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Californium(III) fluoride

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(Redirected fromCalifornium trifluoride)
Californium(III) fluoride
Names
Other names
Californium trifluoride
Identifiers
3D model (JSmol)
  • InChI=1S/Cf.3FH/h;3*1H/q+3;;;/p-3
    Key: RFYJBQZVUMTFMQ-UHFFFAOYSA-K
  • [Cf+3].[F-].[F-].[F-]
Properties
CfF3
Molar mass308 g·mol−1
Appearanceyellow-green solid
Densityg/cm3
Structure
orthorhombic
Related compounds
Related compounds
Berkelium trifluoride
Einsteinium trifluoride
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
radioactive
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Californium(III) fluoride is a binaryinorganic compound ofcalifornium andfluorine with the formulaCfF
3
[1]

Physical properties

[edit]

Californium(III) fluoride is a yellow-green solid[2] and has two crystalline structures that are temperature dependent. At low temperatures the orthorhombic structure (YF
3
type) is found withlattice constantsa = 665.3(3) pm,b = 703.9(1) pm andc = 439.3(3) pm. At higher temperatures it forms a trigonal system (LaF
3
type) with:a = 694.5(3) pm andc = 710.1(2) pm. Here, each californium atom is surrounded by nine fluorine atoms in a distorted triply-capped trigonal-prismatic structure.[3][4]

References

[edit]
  1. ^Haupt, Axel (22 March 2021).Organic and Inorganic Fluorine Chemistry: Methods and Applications.Walter de Gruyter GmbH & Co KG. p. 618.ISBN 978-3-11-065933-7. Retrieved6 April 2023.
  2. ^"WebElements Periodic Table » Californium » californium trifluoride". webelements.com. Retrieved6 April 2023.
  3. ^Stevenson, J. N.; Peterson, J. R. (1 October 1973)."The trigonal and orthorhombic crystal structures of CfF3 and their temperature relationship".Journal of Inorganic and Nuclear Chemistry.35 (10):3481–3486.doi:10.1016/0022-1902(73)80356-2.ISSN 0022-1902. Retrieved6 April 2023.
  4. ^Macintyre, Jane E. (23 July 1992).Dictionary of Inorganic Compounds.CRC Press. p. 2825.ISBN 978-0-412-30120-9. Retrieved6 April 2023.
Cf(II)
Cf(III)
Organocalifornium(III) compounds
Cf(IV)
Salts and covalent derivatives of thefluoride ion
HF?HeF2
LiFBeF2BF
BF3
B2F4
+BO3
CF4
CxFy
+CO3
NF3
FN3
N2F2
NF
N2F4
NF2
?NF5
+N
+NO3
OF2
O2F2
OF
O3F2
O4F2
?OF4
F2Ne
NaFMgF2AlF
AlF3
SiF4P2F4
PF3
PF5
+PO4
S2F2
SF2
S2F4
SF3
SF4
S2F10
SF6
+SO4
ClF
ClF3
ClF5
?ArF2
?ArF4
KFCaF
CaF2
ScF3TiF2
TiF3
TiF4
VF2
VF3
VF4
VF5
CrF2
CrF3
CrF4
CrF5
?CrF6
MnF2
MnF3
MnF4
?MnF5
FeF2
FeF3
FeF4
CoF2
CoF3
CoF4
NiF2
NiF3
NiF4
CuF
CuF2
?CuF3
ZnF2GaF2
GaF3
GeF2
GeF4
AsF3
AsF5
Se2F2
SeF4
SeF6
+SeO3
BrF
BrF3
BrF5
KrF2
?KrF4
?KrF6
RbFSrF
SrF2
YF3ZrF2
ZrF3
ZrF4
NbF4
NbF5
MoF4
MoF5
MoF6
TcF4
TcF
5

TcF6
RuF3
RuF
4

RuF5
RuF6
RhF3
RhF4
RhF5
RhF6
PdF2
Pd[PdF6]
PdF4
?PdF6
Ag2F
AgF
AgF2
AgF3
CdF2InF
InF3
SnF2
SnF4
SbF3
SbF5
TeF4
?Te2F10
TeF6
+TeO3
IF
IF3
IF5
IF7
+IO3
XeF2
XeF4
XeF6
?XeF8
CsFBaF2 LuF3HfF4TaF5WF4
WF5
WF6
ReF4
ReF5
ReF6
ReF7
OsF4
OsF5
OsF6
?OsF
7

?OsF
8
IrF2
IrF3
IrF4
IrF5
IrF6
PtF2
Pt[PtF6]
PtF4
PtF5
PtF6
AuF
AuF3
Au2F10
?AuF6
AuF5•F2
Hg2F2
HgF2
?HgF4
TlF
TlF3
PbF2
PbF4
BiF3
BiF5
PoF2
PoF4
PoF6
AtF
?AtF3
?AtF5
RnF2
?RnF
4

?RnF
6
FrFRaF2 LrF3RfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
LaF3CeF3
CeF4
PrF3
PrF4
NdF2
NdF3
NdF4
PmF3SmF
SmF2
SmF3
EuF2
EuF3
GdF3TbF3
TbF4
DyF2
DyF3
DyF4
HoF3ErF3TmF2
TmF3
YbF2
YbF3
AcF3ThF2
ThF3
ThF4
PaF4
PaF5
UF3
UF4
UF5
UF6
NpF3
NpF4
NpF5
NpF6
PuF3
PuF4
PuF5
PuF6
AmF2
AmF3
AmF4
?AmF6
CmF3
CmF4
 ?CmF6
BkF3
BkF
4
CfF3
CfF4
EsF3
EsF4
?EsF6
FmMdF3No
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