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Disodium phosphate

From Wikipedia, the free encyclopedia
Disodium phosphate
Structural formula of disodium phosphate
Ball-and-stick model of the component ions of disodium phosphate
  Sodium, Na
  Phosphorus, P
  Oxygen, O
  Hydrogen, H
Names
IUPAC name
Disodium hydrogen phosphate
Other names
  • Acetest
  • Dibasic sodium phosphate
  • Disodium hydrogen orthophosphate
  • Disodium hydrogen phosphate
  • Disodium phosphate
  • Sodium phosphate dibasic
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard100.028.590Edit this at Wikidata
EC Number
  • 231-448-7
E numberE339(ii)(antioxidants, ...)
RTECS number
  • WC4500000
UNII
  • InChI=1S/2Na.H3O4P/c;;1-5(2,3)4/h;;(H3,1,2,3,4)/q2*+1;/p-3 ☒N
    Key: BNIILDVGGAEEIG-UHFFFAOYSA-K ☒N
  • InChI=1/2Na.H3O4P/c;;1-5(2,3)4/h;;(H3,1,2,3,4)/q2*+1;/p-3
    Key: BNIILDVGGAEEIG-DFZHHIFOAK
  • OP(=O)([O-])[O-].[Na+].[Na+]
Properties
Na2HPO4
Molar mass
  • 141.96 g/mol (anhydrous)
  • 177.99 g/mol (dihydrate)
  • 268.07 g/mol (heptahydrate)
AppearanceWhite crystalline solid
OdorOdorless
Density1.7 g/cm3
Melting point250 °C (482 °F; 523 K) Decomposes
7.7 g/(100 ml) (20 °C)
11.8 g/(100 ml) (25 °C, heptahydrate)
SolubilityInsoluble inethanol
logP−5.8
Acidity (pKa)12.35
−56.6·10−6 cm3/mol
1.35644 to 1.35717 at 20°C
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Irritant
NFPA 704 (fire diamond)
Flash pointNon-flammable
Lethal dose or concentration (LD, LC):
17000 mg/kg (rat, oral)
Safety data sheet (SDS)ICSC 1129
Related compounds
Otheranions
sodium phosphite
Othercations
Dipotassium phosphate
Diammonium phosphate
Related compounds
Monosodium phosphate
Trisodium phosphate
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Chemical compound

Disodium phosphate (DSP), ordisodium hydrogen phosphate, orsodium phosphate dibasic, is aninorganic compound with thechemical formulaNa2HPO4. It is one of severalsodium phosphates. Thesalt is known inanhydrous form as well ashydratesNa2HPO4·nH2O, wheren is 2, 7, 8, and 12. All are water-soluble white powders. The anhydrous salt ishygroscopic.[1]

ThepH of disodium hydrogen phosphate water solution is between 8.0 and 11.0, meaning it is moderatelybasic:

HPO2−4 + H2O ⇌ H2PO4 + OH

Production and reactions

[edit]

It can be generated by neutralization ofphosphoric acid withsodium hydroxide:

H3PO4 + 2 NaOH → Na2HPO4 + 2 H2O

Industrially It is prepared in a two-step process by treatingdicalcium phosphate withsodium bisulfate, which precipitatescalcium sulfate:[2]

CaHPO4 + NaHSO4 → NaH2PO4 + CaSO4

In the second step, the resulting solution of monosodium phosphate is partially neutralized:

NaH2PO4 + NaOH → Na2HPO4 + H2O

Uses

[edit]

It is used in conjunction withtrisodium phosphate in foods and water softening treatment. In foods, it is used to adjust pH. Its presence prevents coagulation in the preparation of condensed milk. Similarly, it is used as an anti-caking additive in powdered products.[3] It is used in desserts and puddings, e.g.Cream of Wheat to quicken cook time, and Jell-OInstant Pudding for thickening. In water treatment, it retardscalcium scale formation.[citation needed] It is also found in some detergents and cleaning agents.[2]

Heating solid disodium phosphate gives the useful compoundtetrasodium pyrophosphate:[citation needed]

2 Na2HPO4 → Na4P2O7 + H2O

Laxative

[edit]

Monobasic and dibasic sodium phosphate are used as asaline laxative to treatconstipation or to clean the bowel before acolonoscopy.[4]

References

[edit]
  1. ^"Physical data (pdf)"(PDF). Archived fromthe original(PDF) on 2011-07-17. Retrieved2007-03-06.
  2. ^abKlaus Schrödter, Gerhard Bettermann, Thomas Staffel, Friedrich Wahl, Thomas Klein, Thomas Hofmann "Phosphoric Acid and Phosphates" inUllmann’s Encyclopedia of Industrial Chemistry 2008, Wiley-VCH, Weinheim.doi:10.1002/14356007.a19_465.pub3
  3. ^"MSDS". Archived fromthe original on 2017-10-28. Retrieved2011-09-26.
  4. ^"Sodium Phosphate, Dibasic, Sodium Phosphate, Monobasic Oral solution". Krames Patient Education. Archived fromthe original on 2013-01-28. Retrieved2009-10-29.

External links

[edit]
  • Media related toDisodium phosphate at Wikimedia Commons solubility in Prophylaxis alcohol
Inorganic
Halides
Chalcogenides
Pnictogenides
Oxyhalides
Oxychalcogenides
Oxypnictogenides
Metalates
Others
Organic
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