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Cobalt arsenide

From Wikipedia, the free encyclopedia
Cobalt arsenide
Names
Other names
arsanylidynecobalt, cobalt monoarsenide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.043.775Edit this at Wikidata
EC Number
  • 248-168-6
  • InChI=1S/As.Co
    Key: NMLUQMQPJQWTFK-UHFFFAOYSA-N
  • [As]#[Co]
Properties
CoAs
Molar mass133.85
Appearancesolid
Density6.73 g/cm3
Melting point916 °C (1,681 °F; 1,189 K)
Hazards
GHS labelling:[1]
GHS06: ToxicGHS09: Environmental hazard
Danger
H301,H331,H410
P261,P264,P270,P271,P273,P301+P310,P304+P340,P311,P321,P330,P391,P403+P233,P405,P501
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Cobalt arsenide is a binaryinorganic compound ofcobalt andarsenic with the chemical formula CoAs.[2][3] The compound occurs naturally as the mineralmodderite.[4][5]

Physical properties

[edit]

Cobalt arsenide crystallizes in theorthorhombic system,space groupPnam, parameter parameters a = 0.515 nm, b = 0.596 nm, c = 0.351 nm, Z = 4.

Cobalt arsenide is isostructural with FeAs.[6]

At approximately 6-8 GPa, single crystals of CoAs undergo a transformation to a lower-symmetry phase.[5]

Use

[edit]

CoAs is used as asemiconductor and in photo optic applications.[7]

References

[edit]
  1. ^"Cobalt arsenide".pubchem.ncbi.nlm.nih.gov. Retrieved23 January 2022.
  2. ^Lide, David R. (29 June 2004).CRC Handbook of Chemistry and Physics, 85th Edition.CRC Press. pp. 4–53.ISBN 978-0-8493-0485-9. Retrieved20 January 2022.
  3. ^Toxic Substances Control Act (TSCA) Chemical Substance Inventory.U.S. Government Printing Office. 1979. p. 16. Retrieved20 January 2022.
  4. ^"Modderite Mineral Data". webmineral.com. Retrieved20 January 2022.
  5. ^abGramsch, Stephen (December 2004)."Crystal Chemistry of Transition Metal Arsenides and the High Pressure Behavior of CoAs". Retrieved20 January 2022.
  6. ^Heyding, R. D.; Calvert, L. D. (1 May 1957)."Arsenides of Transition Metals: The Arsenides of Iron and Cobalt".Canadian Journal of Chemistry.35 (5):449–457.doi:10.1139/v57-065. Retrieved20 January 2022.
  7. ^"Cobalt(III) Arsenide".American Elements. Retrieved20 January 2022.
Cobalt(I)
Cobalt(II)
Cobalt(0,III)
Cobalt(II,III)
Cobalt(III)
Cobalt(III,IV)
Cobalt(IV)
Cobalt(V)
Arsenic compounds
Arsenides
As(III)
As(III,V)
As(V)
Binary arsenides
AsH3
+H
He
LiAsBeBAsC+N+OFNe
Na3AsMgAlAs-SiPS+ClAr
KCaAsScTiVCrMnAsFeCoAsNiCuZn3As2GaAs-GeAsSe+BrKr
RbSrYAsZrNbMoAs2TcRuRhPdAs2AgCd3As2InAs-SnSb+Te+IXe
CsBa*LuHfTaAsWAs2ReOsIrPtAuHgTlPbBiAsPoAtRn
FrRa**LrRfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
*LaCePrAsNdPmSmAsEuGdTbDyAsHoAsErTmYb
**AcThPaUNpAs
NpAs2
PuAsAmCmBkCfEsFmMdNo
Ternary arsenides
Quaternary arsenides
Quinary arsenides
See also
Retrieved from "https://en.wikipedia.org/w/index.php?title=Cobalt_arsenide&oldid=1292721837"
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