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Dibromine pentoxide

From Wikipedia, the free encyclopedia
Dibromine pentoxide
Names
IUPAC name
Dibromine pentoxide
Other names
Bromine pentoxide
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/Br2O5/c3-1(4)7-2(5)6
    Key: NWWZVGMDNVSHDB-UHFFFAOYSA-N
  • O=[Br](=O)O[Br](=O)=O
Properties
Br2O5
Molar mass239.805 g/mol
Appearancecolorless solid
Melting pointdecomposes around −20°C[1]
Related compounds
Otheranions
Bromine dioxide
Bromine trifluoride
Bromine pentafluoride
Othercations
Oxygen difluoride
Dichlorine monoxide
Chlorine dioxide
Iodine dioxide
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound

Dibromine pentoxide is thechemical compound composed ofbromine andoxygen with theformula Br2O5. It is a colorless solid that is stable below −20 °C. It has the structure O2Br−O−BrO2, the Br−O−Br bond is bent with bond angle 121.2°. Each BrO3 group is pyramidal with the bromine atom at the apex.[2]

Preparation

[edit]

Dibromine pentoxide can be prepared by reacting a solution of bromine indichloromethane withozone at low temperatures and recrystallized frompropionitrile.[1][2]

References

[edit]
  1. ^abPerry, Dale L.; Phillips, Sidney L. (1995),Handbook of Inorganic Compounds, CRC Press, p. 74,ISBN 0-8493-8671-3, retrieved25 August 2015
  2. ^abWiberg, Egon (2001). Wiberg, Nils (ed.).Inorganic chemistry (1st ed.). San Diego, Calif.: Academic Press. p. 464.ISBN 9780123526519.
Br(−I)
Br(−I,I)
Br(I)
Br(II)
Br(I,V)
Br(III)
Br(IV)
Br(V)
Br(VII)


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