vacuum at 800 to 900 °C:[1]

Dy + 2 DyI3 → 3 DyI2

It can also be formed by the reaction of dysprosium andmercury(II) iodide:[1]

Dy + HgI2 → DyI2 + Hg

It can also be formed by the direct reaction of dysprosium andiodine.[3]

Dy + I2 → DyI2

Properties

[edit]

Dysprosium(II) iodide is a dark purple-black solid that is easilydeliquescent and can only be stored in a dry inert gas or a vacuum. In the air, it will absorb moisture and become a hydrate, but they are unstable and will quickly convert into iodide oxides and releasehydrogen gas. This process occurs faster in the presence ofwater. This compound has the same crystal structure ascadmium chloride.[1] It can form complexes withtetrahydrofuran,butanol andphenol.[3]

Uses

[edit]

The reaction between dysprosium(II) iodide andsilicon tetrachloride producestrichlorosilyl radicals, which can catalyze the trimerization ofalkynes.[4][5]

References

[edit]
  1. ^abcdeHandbuch der präparativen anorganischen Chemie. 1 (3., umgearb. Aufl ed.). Stuttgart: Enke. 1975.ISBN 978-3-432-02328-1.
  2. ^"Dysprosium(II) iodide".pubchem.ncbi.nlm.nih.gov.
  3. ^abKarl A. Jr. Gschneidner, Jean-Claude Bunzli, Vitalij K. Pecharsky (2009).Handbook on the Physics and Chemistry of Rare Earths. Elsevier. p. 247.ISBN 978-008093257-6.{{cite book}}: CS1 maint: multiple names: authors list (link)
  4. ^Sigma-Aldrich Co.,product no. 652423.
  5. ^Zhu, Zhenyu; Wang, Chuanfeng; Xiang, Xu; Pi, Chengfu; Zhou, Xigeng (2006)."DyI2 initiated mild and highly selective silyl radical-catalyzed cyclotrimerization of terminal alkynes and polymerization of MMA".Chemical Communications (19):2066–2068.doi:10.1039/b602883g.ISSN 1359-7345.PMID 16767277.
Dy(II)
Dy(III)
Salts and covalent derivatives of theiodide ion
Retrieved from "https://en.wikipedia.org/w/index.php?title=Dysprosium(II)_iodide&oldid=1292656627"
Categories:
Hidden categories:

[8]ページ先頭

©2009-2026 Movatter.jp