Movatterモバイル変換

Carbonate chloride

From Wikipedia, the free encyclopedia

Class of chemical compounds

Thecarbonate chlorides aredouble salts containing bothcarbonate andchloride anions. Quite a few minerals are known. Several artificial compounds have been made. Some complexes have both carbonate and chlorideligands. They are part of the family of halocarbonates. In turn these halocarbonates are a part ofmixed anion materials.

The carbonate chlorides do not have a bond from chlorine to carbon, however "chlorocarbonate" has also been used to refer to thechloroformates which contain the group ClC(O)O-.

Formation

[edit]

Natural

[edit]

Scapolite is produced in nature bymetasomatism, where hot high pressure water solutions of carbon dioxide and sodium chloride modifyplagioclase.^[1]

Chloroartinite is found inSorel cements exposed to air.^[2]

Minerals

[edit]

In 2016 27 chloride containing carbonate minerals were known.^[3]

name	formula	crystal system	space group	unit cell	density	Optics refractive index	Raman spectrum	comments	reference
Alexkhomyakovite	K₆(Ca₂Na)(CO₃)₅Cl∙6H₂O	hexagonal	P6₃/mcm	a=9.2691, c=15.8419, V=1178.72 Z = 2	2.25	uniaxial (–), ω=1.543, ε=1.476			^[4]
Ashburtonite	HPb₄Cu₄(Si₄O₁₂)(HCO₃)₄(OH)₄Cl								^[3]
Balliranoite	(Na,K)₆Ca₂(Si₆Al₆O₂₄)Cl₂(CO₃)	hexagonal	P6₃	a=12.695c=5.325V=743.2Z=1	2.48	uniaxial (+), ω=1.523, ε=1.525			^[5]
Barstowite	Pb₄(CO₃)Cl₆.H₂O
Chlorartinite	Mg₂(CO₃)Cl(OH).3H₂O
Chlormagaluminite	(Mg,Fe²⁺)₄Al₂(OH)₁₂(Cl, 0.5 CO₃)₂·2H₂O		6/mmm		1.98-2.09	ε=1.560 ω=1.540			^[6]
Davyne								can substitute CO3 for SO4	^[7]
Decrespignyite-(Y)	Y₄Cu(CO₃)₄Cl(OH)₅·2H₂O						V4 bending 694, 718 and 746; V2 bending 791, 815, 837 and 849;v3 antisymmetric stretching 1391, 1414, 1489, 1547; also OH stretching^[8]	light blue	^[9]
Defernite	Ca₃CO₃(OH,Cl)₄.H₂O
Hanksite	Na₂₂K(SO₄)₉(CO₃)₂Cl	hexagonal	P6₃/m	a = 10.46 Å c = 21.19 Å;Z = 2
iowaite	Mg₆Fe₂(Cl,(CO₃)_0.5)(OH)₁₆·4H₂O								^[10]
Kampfite	Ba₁₂(Si₁₁Al₅)O₃₁(CO₃)₈Cl₅	monoclinic	Cc	a = 31.2329, b=5.2398, c=9.0966 β = 106.933°		uniaxial (–),n_ω = 1.642n_ε = 1.594			^[11]
Marialite	Na₄(AlSi₃O₈)₃(Cl₂,CO₃,SO₄)
Mineevite-(Y)	Na₂₅BaY₂(CO₃)₁₁(HCO₃)₄(SO₄)₂F₂Cl								^[12]
Northupite	Na₃Mg(CO₃)₂Cl	octahedral	Fd3	Z=16		1.514	v4 bending 714; v3 antisymmetric stretching 1554^[8]		^[13]^[14]
Phosgenite	Pb₂CO₃Cl₂	tetragonal		a=8.15 c=8.87					^[13]
Reederite-(Y)	Na15Y2(CO3)9(SO3F)Cl								^[12]
Sakhaite (withHarkerite)	Ca₄₈Mg₁₆Al(SiO₃OH)₄(CO₃)₁₆(BO₃)₂₈·(H₂O)₃(HCl)₃or Ca₁₂Mg₄(BO₃)₇(CO₃)₄Cl(OH)₂·H₂O								^[3]
Scapolite	Ca₃Na₅[Al₈Si₁₆O₄₈]Cl(CO₃)		P4₂/n	a=12.07899 c=7.583467 V=1106.443					^[15]
Tatarskite	Ca₆Mg₂(SO₄)₂(CO₃)₂(OH)₄Cl₄•7H₂O	orthorhombic				Biaxial (-) nα = 1.567 nβ = 1.654 nγ = 1.722			^[16]
Tunisite	NaCa₂Al₄(CO₃)₄Cl(OH)₈	tetragonal	P4/nmm	a=11.198 c=6.5637 Z=2
Vasilyevite	(Hg₂)₁₀O₆I₃Br₂Cl(CO₃)		P1 overbar	a 9.344,b 10.653,c 18.265, α=93.262 β=90.548 γ=115.422°V=1638.3 Z=2	9.57

