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Boron phosphate

From Wikipedia, the free encyclopedia
Chemical compound

Boron phosphate
Names
IUPAC name
Boron phosphate
Systematic IUPAC name
2,4,5-trioxa-1λ5-phospha-3-borabicyclo[1.1.1]pentane 1-oxide[1]
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard100.033.020Edit this at Wikidata
  • InChI=1S/B.H3O4P/c;1-5(2,3)4/h;(H3,1,2,3,4)/q+3;/p-3
    Key: YZYDPPZYDIRSJT-UHFFFAOYSA-K
  • InChI=1/B.H3O4P/c;1-5(2,3)4/h;(H3,1,2,3,4)/q+3;/p-3
    Key: YZYDPPZYDIRSJT-DFZHHIFOAS
  • B12OP(=O)(O1)O2
Properties
BPO4
Molar mass105.78 g/mol
Density2.52 g/cm3
Hazards
GHS labelling:
GHS07: Exclamation mark
Warning
H302
P264,P270,P301+P312,P330,P501
NFPA 704 (fire diamond)
Safety data sheet (SDS)External SDS
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Boron phosphate is aninorganic compound with thechemical formula BPO4. The simplest way of producing it is the reaction ofphosphoric acid andboric acid. It is a white infusible solid that evaporates above 1450 °C.[3]

Synthesis

[edit]

Boron phosphate is synthesized fromphosphoric acid andboric acid at a temperature range from 80 °C to 1200 °C. The relatively cold treatment produces a whiteamorphous powder, which is converted to amicrocrystalline product when heated at about 1000 °C for 2 hours.[4]

The main reaction of the process is:

H3BO3 + H3PO4 → BPO4 + 3 H2O

New ways of synthesizing the compound have also been reported, such ashydrothermal andmicrowave synthesis.[5]

Due to the particular industrial interest of boron phosphate, other methods are used as well:[5]

Structure

[edit]

If obtained at pressure, the ordinary structure isisomorphous with the β-cristobalite, while subjecting it to high pressure is obtained a compoundisomorphic with α-quartz.[6] The structure of AlPO4,berlinite, isisomorphous with α-quartz.[3]

Applications

[edit]

It is used as a catalyst fordehydration and other reactions inorganic synthesis. Also, it serves as a source of phosphates forexchange reactions in the solid state to obtain metal phosphates.[7]

References

[edit]
  1. ^pubchem.ncbi.nlm.nih.gov/compound/83329#section=IUPAC-Name&fullscreen=true
  2. ^Boron phosphate datasheets.scbt.com
  3. ^abCorbridge DEC 2013,Phosphorus: Chemistry, Biochemistry and Technology, 6th ed., CRC Press, Boca Raton, Florida,ISBN 978-1-4398-4088-7
  4. ^Mylius, F.; Meusser, A. (1904)."Ueber die Bestimmung der Borsäure als Phosphat".Berichte der Deutschen Chemischen Gesellschaft.37:397–401.doi:10.1002/cber.19040370171.
  5. ^abBaykal, A; Kizilyalli, M; Toprak, Muhammet S. & Kniep, R (2001). "Hydrothermal and microwave synthesis of boron phosphate, BPO4".Turkish Journal of Chemistry.25 (4):425–432.
  6. ^MacKenzie, J. D.; Roth, W. L.; Wentorf, R. H. (1959)."New high pressure modifications of BPO4 and BAsO4".Acta Crystallographica.12 (1): 79.Bibcode:1959AcCry..12...79M.doi:10.1107/S0365110X5900024X.
  7. ^Moffat, J. B.; Goltz, H. L. (1965). "Surface Chemistry and Catalytic Properties of Boron Phosphate: 1. Surface Area and Acidity".Canadian Journal of Chemistry.43 (6): 1680.doi:10.1139/v65-222.
Boron pnictogenides
Boron halides
Acids
Boranes
Boron oxides and sulfides
Carbides
Organoboron compounds
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