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Diaspore

From Wikipedia, the free encyclopedia
Aluminium hydroxide oxide mineral
Not to be confused withdiaspora.
For the plant seed structure, seediaspore (botany).
Diaspore
General
CategoryOxide mineral
Formulaα-AlO(OH)
IMA symbolDsp[1]
Strunz classification4.FD.10
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H–M symbol: (2/m 2/m 2/m)
Space groupPbnm
Unit cella = 4.4007(6) Å
b = 9.4253(13) Å
c = 2.8452(3) Å;Z = 4
Identification
ColorWhite, pale gray, colorless, greenish gray, brown, pale yellow, pink, purple; may exhibit color change
Crystal habitPlaty, elongated toacicular crystals; also stalactitic, foliated, scaly, disseminated, and massive
TwinningForms heart shaped twins on {021} or pseudohexagonal aggregates
Cleavage{010} perfect, {110} distinct, {100} in traces
FractureConchoidal
TenacityVery brittle
Mohs scale hardness6.5–7.0
LusterAdamantine, vitreous, pearly on cleavage faces
DiaphaneityTransparent to translucent
Specific gravity3.1–3.4
Optical propertiesBiaxial (+)
Refractive indexnα = 1.682–1.706
nβ = 1.705–1.725
nγ = 1.730–1.752
Birefringenceδ = 0.048
PleochroismStrong
2V angleMeasured: 84–86°
Calculated: 80–84°
Dispersionr <v, weak
FusibilityInfusible
SolubilityInsoluble
Other characteristicsDecrepitates releasing water in closed tube on heating
References[2][3]

Diaspore (/ˈd.əˌspɔːr/) – also calleddiasporite,empholite,kayserite, ortanatarite – is analuminium hydroxide oxide mineral, α-AlO(OH), crystallizing in theorthorhombic system andisomorphous withgoethite. It occurs sometimes as flattened crystals, but usually as lamellar or scaly masses, the flattened surface being a direction of perfectcleavage on which thelustre is markedly pearly in character. It is colorless or greyish-white, yellowish, sometimes violet in color, and varies fromtranslucent to transparent.[4] It may be readily distinguished from other colorless transparent minerals with a perfect cleavage and pearly luster (e.g.mica,talc,brucite, andgypsum) by its greater hardness of 6.5–7. Itsspecific gravity is 3.4. When heated before the blowpipe, itdecrepitates violently, breaking up into white pearly scales.[5]

The mineral occurs as an alteration product ofcorundum oremery and is found in granularlimestone and other crystalline rocks. Well-developed crystals are found in the emery deposits of theUral Mountains and atChester, Massachusetts, and inkaolin at Schemnitz inHungary. If obtainable in large quantity, it would be of economic importance as a source ofaluminium.[5]

Diaspore, along withgibbsite andboehmite, is a major component of the aluminiumorebauxite.[3]

It was first described in 1801 for an occurrence in Mramorsk Zavod,Sverdlovskaya Oblast, MiddleUrals,Russia. The name, which was coined byRené Just Haüy,[6] is from theAncient Greekδιασπείρω meaning "to scatter", in allusion to its decrepitation on heating.[2]

Csarite,ottomanite,Turkizite andzultanite are trade names for gem-quality diaspore (also known as Turkish diaspore) from theİlbir Mountains of southwestTurkey.[7]

References

[edit]
  1. ^Warr, L. N. (2021)."IMA–CNMNC approved mineral symbols".Mineralogical Magazine.85 (3):291–320.Bibcode:2021MinM...85..291W.doi:10.1180/mgm.2021.43.S2CID 235729616.
  2. ^abHandbook of Mineralogy
  3. ^abKlein, Cornelis; Hurlbut, Cornelius S. (1985).Manual of Mineralogy (20th ed.).Wiley. p. 318.ISBN 0-471-80580-7.
  4. ^"The mineral diaspore". minerals.net. Retrieved2014-06-10.
  5. ^ab One or more of the preceding sentences incorporates text from a publication now in thepublic domainSpencer, Leonard James (1911). "Diaspore". InChisholm, Hugh (ed.).Encyclopædia Britannica. Vol. 8 (11th ed.). Cambridge University Press. pp. 168–169.
  6. ^Spencer 1911.
  7. ^Hatipoğlu, Murat; Türk, Necdet; Chamberlain, Steven C.; Akgün, A. Murat (2010). "Gem-quality transparent diaspore (zultanite) in bauxite deposits of the İlbir Mountains, Menderes Massif, SW Turkey".Mineralium Deposita.45 (2):201–205.doi:10.1007/s00126-009-0262-2.
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