Artificial

[edit]

name	formula		crystal system	space group	unit cell in Å	density	comment	reference
	K₅Na₂Cu₂₄(CO₃)₁₆Cl₃(OH)₂₀•12H₂O		cubic	F23	a=15.463 V=3697.5 Z=2	3.044	dark blue	^[17]
	Y₈O(OH)₁₅(CO₃)₃Cl	1197.88	hexagonal	P6₃	a=9.5089 c=14.6730 Z=2 V=1148.97	3.462		^[18]
	Lu₈O(OH)₁₅(CO₃)₃Cl	1886.32	hexagonal	P6₃	a=9.354 c=14.415 V=1092.3 Z=2	5.689	colourless	^[19]
	Y₃(OH)₆(CO₃)Cl		cubic	Im3m	a=12.66 V=2032 Z=8	3.035	colourless	^[20]
	Dy₃(OH)₆(CO₃)Cl		cubic	Im3	a=12.4754 V=1941.6 Z=8	4.687	colourless	^[20]
	Er₃(OH)₆(CO₃)Cl		cubic	Im3m	a=12.4127 V=1912.5 Z=8	4.857	pink	^[20]
	K{Mg(H₂O)₆}₂[Ru₂(CO₃)₄Cl₂]·4H₂O	889.06	monoclinic	P2₁/c	a=11.6399 b=11.7048 c=11.8493 β=119.060 V=1411.6 Z=2	2.092	red-brown	^[21]
	K₂[{Mg(H₂O)₄}2Ru₂(CO₃)₄(H₂O)Cl]Cl₂·2H₂O	880.58	orthorhombic	Fmm2	a=14.392 b=15.699 c=10.741 V=2426.8 Z=4	2.391	dark brown	^[21]
trisodium cobalt dicarbonate chloride	Na₃Co(CO₃)₂Cl		cubic	Fd3	a=13.9959 Z=16	2.75	spin-frustrated antiferromagnetic	^[3]^[22]
trisodium manganese dicarbonate chloride	Na₃Mn(CO₃)₂Cl		cubic		a=14.163		brown	^[23]
di-magnesium hexahydrate trihydrogencarbonate chloride	Mg₂(H₂O)₆(HCO₃)₃Cl			R3c	a=8.22215 c=39.5044 V=2312.85 Z=6	1.61	decompose 125 °C	^[2]
tripotassium tricalcium selenite tricarbonate chloride	K₃Ca₃(SeO₃)(CO₃)₃Cl	579.97	hexagonal	P6₃	a=10.543 c=7.060 V=706.0 Z=2	2.991		^[24]
	LiBa₉[Si₁₀O₂₅]Cl₇(CO₃)				Z=2	3.85	layer silicate	^[25]^[26]
	Ba₃Cl₄CO₃		orthorhombic	Pnma	a=8.407, b=9.589, c=12.483 Z=4			^[27]

Complexes

[edit]

The "lanthaballs" arelanthanoid atom clusters held together by carbonate and otherligands. They can form chlorides. Examples are [La₁₃(ccnm)₆(CO₃)₁₄(H₂O)₆(phen)₁₈] Cl₃(CO₃)·25H₂O where ccnm is carbamoylcyanonitrosomethanide and phen is 1,10-phenanthroline.Praseodymium (Pr) orcerium (Ce) can substitute forlanthanum (La).^[28] Otherlanthanide cluster compounds include :(H₃O)₆[Dy₇₆O₁₀(OH)₁₃₈(OAc)₂₀(L)₄₄(H₂O)₃₄]•2CO₃•4Cl₂•L•2OAc (nicknamed Dy₇₆) and (H₃O)₆[Dy₄₈O₆(OH)₈₄(OAc)₄(L)₁₅(hmp)₁₈(H₂O)₂₀]•CO₃•14Cl•2H₂O (termed Dy₄₈-T) with OAc=acetate, and L=3-furancarboxylate and Hhmp=2,2-bis(hydroxymethyl)propionic acid.^[29]

