Borate fluoride

Русский

From Wikipedia, the free encyclopedia

Theborate fluorides orfluoroborates are compounds containingborate or complex borate ions along withfluoride ions that form salts withcations such as metals. They are in the broader category ofmixed anion compounds. They are not to be confused withtetrafluoroborates (BF₄) or thefluorooxoborates which have fluorine bonded to boron.

Examples

[edit]

formula	name	mw	system	space group	unit cell Å	volume Å³	density	comment	references
Be₂(BO₃)(OH,F) · H₂O	Berborite		trigonal	P3	a = 4.434, c = 5.334	90.82		colourless Uniaxial (-)n_ω = 1.580n_ε = 1.485 Max birefringence δ = 0.095	^[1]
γ-Be₂BO₃F	γ-BBF	95.83	trigonal	R32	a=4.4418 c=19.909 Z=3	340.17	1.946	Uniaxial (-) SHG 2.3 × KDP
NH₄Be₂BO₃F₂	ABBF	132.87	trigonal	R32	a=4.4398 c=12.4697 Z=3	212.87	2.243	Uniaxial (-)n_o=1.49389n_e=1.41919 at 636 nm	^[2]
NaBe₂BO₃F₂	sodium beryllium borate fluoride (NBBF)			C2	a=12.643 b=8.729 c=7.591 β=113.6°	768		double layers of borate rings sandwiching barium atoms. Between pairs of double layers are sodium ions with fluoride.	^[3]
Mg₂(BO₃)(F,OH)	Pertsevite-(F)		orthorhombic	Pna2₁	a = 20.49, b = 4.571, c = 11.89 Z=16	1,113.6		Density 3.12 transparent Biaxial (+)n_α = 1.609n_β = 1.620n_γ = 1.642 2V: 65° Max birefringence: δ = 0.033	^[4]
Mg₃(BO₃)(F,OH)₃	Fluoborite		hexagonal		a = 8.8, c = 3.1	208		colourless Uniaxial (-)n_ω = 1.570n_ε = 1.534 Max birefringence δ = 0.036	^[5]
Mg₃(OH)[B(OH)₄]₂(SO₄)F	sulfoborite		orthorhombic	Pnma	a=10.132 b=12.537 c=7.775	987.6		Biaxial (-)n_α = 1.527n_β = 1.536n_γ = 1.551 2V 79° Max birefringence δ = 0.024	^[6]
Na₆Mg₃B₁₀O₁₈F₆			monoclinic	P2₁/c	a=13.420b=6.400c=10.701β=90.693°			band gap 5.40 eV; birefringence Δn = 0.039 at 1064 nm	^[7]
NaMgBe₂(BO₃)₂F	NMBBF			P3c1	a=4.5408c=13.439			birefringence 0.081 at 546.1 nm	^[8]
Al₆(BO₃)₅F₃	Jeremejevite		hexagonal	P6₃/m	a = 8.5591, c = 8.1814	519		density 3.28 Uniaxial (-)n_ω = 1.653n_ε = 1.640 Max birefringence δ = 0.013	^[9]^[10]
Al₈(BO₃)₄(B₂O₅)F₈		704.7	tetragonal	P4₂/mmc	a=9.134 c=19.112 Z=4	1,595		density 2.935 colourless	^[9]
