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Berkelium tetrafluoride

From Wikipedia, the free encyclopedia
Berkelium tetrafluoride
Names
Other names
berkelium(IV) fluoride
Identifiers
3D model (JSmol)
  • InChI=1S/Bk.4FH/h;4*1H/q+4;;;;/p-4
    Key: RCTCKHUWZHELJP-UHFFFAOYSA-J
  • [Bk+4].[F-].[F-].[F-].[F-]
Properties
BkF4
Molar mass323 g·mol−1
Appearanceyellow-green solid
practically insoluble
Structure
monoclinic
Related compounds
Related compounds
Curium(III) fluoride,berkelium trifluoride
Except where otherwise noted, data are given for materials in theirstandard state (at 25 °C [77 °F], 100 kPa).
Chemical compound

Berkelium tetrafluoride is a binaryinorganic compound ofberkelium andfluorine with the chemical formulaBkF4.[1]

Synthesis

[edit]

Berkelium tetrafluoride may be formed by the fluorination of berkelium trioxide, dioxide, or trifluoride with elemental fluorine at elevated temperatures:

2Bk2O3 + 8F2 → 4BkF4 + 3O2
2BkF3 + F2 → 2BkF4

Physical properties

[edit]

Berkelium(IV) fluoride forms light brown crystals of monoclinic crystal structure ofuranium tetrafluoride type. Cell parameters: a = 1.2396 nm, b = 1.0466 nm, c = 0.8118 nm, angle β = 126.33°.[2][3]

Chemical properties

[edit]

Berkelium tetrafluoride is reduced bylithium at elevated temperatures to metallic berkelium:[4]

BkF4 + 4Li → Bk + 4LiF

References

[edit]
  1. ^Cunningham, B. B. (January 1959)."Berkelium and californium".Journal of Chemical Education.36 (1): 32.doi:10.1021/ed036p32.ISSN 0021-9584. Retrieved5 April 2023.
  2. ^Keenan, Thomas K.; Asprey, Larned B. (February 1969)."Lattice constants of actinide tetrafluorides including berkelium".Inorganic Chemistry.8 (2):235–238.doi:10.1021/ic50072a011.ISSN 0020-1669. Retrieved5 April 2023.
  3. ^Asprey, L. B.; Keenan, T. K. (1 September 1968)."The preparation of berkelium tetrafluoride and its lattice parameters (1)".Inorganic and Nuclear Chemistry Letters.4 (9):537–541.doi:10.1016/0020-1650(68)80028-5.ISSN 0020-1650. Retrieved5 April 2023.
  4. ^Edelstein, Norman M. (11 September 2013).Actinides in Perspective: Proceedings of the Actinides—1981 Conference, Pacific Grove, California, USA, 10-15 September 1981.Elsevier. p. 334.ISBN 978-1-4831-9051-8. Retrieved5 April 2023.
Bk(II)
Bk(III)
Organoberkelium(III) compounds
Bk(IV)
Salts and covalent derivatives of thefluoride ion
HF?HeF2
LiFBeF2BF
BF3
B2F4
+BO3
CF4
CxFy
+CO3
NF3
FN3
N2F2
NF
N2F4
NF2
?NF5
+N
+NO3
OF2
O2F2
OF
O3F2
O4F2
?OF4
F2Ne
NaFMgF2AlF
AlF3
SiF4P2F4
PF3
PF5
+PO4
S2F2
SF2
S2F4
SF3
SF4
S2F10
SF6
+SO4
ClF
ClF3
ClF5
?ArF2
?ArF4
KFCaF
CaF2
ScF3TiF2
TiF3
TiF4
VF2
VF3
VF4
VF5
CrF2
CrF3
CrF4
CrF5
?CrF6
MnF2
MnF3
MnF4
?MnF5
FeF2
FeF3
FeF4
CoF2
CoF3
CoF4
NiF2
NiF3
NiF4
CuF
CuF2
?CuF3
ZnF2GaF2
GaF3
GeF2
GeF4
AsF3
AsF5
Se2F2
SeF4
SeF6
+SeO3
BrF
BrF3
BrF5
KrF2
?KrF4
?KrF6
RbFSrF
SrF2
YF3ZrF2
ZrF3
ZrF4
NbF4
NbF5
MoF4
MoF5
MoF6
TcF4
TcF
5

TcF6
RuF3
RuF
4

RuF5
RuF6
RhF3
RhF4
RhF5
RhF6
PdF2
Pd[PdF6]
PdF4
?PdF6
Ag2F
AgF
AgF2
AgF3
CdF2InF
InF3
SnF2
SnF4
SbF3
SbF5
TeF4
?Te2F10
TeF6
+TeO3
IF
IF3
IF5
IF7
+IO3
XeF2
XeF4
XeF6
?XeF8
CsFBaF2 LuF3HfF4TaF5WF4
WF5
WF6
ReF4
ReF5
ReF6
ReF7
OsF4
OsF5
OsF6
?OsF
7

?OsF
8
IrF2
IrF3
IrF4
IrF5
IrF6
PtF2
Pt[PtF6]
PtF4
PtF5
PtF6
AuF
AuF3
Au2F10
?AuF6
AuF5•F2
Hg2F2
HgF2
?HgF4
TlF
TlF3
PbF2
PbF4
BiF3
BiF5
PoF2
PoF4
PoF6
AtF
?AtF3
?AtF5
RnF2
?RnF
4

?RnF
6
FrFRaF2 LrF3RfDbSgBhHsMtDsRgCnNhFlMcLvTsOg
LaF3CeF3
CeF4
PrF3
PrF4
NdF2
NdF3
NdF4
PmF3SmF
SmF2
SmF3
EuF2
EuF3
GdF3TbF3
TbF4
DyF2
DyF3
DyF4
HoF3ErF3TmF2
TmF3
YbF2
YbF3
AcF3ThF2
ThF3
ThF4
PaF4
PaF5
UF3
UF4
UF5
UF6
NpF3
NpF4
NpF5
NpF6
PuF3
PuF4
PuF5
PuF6
AmF2
AmF3
AmF4
?AmF6
CmF3
CmF4
 ?CmF6
BkF3
BkF
4
CfF3
CfF4
EsF3
EsF4
?EsF6
FmMdF3No
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