Movatterモバイル変換


[0]ホーム

URL:


Jump to content
WikipediaThe Free Encyclopedia
Search

Dichloramine

From Wikipedia, the free encyclopedia
Dichloramine
Names
IUPAC name
Azonous dichloride
Other names
Chlorimide
Identifiers
3D model (JSmol)
ChemSpider
UNII
  • InChI=1S/Cl2HN/c1-3-2/h3H checkY
    Key: JSYGRUBHOCKMGQ-UHFFFAOYSA-N checkY
  • InChI=1/Cl2HN/c1-3-2/h3H
    Key: JSYGRUBHOCKMGQ-UHFFFAOYAB
  • ClNCl
Properties
NHCl2
Molar mass85.92 g·mol−1
Appearanceyellow gas[1]
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Chemical compound

Dichloramine (IUPAC name:Azonous dichloride) is a reactiveinorganic compound with thechemical formulaNHCl2. It is one of the threechloramines ofammonia, the others beingmonochloramine (NH2Cl) andnitrogen trichloride (NCl3). This yellow gas is unstable and reacts with many materials.[1] It is formed by a reaction betweenammonia andchlorine orsodium hypochlorite. It is a byproduct formed during the synthesis of monochloramine and nitrogen trichloride.

Synthesis

[edit]

Dichloramine can be prepared by a reaction betweenmonochloramine andchlorine orsodium hypochlorite:[1]

NH2Cl + Cl2 → NHCl2 +HCl

Reactions

[edit]

Dichloramine reacts with thehydroxide ion, which can be present inwater or comes from water molecules, to yieldnitroxyl and thechloride ion.[2]

References

[edit]
  1. ^abcHolleman-Wiberg: Lehrbuch der Anorganischen Chemie, 102. Auflage, Berlin 2007,ISBN 978-3-11-017770-1.
  2. ^White, George Clifford (1986).The handbook of chlorination (2nd ed.). New York: Van Nostrand Reinhold. p. 169.ISBN 0-442-29285-6.
Nitrogen species
Hydrides
Organic
Oxides
Halides
Oxidation states
−3,−2,−1, 0,+1,+2,+3,+4,+5 (a stronglyacidic oxide)
Retrieved from "https://en.wikipedia.org/w/index.php?title=Dichloramine&oldid=1305955363"
Categories:
Hidden categories:

[8]ページ先頭

©2009-2025 Movatter.jp