Na(Mg₃)Al₆(Si₆O₁₈)(BO₃)₃(OH)₃F	Fluor-dravite		trigonal	R3m	a = 15.955, c = 7.153 Z=3	1,577		density 3.120 dark brown Uniaxial (-)n_ω = 1.645(2)n_ε = 1.621(2) Max birefringence δ = 0.024	^[11]
Na(Li_1.5Al_1.5)Al₆(Si₆O₁₈)(BO₃)₃(OH)₃F	Fluor-elbaite		trigonal	R3m	a = 15.8933, c = 7.1222	1,558		blue green Uniaxial (-)	^[12]
K₆B₁₂O₁₉F₄		744.32	orthorhombic	Pnma	a =15.291b =7.707c =8.672 Z=2	1022.0	2.419		^[13]
KBe₂BO₃F₂	KBBF		hexagonal	R32	a=4.427 c=18.744	318.3	2.40	Be₂BO₆F₂ rings SHG 1.2 × KDP; UV cutoff 147 nm	^[14]
Ca₅(BO₃)₃F									^[15]
Li₃CaB₂O₅F		363.04	orthorhombic	Pnma	a=25.685 b=3.4697 c=5.4404 Z=2	484.84	2.487	colourless	^[16]
Li₅Ca₉(BO₃)₇F₂				P1
NaCaBe₂B₂O₆F									^[17]
KCaBe₂B₂O₆F		467.64		P3_1c	a=4.705 c=14.554 Z=2	279.1	2.783		^[18]
Ca(Li₂Al)Al₆(Si₆O₁₈)(BO₃)₃(OH)₃F	Fluor-liddicoatite		trigonal	R3m	a = 15.875, c = 7.126 Z=3	1,555		density 3.02 Uniaxial (-)n_ω = 1.637n_ε = 1.621 Max birefringence δ = 0.016	^[19]
CaMg₃(Al₅Mg)(Si₆O₁₈)(BO₃)₃(OH)₃F	Fluor-uvite		trigonal	R3m	a = 15.954, c = 7.214 Z=3	1,590		black Uniaxialn_ω = 1.637 - 1.668n_ε = 1.619 - 1.639 Max birefringence δ = 0.018 - 0.029	^[20]
KCaBe₂B₂O₆F
Sc₂F₂(B₂O₅)		229.54	orthorhombic	Pbam	a=9.667 b=14.199 c=4.0395 Z=4	554.4	2.750	colourless	^[21]
K₁₁Sc₅(B₅O₁₀)₄F₆			orthorhombic	Fdd2	a 56.769b 12.207c 12.6088			transparent to <190 nm	^[22]
Na(Mn²⁺)₃Al₆(Si₆O₁₈)(BO₃)₃(OH)₃F	Fluor-tsilaisite		trigonal	R3m	a = 15.9398, c = 7.1363	1,570		greenish yellow Uniaxial (-)	^[23]
NaFe₃Al₆Si₆B₃O₃₀F									^[9]
Na(Fe²⁺₃)Al₆(Si₆O₁₈)(BO₃)₃(OH)₃F	Fluor-schorl		trigonal	R3m	a = 16.005, c = 7.176 Z=3	1,591.9		black Uniaxial (-)n_ω = 1.660 - 1.661n_ε = 1.636 - 1.637 Max birefringence δ = 0.024	^[24]
Na(Fe³⁺₃)Al₆(Si₆O₁₈)(BO₃)₃O₃F	Fluor-buergerite		trigonal	R3m	a = 15.8692, c = 7.1882	1,568		density 3.311 brown Uniaxial (-)n_ω = 1.735n_ε = 1.655 Birefringence 0.080	^[25]
Ca(Fe²⁺)₃MgAl₅(Si₆O₁₈)(BO₃)₃(OH)₃F	Fluor-feruvite								^[26]
KCaZn₂(BO₃)₂F
Li₆RbB₂O₆F		263.73	orthorhombic	Pnma	a=8.41 b=15.96 c=5.08 Z=2	682	2.568		^[27]
RbBe₂BO₃F₂	RBBF		Trigonal	R32	a=4.434 c=19.758 z=3			also contains BeO₃F tetrahedra and BO₃. It transmits radiation from 180 to 3500 nm.	^[28]
Rb₁₈Mg₆(B₅O₁₀)₃(B₇O₁₄)₂F			monoclinic	C2/c	a=11.06b=19.70c=31.01β=90.13°				^[29]
