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Bromofluorodiiodomethane

From Wikipedia, the free encyclopedia
Bromofluorodiiodomethane
Names
Preferred IUPAC name
Bromo(fluoro)diiodomethane
Other names
  • Bromo-fluoro-diiodomethane
  • Fluorobromodiiodomethane
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1/CBrFI2/c2-1(3,4)5
    Key: JJVQDAVWWKZORR-UHFFFAOYSA-N
  • C(F)(Br)(I)I
Properties
CBrFI2
Molar mass364.722 g·mol−1
Density3.6 g/cm3
Boiling point176.6 °C (349.9 °F; 449.8 K)
soluble
Hazards
Flash point60.6 °C
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Bromofluorodiiodomethane is atetrahalomethane with the chemical formulaCBrFI2.[1] This is an organic compound containing twoiodine atoms, onebromine atom, and onefluorine atom attached to the methane backbone.[2][3]

Synthesis

[edit]

Bromofluorodiiodomethane can be obtained as a byproduct in the reaction of (dibromo-fluoromethyl)triphenylphosphonium bromide, formed fromtriphenylphosphine andCBr3F inTHF, with iodine in DMF.[4]

References

[edit]
  1. ^Dolbier Jr., William R. (24 August 2016).Guide to Fluorine NMR for Organic Chemists.John Wiley & Sons. p. 7-56.ISBN 978-1-118-83109-0. Retrieved9 September 2025.
  2. ^Frenkel, Michael; Kabo, G. J.; Marsh, K. N.; Roganov, G. N.; Wilhoit, R. C. (15 June 1994).Thermodynamics of Organic Compounds in the Gas State.CRC Press. p. 919.ISBN 978-1-883400-04-0. Retrieved9 September 2025.
  3. ^"753-67-3 methane, bromofluorodiiodo- - CAS数据库". cheman.chemnet.com. Retrieved9 September 2025.
  4. ^Katritzky, Alan R.; Gilchrist, Thomas L.; Meth-Cohn, Otto; Rees, Charles Wayne (21 March 2003).Comprehensive Organic Functional Group Transformations.Elsevier. p. 228.ISBN 978-0-08-042704-1. Retrieved9 September 2025.
By substitution pattern
Unsubstituted
Monosubstituted
Disubstituted
X,X
X,Y
Trisubstituted
X,X,X
X,X,Y
X,Y,Z
Tetrasubstituted
X,X,X,X
X,X,X,Y
X,X,Y,Y
X,X,Y,Z
X,Y,Z,W
Special types
Chiral
Isotopologues
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