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Coconut oil

From Wikipedia, the free encyclopedia
For the EP by Lizzo, seeCoconut Oil (EP).
Coconut oil
Edible oil derived from coconut

Coconut oil (orcoconut fat) is an edible oil derived from the meat of thecoconut palm fruit.[1][2] Coconut oil is a white solidfat below around 25 °C (77 °F), and a clear thin liquid oil at higher temperatures. Unrefined varieties have a distinct coconut aroma.[2] Coconut oil is used as a food oil, and in industrial applications forcosmetics anddetergent production.[1][2] The oil is rich inmedium-chain fatty acids.[3]

Due to its high levels ofsaturated fat, numerous health authorities recommend limiting its consumption as a food.[2][4][5]

Coconut oil is widely used forcooking and baking due to its high smoke point and distinct flavor.

Manufacturing

[edit]

Coconut oil can be extracted through a wet or dry process.[1] More simply (but perhaps less effectively), oil can be produced by heating the meat via boiling water, the sun or a slow fire.[6]

Wet process

[edit]
Traditional (lana) extraction directly fromthe milk in thePhilippines. The process also produceslatik (curds), used as agarnish in Filipino desserts.

The all-wet process usescoconut milk extracted from raw coconut rather than driedcopra. The proteins in the coconut milk create anemulsion of oil and water.[7] The more problematic step is breaking up the emulsion to recover the oil. This used to be done by prolonged boiling, but this produces a discolored oil and is not economical. Modern techniques usecentrifuges and pre-treatments including cold, heat, acids, salts,enzymes,electrolysis, shock waves,steam distillation, or some combination thereof. Despite numerous variations and technologies, wet processing is less viable than dry processing due to a 10–15% lower yield, even taking into account the losses due to spoilage and pests with dry processing. Wet processes also require investment in equipment and energy, incurring high capital and operating costs.[8]

Dry process

[edit]
Traditional way of making coconut oil using an ox-powered mill in Seychelles
Traditional manufacturing inSeychelles

Dry processing requires that the meat be extracted from the shell and dried using fire, sunlight, orkilns to create copra.[9] The copra is pressed or dissolved withsolvents, producing the coconut oil and a high-protein, high-fiber mash. The mash is of poor quality for human consumption and is instead fed toruminants; there is no process to extract protein from the mash.

Proper harvesting of the coconut (the age of a coconut can be 2 to 20 months when picked) makes a significant difference in the efficacy of the oil-making process. Copra made from immature nuts is more difficult to work with and produces an inferior product with lower yields.[10]

Conventional coconut oil processors usehexane as a solvent to extract up to 10% more oil than is produced with justrotary mills andexpellers. They then refine the oil to remove certainfree fatty acids to reduce susceptibility to rancidification. Other processes to increase shelf life include using copra with a moisture content below 6%, keeping the moisture content of the oil below 0.2%, heating the oil to 130–150 °C (266–302 °F) and addingsalt orcitric acid.[11]

Virgin oil

[edit]

Virgin coconut oil (VCO) can be produced from fresh coconut milk, meat, or residue. Producing it from the fresh meat involves either wet-milling or drying the residue, and using ascrew press to extract the oil. VCO can also be extracted from fresh meat by grating and drying it to a moisture content of 10–12%, then using a manual press to extract the oil. Producing it from coconut milk involves grating the coconut and mixing it with water, then squeezing out the oil. The milk can also be fermented for 36–48 hours, the oil removed, and the cream heated to remove any remaining oil. A third option involves using a centrifuge to separate the oil from the other liquids. Coconut oil can also be extracted from the dry residue left over from the production of coconut milk.[11]

A thousand mature coconuts weighing approximately 1,440 kilograms (3,170 pounds)[clarification needed] yield around 170 kg (370 lb) of copra from which around 70 litres (15 imp gal) of coconut oil can be extracted.[12]

Refined oil

[edit]
Coconut oil on a wooden spoon

Refined, bleached, and deodorized (RBD) oil is usually made from copra and dried coconut kernels, which are pressed in a heatedhydraulic press to extract the oil. This yields practically all the oil present, amounting to more than 60% of the dry weight of the coconut. This crude coconut oil is not suitable for consumption because it contains contaminants and must be refined with further heating and filtering.[13]

Another method for extraction of coconut oil involves theenzymatic action ofalpha-amylase,polygalacturonases, andproteases on diluted coconut paste.[14]

Unlike virgin coconut oil, refined coconut oil has no coconut taste or aroma. RBD oil is used for home cooking, commercial food processing, and cosmetic, industrial, and pharmaceutical purposes.