RbCaBe₂B₂O₆F			Trigonal	R32					^[30]
KSrBe₂B₂O₆F									^[17]
LiSr₃Be₃B₃O₉F₄									^[31]
NaSr₃Be₃B₃O₉F₄									^[32]
K₃Sr₃Li₂Al₄B₆O₂₀F								SHG 4 × KDP; 170 nm UV cutoff	^[9]
Ca(Y,REE,Ca,Na,Mn)₁₅Fe²⁺(P,Si)Si₆B₃O₃₄F₁₄	Proshchenkoite-(Y)		trigonal	R3m	a = 10.7527, c = 27.4002	2,743.6		brownish	^[33]
(Y,REE,Ca,Na)₁₅(Al,Fe³⁺)(Ca_xAs³⁺_1−x)(Si,As⁵⁺)Si₆B₃(O,F)₄₈	Hundholmenite-(Y)		trigonal	R3m	a = 10.675, c = 27.02 Z=3	2,667		density 5.206 brownish Uniaxial (-)	^[34]
(Na,Ca)₃(Y,Ce)₁₂Si₆B₂O₂₇F₁₄	Okanoganite-(Y)		trigonal	R3m	a = 10.7108, c = 27.040		4.35	Tan coloured Uniaxial (-)n_ω = 1.753n_ε = 1.740 Max birefringence δ = 0.013	^[35]
? Y₅(SiO₄,BO₄)₃(O,OH,F)	Tritomite-(Y)		?hexagonal		a = 9.32, c = 6.84		3.05-3.4	isotropic n = 1.627 - 1.685
Cd₈B₅O₁₅F		1212.25	cubic	Fd3m	a = 13.972Z = 8	2,727	5.904	colourless	^[36]
CdZn₂KB₂O₆F
Li₃Cs₆Al₂B₁₄O₂₈F		1490.58	orthorhombic	Pnma	a=21.8412b=19.8875c=7.1577 Z=4	3109.1	3.184		^[37]
CsBe₂BO₃F₂		247.74	trigonal	R32	a=4.4575 c=21.310 Z=3	366.7	3.366	colourless	^[38]
Cs₁₈Mg₆(B₅O₁₀)₃(B₇O₁₄)₂F			monoclinic	C2/c	a=11.234b=20.11c=32.12β=90.225°				^[29]
CsCaBe₂B₂O₆F			trigonal	R32					^[39]
BaBOF₃		221.15	monoclinic	P2₁/c	a = 4.620 b = 15.186 c = 4.426 β = 92.045° Z=4	310.3		contains chains of -OB(F₂)- and a double chain of BaF	^[40]
Ba₅(BO₃)₃F									^[41]
Li₂BaSc(BO₃)₂F		332.80	hexagonal	P6₃/m	a=4.895 c=14.346	297.7	3.713		^[42]
LiBa₁₂(BO₃)₇F₄				I4/mcm
BaBe₂BO₃F₃		271.16	hexagonal	P6₃	a=7.628 c=13.990 Z=6	704.9	3.832	UV cutoff <185 nm; birefringence 0,081 at 200 nm	^[43]
NaBa₁₂(BO₃)₇F₄				I4/mcm
BaMgBe₂(BO₃)₂F₂	BMBBF	335.283	trigonal	P3c1	a=4.5898 c=15.348	280.01	3.976	colourless [Be₂B₃O₆F₂]_∞	^[44]
Ba_3.75MgB₇O₁₄F_2.5		886.50	monoclinic	C2/c	a 16.611b 13.677c 15.141β 121.239° Z=8	2941.0	4.004	transparent > 203 nm; birefringence 0.081@546 nm	^[45]
BaAl(BO₃)F₂			hexagonal	P6	a=4.8879 c=9.403 Z=2	194.5		UV cutoff 165 nm	^[46]
K₃Ba₃Li₂Al₄B₆O₂₀F									^[9]
K₅Ba₁₀(BO₃)₈F			trigonal	R3c	a = 15.293,c = 22.699Z = 6				^[47]
KBa₇Mg₂B₁₄O₂₈F₅			monoclinic	C2/c	a = 16.638 b = 13.609 c = 15.214 β = 121.309° Z=4	2943.3	3.934	colourless	^[48]
BaCaBe₂(BO₃)₂F₂	BCBBF		trigonal	P3c1	a=4.6931 c=16.049	306.12	3.808	colourless [Be₂B₃O₆F₂]_∞	^[44]
