Movatterモバイル変換


[0]ホーム

URL:


Jump to content
WikipediaThe Free Encyclopedia
Search

Dimethenamid

From Wikipedia, the free encyclopedia
Dimethenamid[1][2]
Names
IUPAC name
(RS)-2-Chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)acetamide
Other names
Frontier Herbicide
Dimethenamid-P ((S)-isomer)
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard100.121.887Edit this at Wikidata
EC Number
  • 618-045-5
KEGG
RTECS number
  • AB5444200
UNII
  • InChI=1S/C12H18ClNO2S/c1-8-7-17-10(3)12(8)14(11(15)5-13)9(2)6-16-4/h7,9H,5-6H2,1-4H3 checkY
    Key: JLYFCTQDENRSOL-UHFFFAOYSA-N checkY
  • InChI=1/C12H18ClNO2S/c1-8-7-17-10(3)12(8)14(11(15)5-13)9(2)6-16-4/h7,9H,5-6H2,1-4H3
    Key: JLYFCTQDENRSOL-UHFFFAOYAR
  • CC1=CSC(=C1N(C(C)COC)C(=O)CCl)C
  • ClCC(=O)N(c1c(scc1C)C)C(COC)C
Properties
C12H18ClNO2S
Molar mass275.79 g/mol
AppearanceTan to brown liquid
Density1.141 g/cm3
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Xn (harmful)
GHS labelling:
GHS07: Exclamation markGHS09: Environmental hazard
Warning
H302,H317,H332,H410,H411
P261,P264,P270,P271,P272,P273,P280,P301+P312,P302+P352,P304+P312,P304+P340,P312,P321,P330,P333+P313,P363,P391,P501
Flash point151 °C (304 °F; 424 K)
Safety data sheet (SDS)MSDS fromBASF
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Chemical compound

Dimethenamid is a widely usedherbicide belonging to the chloroacetamide class (group 15). Group 15 herbicides inhibit synthesis of certain long-chain fatty acids, thus reducing plant growth.[3] In 2001, about 7 million pounds (3,200 t) of dimethenamid were used in the United States.[4] Dimethenamid is registered for control of annual grasses, certain annual broadleaf weeds and sedges in field corn, seed corn, popcorn and soybeans. Supplemental labeling also allows use on sweet corn, grain sorghum, dry beans and peanuts. In registering dimethinamide (SAN 582H/Frontier), EPA concluded that the primary means of dissipation of dimethenamid applied to the soil surface isphotolysis, whereas below the surface loss was due largely to microbial metabolism. The herbicide was found to undergo anaerobic microbial degradation under denitrifying, iron-reducing, sulfate-reducing, or methanogenic conditions.[5] In that study, more than half of the herbicide carbon (based on14C-labeling) added was found to be incorporated irreversibly into soil-bound residue.

References

[edit]
  1. ^Dimethenamid atSigma-Aldrich
  2. ^Material Safety Data Sheet[permanent dead link] fromBASF
  3. ^Lamberth, C. (2016). Chloroacetamide Herbicides. In Bioactive Carboxylic Compound Classes (eds C. Lamberth and J. Dinges).https://doi.org/10.1002/9783527693931.ch21
  4. ^2000-2001 Pesticide Market EstimatesArchived 2009-02-07 at theWayback Machine,U.S. Environmental Protection Agency
  5. ^Crawford, J.J.; Sims, G. K.; Simmons, F. W.; Wax, L. M.; Freedman, D. L. (2002). "Dissipation of the herbicide (14C) Dimethenamid under anaerobic aquatic conditions in flooded soil microcosms".J. Agric. Food Chem.50 (6):61483–1491.doi:10.1021/jf010612i.PMID 11879025.
Anilides/anilines
Aromaticacids
Arsenicals
HPPD inhbitors
Nitriles
Organophosphorus
Phenoxy
Auxins
ACCase inhibitors
FOP herbicides
DIM herbicides
Protox inhibitors
Nitrophenyl ethers
Pyrimidinediones
Triazolinones
Pyridines
Quaternary
Photosystem I inhibitors
Thiocarbamates
Triazines
cellulose biosynthesis inhibitors
Photosystem II inhibitors
Ureas
Photosystem II inhibitors
ALS inhibitors
Others
Retrieved from "https://en.wikipedia.org/w/index.php?title=Dimethenamid&oldid=1227328761"
Categories:
Hidden categories:

[8]ページ先頭

©2009-2026 Movatter.jp