Thebreakdown voltage of aninsulator is the minimum voltage that causes a portion of an insulator to experienceelectrical breakdown and become electricallyconductive.
Fordiodes, the breakdown voltage is the minimum reverse voltage that makes the diode conduct appreciably in reverse. Some devices (such asTRIACs) also have aforward breakdown voltage.
Materials are often classified asconductors orinsulators based on theirresistivity. A conductor is a substance which contains many mobilecharged particles calledcharge carriers which are free to move about inside the material. Anelectric field is created across a piece of the material by applying a voltage difference between electrical contacts on different sides of the material. The force of the field causes the charge carriers within the material to move, creating anelectric current from the positive contact to the negative contact. For example, inmetals one or more of the negatively chargedelectrons in each atom, calledconduction electrons, are free to move about the crystal lattice. An electric field causes a large current to flow, so metals have lowresistivity, making them good conductors. In contrast in materials like plastics andceramics all the electrons are tightly bound to atoms, so under normal conditions there are very few mobile charge carriers in the material. Applying a voltage causes only a very small current to flow, giving the material a very highresistivity, and these are classed as insulators.
However, if a strong enoughelectric field is applied, all insulators become conductors. If the voltage applied across a piece of insulator is increased, at a certain electric field strength the number of charge carriers in the material suddenly increases enormously and its resistivity drops, causing a strong current to flow through it. This is calledelectrical breakdown. Breakdown occurs when the electric field becomes strong enough to pull electrons from the molecules of the material,ionizing them. The released electrons are accelerated by the field and strike other atoms, creating more free electrons and ions in a chain reaction, flooding the material with charged particles. This occurs at a characteristic electric field strength in each material, measured involts per centimeter, called itsdielectric strength.
When a voltage is applied across a piece of insulator, the electric field at each point is equal to thegradient of the voltage. The voltage gradient may vary at different points across the object, due to its shape or local variations in composition. Electrical breakdown occurs when the field first exceeds the dielectric strength of the material in some region of the object. Once one area has broken down and become conductive, that area has almost no voltage drop and the full voltage is applied across the remaining length of the insulator, resulting in a higher gradient and electric field, causing additional areas in the insulator to break down. The breakdown quickly spreads in a conductive path through the insulator until it extends from the positive to the negative contact. The voltage at which this occurs is called thebreakdown voltage of that object. Breakdown voltage[1] varies with the material composition, shape of an object, and the length of material between the electrical contacts.
Breakdown voltage is a characteristic of aninsulator that defines the maximumvoltage difference that can be applied across the material before the insulator conducts. In solid insulating materials, this usually[citation needed] creates a weakened path within the material by creating permanent molecular or physical changes by the suddencurrent. Within rarefied gases found in certain types of lamps, breakdown voltage is also sometimes called thestriking voltage.[2]
The breakdown voltage of a material is not a definite value because it is a form of failure and there is a statistical probability whether the material will fail at a given voltage. When a value is given it is usually the mean breakdown voltage of a large sample. Another term iswithstand voltage, where the probability of failure at a given voltage is so low it is considered, when designing insulation, that the material will not fail at this voltage.
Two different breakdown voltage measurements of a material are the AC and impulse breakdown voltages. The AC voltage is theline frequency of the mains. The impulse breakdown voltage is simulating lightning strikes, and usually uses a 1.2 microsecond rise for the wave to reach 90% amplitude, then drops back down to 50% amplitude after 50 microseconds.[3]
Two technical standards governing performing these tests are ASTM D1816 and ASTM D3300 published by ASTM.[4]
In standard conditions at atmospheric pressure, air serves as an excellent insulator, requiring the application of a voltage of3.0 kV/mm before breaking down (e.g.,lightning, orsparking across plates of acapacitor, or the electrodes of aspark plug). Using other gases, this breakdown potential may decrease to an extent that two uninsulated surfaces with different potentials might induce the electrical breakdown of the surrounding gas. This may damage an apparatus, as a breakdown is analogous to a short circuit.
In a gas, the breakdown voltage can be determined byPaschen's law.
The breakdown voltage in a partial vacuum is represented as[5][6][7]where is the breakdown potential in volts, and areconstants that depend on the surrounding gas, represents the pressure of the surrounding gas, represents the distance between the electrodes, and represents thesecondary electron emission coefficient.
A detailed derivation, and some background information, is given in the article aboutPaschen's law.

Breakdown voltage is aparameter of adiode that defines the largest reversevoltage that can be applied without causing an exponential increase in the leakagecurrent in the diode. Exceeding the breakdown voltage of a diode, per se, is not destructive; although, exceeding its current capacity will be. In fact,Zener diodes are essentially justheavily doped normal diodes that exploit the breakdown voltage of a diode to provide regulation of voltage levels.
Rectifier diodes (semiconductor or tube/valve) may have several voltage ratings, such as the peak inverse voltage (PIV) across the diode, and the maximumRMS input voltage to the rectifier circuit (which will be much less).
Many small-signal transistors need to have any breakdown currents limited to much lower values to avoid excessive heating. To avoid damage to the device, and to limit the effects excessive leakage current may have on the surrounding circuit, the followingbipolar transistor maximum ratings are often specified:
Field-effect transistors have similar maximum ratings, the most important one for junction FETs is the gate-drain voltage rating.
Some devices may also have amaximum rate of change of voltage specified.
Powertransformers,circuit breakers,switchgear and other electrical apparatus connected to overheadtransmission lines are exposed to transient lightning surge voltages induced on the power circuit. Electrical apparatus will have abasic lightning impulse level (BIL) specified. This is the crest value of an impulse waveform with a standardized wave shape, intended to simulate the electrical stress of a lightning surge or a surge induced by circuit switching. The BIL is coordinated with the typical operating voltage of the apparatus. For high-voltagetransmission lines, the impulse level is related to the clearance to ground of energized components. As an example, a transmission line rated 138 kV would be designed for a BIL of 650 kV. A higher BIL may be specified than the minimum, where the exposure to lightning is severe.[8]