Hydrogenation

[edit]

RBD coconut oil can be processed further into partially or fullyhydrogenated oil to increase its melting point. Since virgin and RBD coconut oils melt at 24 °C (75 °F), foods containing coconut oil tend to melt in warm climates. A higher melting point is desirable in these warm climates, so the oil is hydrogenated. The melting point of hydrogenated coconut oil is 36–40 °C (97–104 °F).

In the process of hydrogenation, unsaturated fats (monounsaturated and polyunsaturated fatty acids) are combined with hydrogen in a catalytic process to make them more saturated. Coconut oil contains only 6% monounsaturated and 2% polyunsaturated fatty acids. In the partial hydrogenation process, some of these are transformed intotrans fatty acids.[15]

Fractionation

[edit]

Fractionated coconut oil provides fractions of the whole oil so that its different fatty acids can be separated for specific uses.Lauric acid, a 12-carbon chain fatty acid, is often removed because of its high value for industrial and medical purposes.[16] The fractionation of coconut oil can also be used to isolatecaprylic acid andcapric acid, which aremedium-chain triglycerides, as these are used for medical applications, special diets and cosmetics, sometimes also being used as a carrier oil for fragrances.[17]

Coconut oil production – 2020
(millions oftonnes)
 Philippines0.96
 Indonesia0.60
 India0.34
 Vietnam0.18
 Mexico0.13
World2.61
Source:FAOSTAT
of theUnited Nations[18]

Standards

[edit]

The World Health Organization'sCodex Alimentarius guidelines on food, food production, and food safety, published by theFood and Agriculture Organization, includes standards for commercial partners who produce coconut oil for human consumption.[19]

TheAsian and Pacific Coconut Community (APCC), whose 18 members produce about 90 per cent of the coconut sold commercially,[20] has published its standards for virgin coconut oil (VCO), defining virgin coconut oil as obtained from fresh, mature coconut kernels through means that do not "lead to alteration of the oil."[21]

Pests

[edit]

Oil quality and production are dependent upon palm cultivation, which is threatened bycoconut pests, such as theOryctes rhinoceros beetles – especially the Asiatic rhinoceros beetle (O. rhinoceros) – and the red palm weevil (Rhynchophorus ferrugineus).[22]

Production

[edit]

In 2020, world production of coconut oil was 2.61 million metric tons (2.88 million short tons), led by thePhilippines andIndonesia accounting together for 60% of the world total.[18]

Composition and comparison

[edit]

Coconut oil contains only trace amounts of free fatty acids (about 0.03% by mass).[23] Most of the fatty acids are present in the form of esters. In the following content, the expressions "fatty acids" and "acid" below refer toesters rather thancarboxylic acids. When forming an ester, the coconut oil is usually referred to as "cocoyl" where the "-yl" root denotes the functional group. For example, the sodium cocoylisenthionate is asodium salt of the ester formed by coconut oil andisethionic acid.

The approximate concentration of fatty acids in coconut oil (midpoint of range in source):[citation needed]

Fatty acid content of coconut oil
Type of fatty acidpct
Lauric saturated C12
48%
Myristic saturated C14
16%
Palmitic saturated C16
9.5%
Capric saturated C10
8%
Caprylic saturated C8
7%
Oleic monounsaturated C18:1
6.5%
Other
5%
black: Saturated;grey: Monounsaturated;blue: Polyunsaturated

The following table provides information about the composition of coconut oil and how it compares with other vegetable oils.