Platinum can form complexes with carbonate and chloride ligands, in addition to anamino acid. Examples include the platinum compound [Pt(gluH)Cl(CO₃)]₂.2H₂O gluH=glutamic acid, and Na[Pt(gln)Cl₂(CO₃)].H₂O gln=glutamine.^[30]Rhodium complexes include Rh₂(bipy)₂(CO₃)₂Cl (bipy=bipyridine)^[31]

References

[edit]

^Harlov, D. E.; Budzyn, B. (December 2008). "The stability of Cl-CO₃-scapolite relative to plagioclase + CaCO3 + CaSO4 in the presence of NaCl brines as a function of P-T-XNaCl".AGUFM.2008: V31C–2156–2156.Bibcode:2008AGUFM.V31C2156H.
^^a ^bDinnebier, Robert E.; Jansen, Martin (2008-12-01)."The Crystal Structure of [Mg2(H2O)6(HCO3)3]+Cl–, Containing a Magnesium-based Hetero-polycation".Zeitschrift für Naturforschung B.63 (12):1347–1351.doi:10.1515/znb-2008-1201.ISSN 1865-7117.S2CID 196866126.
^^a ^b ^c ^dHazen, Robert M.; Hummer, Daniel R.; Hystad, Grethe; Downs, Robert T.; Golden, Joshua J. (April 2016). "Carbon mineral ecology: Predicting the undiscovered minerals of carbon".American Mineralogist.101 (4):889–906.Bibcode:2016AmMin.101..889H.doi:10.2138/am-2016-5546.ISSN 0003-004X.S2CID 741788.
^Pekov, Igor V.; Zubkova, Natalia V.; Yapaskurt, Vasiliy O.; Lykova, Inna S.; Chukanov, Nikita V.; Belakovskiy, Dmitry I.; Britvin, Sergey N.; Turchkova, Anna G.; Pushcharovsky, Dmitry Y. (2019-02-21). "Alexkhomyakovite, K6(Ca2Na)(CO3)5Cl∙6H2O, a new mineral from the Khibiny alkaline complex, Kola peninsula, Russia".European Journal of Mineralogy.31 (1):135–143.Bibcode:2019EJMin..31..135P.doi:10.1127/ejm/2018/0030-2798.ISSN 0935-1221.S2CID 134451790.
^Chukanov, Nikita V.; Zubkova, Natalia V.; Pekov, Igor V.; Olysych, Lyudmila V.; Bonaccorsi, Elena; Pushcharovsky, Dmitry YU. (2010-03-18). "Balliranoite, (Na,K)6Ca2(Si6Al6O24)Cl2(CO3), a new cancrinite-group mineral from Monte Somma Vesuvio volcanic complex, Italy".European Journal of Mineralogy.22 (1):113–119.Bibcode:2010EJMin..22..113C.doi:10.1127/0935-1221/2010/0022-1983.ISSN 0935-1221.
^Kashayev, A. A.; Feoktistov, G. D.; Petrova, S. V. (July 1983). "Chlormagaluminite (Mg, Fe 2+ ) 4 Al 2 (OH) 12 (Cl, 1/2 CO 3 ) 2 ·2H 2 O-a new mineral of the manasseite-sjogrenite group".International Geology Review.25 (7):848–853.Bibcode:1983IGRv...25..848K.doi:10.1080/00206818309466774.ISSN 0020-6814.
^BALLIRANO, PAOLO (1998)."CARBONATEGROUPSIN DAWNE:STRUCTURAL AND CRYSTAL.CHEMICAL CONSIDERATIONs"(PDF).The Canadian Mineralogist.36:1285–1292.
^^a ^bFrost, Ray L.; Palmer, Sara J. (2011-11-15). "Raman spectrum of decrespignyite [(Y,REE)4Cu(CO3)4Cl(OH)5·2H2O] and its relation with those of other halogenated carbonates including bastnasite, hydroxybastnasite, parisite and northupite".Journal of Raman Spectroscopy.42 (11):2042–2048.Bibcode:2011JRSp...42.2042F.doi:10.1002/jrs.2959.