Li₂BaSc(BO₃)₂F			hexagonal	P6₃/m	a=4.895c=14.346				^[49]
Ba₃Zn(BO₃)(B₂O₅)F		656.82	monoclinic	P2₁/c	a = 15.179 b = 7.0064 c = 8.763 β = 100.15° Z=4	917.4	4.755	colourless	^[50]
Ba₄Zn₂(BO₃)₂(B₂O₅)F₂		937.34	monoclinic	C2/c	a=20.39 b=4.998 c=13.068 β = 192.59 Z=44	1,331	4.679	colourless	^[50]
BaZnBe₂(BO₃)₂F₂		376.35	trigonal	P3	a = 4.5998,c = 7.7037Z = 1	141.16	4.427	colourless	^[51]
Rb₃Ba₃Li₂Al₄B₆O₂₀F									^[9]
BaCdBe₂(BO₃)₂F₂	BDBBF			P3c1	a=4.6808c=15.788				^[8]
Ba_1.09Pb_0.91Be₂(BO₃)₂F₂	BPBBF		trigonal	P3m1	a = 4.7478c = 8.386,Z = 1	163.70		UV absorption edge=279.1 nm; birefringence 0.054 at 546.1 nm; 2D [Be₃B₃O₆F₃]_∞ layer	^[52]
LiBa₂Pb(BO₃)₂F			orthorhombic	Pmmn	a=5.487b=15.96c=4.034				^[49]
KNa₃Na₆Ca₂Ba₆Mn₆(Ti⁴⁺,Nb)₆B₁₂Si₃₆O₁₁₄(O,OH,F)₁₁	Tienshanite		hexagonal	P6/m	a = 16.785, c = 10.454 Z=1	2,551		pale olive green Uniaxial (-)n_ω = 1.666n_ε = 1.653 Max birefringence δ = 0.013	^[53]
Ca₆(Fe²⁺,Mn²⁺)Y₃REE₇(SiO₄)₃(PO₄)(B₃Si₃O₁₈)(BO₃)F₁₁	Laptevite-(Ce)		trigonal	R3m	a = 10.804, c = 27.726 Z=3	2,803		density 4.61 dark brown Uniaxial (-)n_ω = 1.741(3)n_ε = 1.720(3) Max birefringence δ = 0.021	^[54]
Ba(Y,Ce)₆Si₃B₆O₂₄F₂	Cappelenite-(Y)		trigonal	P3	a = 10.67, c = 4.68 Z=1	461	4.407	greenish brown	^[55]
CaMg[(Ce₇Y₃)Ca₅](SiO₄)₄(Si₂B₃AsO₁₈)(BO₃)F₁₁	Arrheniusite-(Ce)		trigonal	R3m	a = 10.8082, c = 27.5196				^[56]
Gd₄(BO₂)O₅F			orthorhombic	Pmmn	a=15.746 b=3.8142 c=6.609 Z=2	396.9	6.45	colourless	^[57]
Gd₂(BO₃)F₃
Gd₃(BO₃)₂F₃
Gd₄[B₄O₁₁]F₂
Ba₂Gd(BO₃)₂F			orthorhombic	Pnma	a = 7.571b = 10.424c = 8.581Z = 2				^[58]
Eu₅(BO₃)₃F			orthorhombic	Pnma	a=7.225 b=14.124 c=9.859 Z=4	1006.1	6.306	yellow	^[59]
TlBe₂BO₃F₂			Trigonal	R32	a=4.4387 c=19.942 Z=3	340.27	4.673	colourless	^[60]
LiBa₂Pb(BO₃)₂F			orthorhombic	Pmmn	a=5.487 b=15.97 c=4.034	353.4	5.887	colourless	^[61]
(Ca,Ce,La,Th)₁₅As⁵⁺(As³⁺_0.5,Na_0.5)Fe³⁺Si₆B₄O₄₀F₇	Vicanite-(Ce)		trigonal	R3m	a=10.881 c=27.33	2,766	4.82	greenish yellow Uniaxial (-)n_ω = 1.757n_ε = 1.722 Max birefringence δ = 0.035	^[62]

References

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^"Proshchenkoite-(Y)".www.mindat.org. Retrieved2020-12-14.
