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Dialane

From Wikipedia, the free encyclopedia
Dialane
Names
IUPAC name
Dialumane(6)
Other names
Dialumane, dialane
Identifiers
3D model (JSmol)
  • InChI=1S/Al2H6/c1-3-2-4-1/h1-2H2
  • [AlH2]1[H][AlH2][H]1
Properties
Al2H6
Molar mass60.011 g·mol−1
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Dialane is an unstable compound ofaluminium andhydrogen with formula Al2H6.[1][2][3] Dialane is unstable in that it reacts with itself to form a polymer,aluminium hydride. Isolated molecules can be stabilised and studied insolid hydrogen.[2]

References

[edit]
  1. ^Tian, Shan Xi (May 2005). "Dialane Anion: Three-Center Two-Electron or Two-Center One-Electron Bonded".The Journal of Physical Chemistry A.109 (20):4428–4430.Bibcode:2005JPCA..109.4428T.doi:10.1021/jp051479q.PMID 16833776.
  2. ^abAndrews, Lester; Wang, Xuefeng (28 March 2003). "The Infrared Spectrum of Al 2 H 6 in Solid Hydrogen".Science.299 (5615):2049–2052.doi:10.1126/science.1082456.PMID 12663923.
  3. ^Goebbert, Daniel J.; Hernandez, Heriberto; Francisco, Joseph S.; Wenthold, Paul G. (24 August 2005). "The Binding Energy and Bonding in Dialane".Journal of the American Chemical Society.127 (33):11684–11689.Bibcode:2005JAChS.12711684G.doi:10.1021/ja0424070.PMID 16104745.
Alkali metal
(Group 1) hydrides
Alkaline (Group 2)
earth hydrides
Monohydrides
Dihydrides
Group 13
hydrides
Boranes
Alanes
Gallanes
Indiganes
Thallanes
Nihonanes(predicted)
  • NhH
  • NhH3
  • Nh2H6
  • NhH5
Group 14 hydrides
Hydrocarbons
Silanes
Silenes
Silynes
Germanes
Stannanes
Plumbanes
Flerovanes(predicted)
  • FlH
  • FlH2
  • FlH4
Pnictogen
(Group 15) hydrides
Azanes
Azenes
Phosphanes
Phosphenes
Arsanes
Stibanes
Bismuthanes
Moscovanes
Hydrogen
chalcogenides
(Group 16 hydrides)
Polyoxidanes
Polysulfanes
Selanes
Tellanes
Polanes
Livermoranes
Hydrogen halides
(Group 17 hydrides)
  • HF
  • HCl
  • HBr
  • HI
  • HAt
  • HTs(predicted)
  • Transition
    metal hydrides
    Lanthanide
    hydrides
    Actinide
    hydrides
    Exotic matter hydrides


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