^Wallwork, K.; Kolitsch, U.; Pring, A.; Nasdala, L. (February 2002). "Decrespignyite-(Y), a new copper yttrium rare earth carbonate chloride hydrate from Paratoo, South Australia".Mineralogical Magazine.66 (1):181–188.Bibcode:2002MinM...66..181W.doi:10.1180/0026461026610021.ISSN 0026-461X.S2CID 4820053.
^Frost, R. L.; Erickson, K. L. (2004)."Thermal decomposition of natural iowaite"(PDF).Journal of Thermal Analysis and Calorimetry.78 (2):367–373.doi:10.1023/B:JTAN.0000046103.00586.61.ISSN 1388-6150.S2CID 97065830.
^"Kampfite: Mineral information, data and localities".www.mindat.org. Retrieved2019-11-26.
^^a ^bHarlov, Daniel E.; Aranovich, Leonid (2018-01-30).The Role of Halogens in Terrestrial and Extraterrestrial Geochemical Processes: Surface, Crust, and Mantle. Springer.ISBN 978-3-319-61667-4.
^^a ^bIvan Kostov, Ruslan I. Kostov (2016)."Systematics and crystal genesis of carbonate minerals"(PDF).ANNUAL OF THE UNIVERSITY OF MINING AND GEOLOGY "ST. IVAN RILSKI", Part I, Geology and Geophysics.49:111–118.
^Batsanov, Stepan S.; Ruchkin, Evgeny D.; Poroshina, Inga A. (2016-08-10).Refractive Indices of Solids. Springer. p. 61.ISBN 978-981-10-0797-2.
^Antao, S. M.; Hassan, I. (2011-04-01). "COMPLETE Al-Si ORDER IN SCAPOLITE Me37.5, IDEALLY Ca3Na5[Al8Si16O48]Cl(CO3), AND IMPLICATIONS FOR ANTIPHASE DOMAIN BOUNDARIES (APBs)".The Canadian Mineralogist.49 (2):581–586.Bibcode:2011CaMin..49..581A.doi:10.3749/canmin.49.2.581.ISSN 0008-4476.
^"Tatarskite: Mineral information, data and localities".www.mindat.org. Retrieved10 May 2020.
^Sokolova, Elena; Hawthorne, Frank C. (2003). "The Crystal Structure Of An Anthropogenic Cu–k–na–hydro-Hydroxyl–carbonate–chloride From Johanngeorgenstadt, Saxony, Germany".The Canadian Mineralogist.41 (4):929–936.Bibcode:2003CaMin..41..929S.doi:10.2113/gscanmin.41.4.929.
^Zhang, Yiting; Long, Ying; Dong, Xuehua; Wang, Lei; Huang, Ling; Zeng, Hongmei; Lin, Zhien; Wang, Xin; Zou, Guohong (2019). "Y 8 O(OH) 15 (CO 3 ) 3 Cl: an excellent short-wave UV nonlinear optical material exhibiting an infrequent three-dimensional inorganic cationic framework".Chemical Communications.55 (31):4538–4541.doi:10.1039/C9CC00581A.ISSN 1359-7345.PMID 30924839.S2CID 85566544.
^Cao, Liling; Song, Yunxia; Peng, Guang; Luo, Min; Yang, Yi; Lin, Chen-sheng; Zhao, Dan; Xu, Feng; Lin, Zheshuai; Ye, Ning (2019-03-26). "Refractive Index Modulates Second-Harmonic Responses in RE 8 O(CO 3 ) 3 (OH) 15 X (RE = Y, Lu; X = Cl, Br): Rare-Earth Halide Carbonates as Ultraviolet Nonlinear Optical Materials".Chemistry of Materials.31 (6):2130–2137.doi:10.1021/acs.chemmater.9b00068.ISSN 0897-4756.S2CID 107652980.
^^a ^b ^cWang, Yanyan; Han, Tian; Ding, You-Song; Zheng, Zhiping; Zheng, Yan-Zhen (2016)."Sodalite-like rare-earth carbonates: a study of structural transformation and diluted magnetism".Dalton Transactions.45 (3):1103–1110.doi:10.1039/C5DT03314D.ISSN 1477-9226.PMID 26660232.