^"Hundholmenite-(Y)".www.mindat.org. Retrieved2020-12-14.
^"Okanoganite-(Y)".www.mindat.org. Retrieved2020-12-14.
^Yang, Yun; Dong, Xiaoyu; Pan, Shilie (2016)."New fluoroborate Cd 8 B 5 O 15 F with two different isolated borate anions prepared by an open high-temperature solution method".Dalton Transactions.45 (16):7008–7013.doi:10.1039/C6DT00621C.ISSN 1477-9226.PMID 26988597.
^Li, Xingqi; Chu, Dongdong; Jin, Wenqi; Yang, Zhihua; Pan, Shilie; Mutailipu, Miriding (2022-08-08)."Rearrangement of [B 2 O 5 ] Dimers within [B 7 O 14 ] Clusters Enables Enhanced Optical Anisotropy in Li 3 Cs 6 Al 2 B 14 O 28 F".Inorganic Chemistry.61 (31):12067–12072.doi:10.1021/acs.inorgchem.2c02347.ISSN 0020-1669.PMID 35894746.S2CID 251102413.
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^Liu, Lili; Yang, Yun; Jing, Qun; Dong, Xiaoyu; Yang, Zhihua; Pan, Shilie; Wu, Kui (2016-08-25)."K 5 Ba 10 (BO 3 ) 8 F: A New Potassium Barium Borate Fluoride with a Perovskite-Like Structure".The Journal of Physical Chemistry C.120 (33):18763–18770.doi:10.1021/acs.jpcc.6b05489.ISSN 1932-7447.
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^Chen, Yanna; Zhang, Min; Hu, Cong; Wu, Hongping; Yang, Zhihua; Pan, Shilie (2018-10-17)."Li 2 BaSc(BO 3 ) 2 F and LiBa 2 Pb(BO 3 ) 2 F with Layered Structures featuring Special Li−O/F Configurations".Chemistry - A European Journal.24 (58):15477–15481.doi:10.1002/chem.201804126.PMID 30230058.
^Guo, Shu; Jiang, Xingxing; Liu, Lijuan; Xia, Mingjun; Fang, Zhi; Wang, Xiaoyang; Lin, Zheshuai; Chen, Chuangtian (2016-12-27)."BaBe 2 BO 3 F 3: A KBBF-Type Deep-Ultraviolet Nonlinear Optical Material with Reinforced [Be 2 BO 3 F 2 ] ∞ Layers and Short Phase-Matching Wavelength".Chemistry of Materials.28 (24):8871–8875.doi:10.1021/acs.chemmater.6b04403.ISSN 0897-4756.
^^a ^bGuo, Shu; Jiang, Xingxing; Xia, Mingjun; Liu, Lijuan; Fang, Zhi; Huang, Qian; Wu, Ruofei; Wang, Xiaoyang; Lin, Zheshuai; Chen, Chuangtian (2017-10-02). "Structural Design of Two Fluorine–Beryllium Borates BaMBe2(BO3)2F2 (M = Mg, Ca) Containing Flexible Two-Dimensional [Be3B3O6F3]∞ Single Layers without Structural Instability Problems".Inorganic Chemistry.56 (19):11451–11454.doi:10.1021/acs.inorgchem.7b01627.ISSN 0020-1669.PMID 28885824.
^Bai, Yunjie; Wang, Xinyue; Huang, Hongbo; Dou, Danyang; Chen, Cheng; Zhang, Bingbing; Wang, Ying (2023-09-08)."Ba 3.75 MgB 7 O 14 F 2.5: A Mixed Alkaline-Earth Metal Borate Fluoride with Short Ultraviolet Cutoff Edge and Large Birefringence".Inorganic Chemistry.62 (37):15293–15299.doi:10.1021/acs.inorgchem.3c02532.ISSN 0020-1669.PMID 37681248.S2CID 261609707.