Properties ofvegetable oils[24]
The nutritional values are expressed as percent (%) by mass of total fat.
TypeProcessing
treatment[25]
Saturated
fatty acids
Monounsaturated
fatty acids
Polyunsaturated
fatty acids
Smoke point
Total[24]Oleic
acid
(ω−9)
Total[24]α-Linolenic
acid
(ω−3)
Linoleic
acid
(ω−6)
ω−6:3
ratio
Avocado[26]11.670.667.913.5112.512.5:1250 °C (482 °F)[27]
Brazil nut[28]24.832.731.342.00.141.9419:1208 °C (406 °F)[29]
Canola[30]7.463.361.828.19.118.62:1204 °C (400 °F)[31]
Coconut[32]82.56.361.70.0191.6888:1175 °C (347 °F)[29]
Corn[33]12.927.627.354.715858:1232 °C (450 °F)[31]
Cottonseed[34]25.917.81951.915454:1216 °C (420 °F)[31]
Cottonseed[35]hydrogenated93.61.50.60.20.31.5:1
Flaxseed/linseed[36]9.018.41867.853130.2:1107 °C (225 °F)
Grape seed[37] 9.616.115.8  69.90.1069.6very high216 °C (421 °F)
Hemp seed[38]7.09.09.082.022.054.02.5:1166 °C (330 °F)[39]
High-oleic safflower oil[40]7.575.275.212.8012.8very high212 °C (414 °F)[29]
Olive (extra virgin)[41]13.873.071.310.50.79.814:1193 °C (380 °F)[29]
Palm[42]49.337.0409.30.29.145.5:1235 °C (455 °F)
Palm[43]hydrogenated88.25.70
Peanut[44]16.257.155.419.90.31819.661.6:1232 °C (450 °F)[31]
Rice bran oil2538.438.436.62.234.4[45]15.6:1232 °C (450 °F)[46]
Sesame[47]14.239.739.341.70.341.3138:1
Soybean[48]15.622.822.657.77517.3:1238 °C (460 °F)[31]
Soybean[49]partially hydrogenated14.943.042.537.62.634.913.4:1
Sunflower oil[50]8.9963.462.920.70.1620.5128:1227 °C (440 °F)[31]
Walnut oil[51]unrefined9.122.822.263.310.452.95:1160 °C (320 °F)[52]

Health concerns

[edit]

Many health organizations advise against the consumption of coconut oil owing to its high levels ofsaturated fat,[4] including the United StatesFood and Drug Administration,[53]World Health Organization,[54] the BritishNational Health Service,[55] theAmerican Dietetic Association,[56]American Heart Association,[57]British Nutrition Foundation,[58][59] andDietitians of Canada.[60]

Marketing of coconut oil has created the inaccurate belief that it is a "healthy food".[61][62] Instead, studies have found that coconut oil consumption has health effects similar to those of other unhealthy fats, includingbutter,beef fat, andpalm oil.[4][61]

Coconut oil contains a high amount oflauric acid, a saturated fat that raises total blood cholesterol levels by increasing the amounts of bothhigh-density lipoprotein (HDL) cholesterol andlow-density lipoprotein (LDL) cholesterol.[4][63][64] Although lauric acid consumption may create a more favorable total blood cholesterol profile, this does not exclude the possibility that persistent consumption of coconut oil may actually increase the risk ofcardiovascular diseases through other mechanisms,[63] particularly via the marked increase in total blood cholesterol induced by lauric acid.[64][65] Because the majority of saturated fat in coconut oil is lauric acid,[64][65] coconut oil may be preferred overpartially hydrogenated vegetable oil when solid fats are used in the diet.[66]

Clinical research

[edit]

A 2017 review of clinical research by experts associated with the American Heart Association recommended against consumption of coconut oil due to its propensity for increasing blood levels of LDL as a risk factor for cardiovascular diseases.[4]

A 2020systematic review andmeta-analysis ofclinical trials on whether chronic consumption of coconut oil might affectrisk factors forcardiovascular diseases found thatlow-density lipoprotein (LDL) cholesterol (but alsohigh-density lipoprotein (HDL)) concentrations were elevated compared with non-tropicalvegetable oils. The review stated that "coconut oil should not be viewed as healthy oil for cardiovascular disease risk reduction, and limiting coconut oil consumption because of its high saturated fat content is warranted."[63]