^^a ^bYang, Jian-Hui; Cheng, Ru-Mei; Jia, Yan-Yan; Jin, Jin; Yang, Bing-Bing; Cao, Zhi; Liu, Bin (2016). "Chlorine and temperature directed self-assembly of Mg–Ru 2 ( ii , iii ) carbonates and particle size dependent magnetic properties".Dalton Transactions.45 (7):2945–2954.doi:10.1039/C5DT04463D.ISSN 1477-9226.PMID 26750871.
^Fu, Zhendong (2012).Spin Correlations and Excitations in Spin-frustrated Molecular and Molecule-based Magnets. Forschungszentrum Jülich. pp. 97–165.ISBN 978-3-89336-797-9.
^Nawa, Kazuhiro; Okuyama, Daisuke; Avdeev, Maxim; Nojiri, Hiroyuki; Yoshida, Masahiro; Ueta, Daichi; Yoshizawa, Hideki; Sato, Taku J. (2018-10-18). "Degenerate ground state in the classical pyrochlore antiferromagnet Na 3 Mn ( CO 3 ) 2 Cl".Physical Review B.98 (14) 144426.arXiv:1810.05126.Bibcode:2018PhRvB..98n4426N.doi:10.1103/PhysRevB.98.144426.ISSN 2469-9950.S2CID 119245230.
^Schmitz, Dieter (2001).Synthese, Charakterisierung und Bildungsprinzipien von sauren und neutralen Oxoselenaten(IV) und Oxoselenat(IV)-hydraten (Thesis) (in German). p. 182 – via Fachbereich 8.
^"LiBa9[Si10O25]Cl7(CO3) (LiBa9Si10[CO3]Cl7O25) Crystal Structure - SpringerMaterials".materials.springer.com. Retrieved2019-11-27.
^Il'Inets, A. M.; Nevskii, N. N.; Ilyukhin, V. V.; Belov, N. V. (March 1983). "A new type of infinite silicate radical [Si10O25] in the synthetic compound LiBa9[Si10O25]CI7(CO3)".SPHD.28: 213.Bibcode:1983SPhD...28..213I.
^Leyva-Bailen, Patricia; Vaqueiro, Paz; Powell, Anthony V. (September 2009). "Ionothermal synthesis of the mixed-anion material, Ba3Cl4CO3".Journal of Solid State Chemistry.182 (9):2333–2337.Bibcode:2009JSSCh.182.2333L.doi:10.1016/j.jssc.2009.06.019.
^Chesman, Anthony S. R.; Turner, David R.; Langley, Stuart K.; Moubaraki, Boujemaa; Murray, Keith S.; Deacon, Glen B.; Batten, Stuart R. (2015-02-02). "Synthesis and Structure of New Lanthanoid Carbonate "Lanthaballs"".Inorganic Chemistry.54 (3):792–800.doi:10.1021/ic5016115.ISSN 0020-1669.PMID 25349948.
^Li, Xiao-Yu; Su, Hai-Feng; Li, Quan-Wen; Feng, Rui; Bai, Hui-Yun; Chen, Hua-Yu; Xu, Jian; Bu, Xian-He (22 July 2019). "A Giant Dy76 Cluster: A Fused Bi-Nanopillar Structural Model for Lanthanide Clusters".Angewandte Chemie International Edition.58 (30):10184–10188.doi:10.1002/anie.201903817.PMID 31090998.S2CID 155089115.
^Shatnawi, Razan Ahmad Mahmoud (November 2013).Synthesis and Characterization of Some Amino Acid Complexes with Metal Ions.Yarmouk University (Article).
^Davidson, G.; Ebsworth, E. A. V. (2007).Spectroscopic Properties of Inorganic and Organometallic Compounds. Royal Society of Chemistry. p. 294.ISBN 978-1-84755-506-9.

Retrieved from "https://en.wikipedia.org/w/index.php?title=Carbonate_chloride&oldid=1314299375"

Categories:

Hidden categories:

[8]ページ先頭