^Hu, ζ G.; Maramatsu, κ.; Kanehisa, ν.; Yoshimura, M.; Mori, Y.; Sasaki, T.; Kai, Y. (December 2003)."Reinvestigation of the crystal structure of barium aluminum borate difluoride, BaAlBO3F2, a new nonlinear optical material".Zeitschrift für Kristallographie - New Crystal Structures.218 (JG):1–2.doi:10.1524/ncrs.2003.218.jg.1.ISSN 2197-4578.S2CID 201282179.
^Liu, Lili; Yang, Yun; Jing, Qun; Dong, Xiaoyu; Yang, Zhihua; Pan, Shilie; Wu, Kui (2016-08-25)."K 5 Ba 10 (BO 3 ) 8 F: A New Potassium Barium Borate Fluoride with a Perovskite-Like Structure".The Journal of Physical Chemistry C.120 (33):18763–18770.doi:10.1021/acs.jpcc.6b05489.ISSN 1932-7447.
^Li, R. K.; Chen, Peng (2010-01-15)."KBa 7 Mg 2 B 14 O 28 F 5 , a new borate with an unusual heptaborate group and double perovskite unit".Acta Crystallographica Section C Crystal Structure Communications.66 (1):i7 –i8.Bibcode:2010AcCrC..66I...7L.doi:10.1107/S0108270109054341.ISSN 0108-2701.PMID 20048410.
^^a ^bChen, Yanna; Zhang, Min; Hu, Cong; Wu, Hongping; Yang, Zhihua; Pan, Shilie (2018-10-17)."Li 2 BaSc(BO 3 ) 2 F and LiBa 2 Pb(BO 3 ) 2 F with Layered Structures featuring Special Li−O/F Configurations".Chemistry – A European Journal.24 (58):15477–15481.doi:10.1002/chem.201804126.ISSN 0947-6539.PMID 30230058.S2CID 52294586.
^^a ^bMutailipu, Miriding; Su, Xin; Zhang, Min; Yang, Zhihua; Pan, Shilie (2017)."Ba n+2 Zn n (BO 3 ) n (B 2 O 5 )F n (n = 1, 2): new members of the zincoborate fluoride series with two kinds of isolated B–O units".Inorganic Chemistry Frontiers.4 (2):281–288.doi:10.1039/C6QI00467A.ISSN 2052-1553.
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^"Tienshanite".www.mindat.org. Retrieved2020-12-14.
^"Laptevite-(Ce)".www.mindat.org. Retrieved2020-12-14.
^"Cappelenite-(Y)".www.mindat.org. Retrieved2020-12-14.
^"Arrheniusite-(Ce)".www.mindat.org. Retrieved2020-12-14.
^Höppe, Henning A. (1 November 2015). "Gd4(BO2)O5F – a gadolinium borate fluoride oxide comprising a linear BO2 moiety".Zeitschrift für Naturforschung B.70 (11):769–774.doi:10.1515/znb-2015-0112.S2CID 197372271.
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^Kazmierczak, Karolina; Höppe, Henning A. (June 2010)."Synthesis, Crystal Structure and Optical Spectra of Europium Borate Fluoride Eu5(BO3)3F".European Journal of Inorganic Chemistry.2010 (18):2678–2681.doi:10.1002/ejic.201000105.
^McMillen, Colin D.; Hu, Jia; VanDerveer, Donald; Kolis, Joseph W. (2009-08-01)."Trigonal structures of A Be 2 BO 3 F 2 ( A = Rb, Cs, Tl) crystals".Acta Crystallographica Section B Structural Science.65 (4):445–449.doi:10.1107/S0108768109024161.ISSN 0108-7681.PMID 19617679.
^Chen, Yanna; Zhang, Min; Hu, Cong; Wu, Hongping; Yang, Zhihua; Pan, Shilie (2018-10-17)."Li 2 BaSc(BO 3 ) 2 F and LiBa 2 Pb(BO 3 ) 2 F with Layered Structures featuring Special Li−O/F Configurations".Chemistry - A European Journal.24 (58):15477–15481.doi:10.1002/chem.201804126.PMID 30230058.
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