Uses

[edit]
Coconut oil
Nutritional value per 100 g
Energy3,730 kJ (890 kcal)
99 g
Saturated82.5 g
Monounsaturated6.3 g
Polyunsaturated1.7 g
Vitamins and minerals
VitaminsQuantity
Vitamin E
20%
3 mg
Vitamin K
1%
0.6 μg
MineralsQuantity
Iron
0%
0.05 mg
Other constituentsQuantity
phytosterols86 mg

Percentages estimated usingUS recommendations for adults.[67]

Nutrition and fat composition

[edit]

Coconut oil is 99% fat, composed mainly of saturated fats (82% of total; table). In a 100 gram reference amount, coconut oil supplies 890calories. Half of the saturated fat content of coconut oil is lauric acid (41.8 grams per 100 grams of total composition), while other significant saturated fats aremyristic acid (16.7g),palmitic acid (8.6g), andcaprylic acid (6.8g).[68]Monounsaturated fats are 6% of total composition, andpolyunsaturated fats are 2% (table). Coconut oil containsphytosterols, whereas there are nomicronutrients in significant content (table).

Solid coconut fat

In food

[edit]

Coconut oil has a long history inAsia, particularly in tropical regions where the plant is abundant, where it has been used for cooking. It is the oil of choice inSri Lankan cuisine, where it is used for sautéing and frying, in both savoury and sweet dishes. It also plays a prominent role in the cuisines ofThailand andKerala.

Coconut oil was introduced relatively recently to most Western cuisines, and is commonly used in baked goods, pastries, andsautés, having a nut-like quality with some sweetness.[69] It is sometimes used by movie theatre chains to poppopcorn.

Other culinary uses include replacing solid fats produced throughhydrogenation in baked andconfectionery goods.[66]Hydrogenated or partially hydrogenated coconut oil is often used innon-dairy creamers and snack foods. In frying, thesmoke point of coconut oil is 177 °C (351 °F).

Industry

[edit]
See also:Vegetable oil fuel

Coconut oil has been tested for use as a feedstock forbiodiesel to use as adiesel engine fuel. In this manner, it can be applied to powergenerators and transport using diesel engines. Since straight coconut oil has a highgelling temperature (22–25 °C (72–77 °F)), a highviscosity, and a minimumcombustion chamber temperature of 500 °C (932 °F) (to avoidpolymerization of the fuel), coconut oil typically istransesterified to make biodiesel. Use of B100 (100% biodiesel) is possible only in temperate climates, as the gel point is approximately 10 °C (50 °F). The oil must meet theWeihenstephan standard[70][better source needed] to use pure vegetable oil as a fuel. Moderate to severe damage fromcarbonisation and clogging would occur in an unmodified engine.

The Philippines,Vanuatu,Samoa, and several other tropical island countries use coconut oil as an alternative fuel source to run automobiles, trucks, and buses, and to power generators.[71][better source needed] Biodiesel fuel derived from coconut oil is currently used as a fuel for transport in the Philippines.[72][73] Further research into the potential of coconut oil as a fuel for electricity generation is being carried out in the islands of the Pacific, although to date it appears that it is not useful as a fuel source due to the cost of labour and supply constraints.[74]

Coconut oil has been tested for use as anengine lubricant[75] and as atransformer oil.[76] Coconut oil (and derivatives, such as coconut fatty acid) are used as raw materials in the manufacture ofsurfactants such ascocamidopropyl betaine,cocamide MEA, andcocamide DEA.

Acids derived from coconut oil can be used asherbicides.[77] Before the advent of electrical lighting, coconut oil was the primary oil used for illumination in India and was exported as cochin oil.[78]

Soap

[edit]
See also:Soap

Coconut oil is an important base ingredient for the manufacturing of soap. Soap made with coconut oil tends to be hard, though it retains more water than soap made with other oils and thus increases manufacturer yields. It is more soluble in hard water and salt water than other soaps allowing it to lather more easily.[79]

Other uses

[edit]

It can be used as fuel for burning in atorch or dripped into fire to createinsect-repelling smoke. It also protects metal from corrosion.[6]

  • Soap
    Soap
  • Homemade oil products
    Homemade oil products

See also

[edit]

References

[edit]
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